Citation: Yongsheng Zhang, Yu Shi, Liang Zhang, Jun Li, Qian Fu, Xun Zhu, Qiang Liao. Graphene oxide modified membrane for alleviated ammonia crossover and improved electricity generation in thermally regenerative batteries[J]. Chinese Chemical Letters, ;2023, 34(2): 107704. doi: 10.1016/j.cclet.2022.07.047 shu

Graphene oxide modified membrane for alleviated ammonia crossover and improved electricity generation in thermally regenerative batteries

Yongsheng Zhang ^{a, b} ,
Yu Shi ^{a, b} ,
Liang Zhang ^{a, b, *,} ,
Jun Li ^{a, b} ,
Qian Fu ^{a, b} ,
Xun Zhu ^{a, b} ,
Qiang Liao ^{a, b}

a.
Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Ministry of Education, Chongqing 400030, China
b.
Institute of Engineering Thermophysics, School of Energy and Power Engineering, Chongqing University, Chongqing 400030, China

liangzhang@cqu.edu.cn

Received Date: 21 June 2022
Revised Date: 17 July 2022
Accepted Date: 20 July 2022
Available Online: 23 July 2022

Figures(5)

Thermally regenerative batteries (TRBs) are promising for harvesting low-grade waste heat into electrical power. However, the ammonia crossover from anode to cathode causes self-discharge and then leads to the decay of capacity. To alleviate the ammonia crossover and improve electricity generation, a stable graphene oxide (GO) modified anion exchange membrane (AEM) was proposed. Compared with the original AEM, the GO modified AEM with a 39.5% lower ammonia permeability induces a 24.3% higher maximal power output and 20.2% higher energy density in TRBs. Together with the visualization result, it was demonstrated the ammonia crossover was effectively alleviated by GO modifying the AEM not at a cost of the reduced battery performance, indicating the promising application in future TRBs.
- Thermally regenerative batteries,
- Ammonia crossover,
- Surface modification,
- Graphene oxide,
- Electrophoretic deposition
1. [1]
  Z.X. Su, M.L. Zhang, P.H. Xu, et al., Energy Convers. Manage. 229 (2021) 113769. doi: 10.1016/j.enconman.2020.113769
2. [2]
  D. Zhao, A. Würger, X. Crispin, J. Energy Chem. 61 (2021) 88–103. doi: 10.1016/j.jechem.2021.02.022
3. [3]
  M. Rahimi, A.P. Straub, F. Zhang, et al., Energy Environ. Sci. 11 (2018) 276–285. doi: 10.1039/c7ee03026f
4. [4]
  M.F. Dupont, D.R. MacFarlane, J.M. Pringle, Chem. Commun. 53 (2017) 6288–6302. doi: 10.1039/C7CC02160G
5. [5]
  M. Rahimi, L. Zhu, K.L. Kowalski, et al., J. Power Source. 342 (2017) 956–963. doi: 10.1016/j.jpowsour.2017.01.003
6. [6]
  F. Zhang, J. Liu, W. Yang, B.E. Logan, Energy Environ. Sci. 8 (2015) 343–349. doi: 10.1039/C4EE02824D
7. [7]
  V.M. Palakkal, T. Nguyen, P. Nguyen, et al., ACS Appl. Energy Mater. 3 (2020) 4787–4798. doi: 10.1021/acsaem.0c00400
8. [8]
  Y.S. Zhang, L. Zhang, J. Li, et al., Electrochim. Acta 331 (2020) 135442. doi: 10.1016/j.electacta.2019.135442
9. [9]
  Y.S. Zhang, Y. Shi, L. Zhang, et al., J. Power Source 495 (2021) 229815. doi: 10.1016/j.jpowsour.2021.229815
10. [10]
  W.G. Wang, G.Q. Shu, H. Tian, X.P. Zhu, J. Power Source 388 (2018) 32–44. doi: 10.5539/enrr.v8n4p32
11. [11]
  H. Tian, W. Jiang, G.Q. Shu, et al., J. Electrochem. Soc. 166 (2019) A2814–A2825. doi: 10.1149/2.0711912jes
12. [12]
  M. Rahimi, A. D'angelo, C.A. Gorski, O. Scialdone, B.E. Logan, J. Power Source 351 (2017) 45–50. doi: 10.1016/j.jpowsour.2017.03.074
13. [13]
  M. Rahimi, T. Kim, C.A. Gorski, B. Logan, J. Power Source. 373 (2018) 95–102. doi: 10.1016/j.jpowsour.2017.10.089
14. [14]
  L. Zhang, Y.X. Li, X. Zhu, et al., Ind. Eng. Chem. Res. 58 (2019) 7408–7415. doi: 10.1021/acs.iecr.9b00616
15. [15]
  Y. Shi, L. Zhang, J. Li, et al., Renew. Energ. 159 (2020) 162–171. doi: 10.1016/j.renene.2020.05.147
16. [16]
  Y. Shi, L. Zhang, Y.S. Zhang, et al., Chem. Eng. J. 423 (2021) 130339. doi: 10.1016/j.cej.2021.130339
17. [17]
  P.Y. Chen, L. Zhang, Y. Shi, et al., J. Power Source. 517 (2022) 230719. doi: 10.1016/j.jpowsour.2021.230719
18. [18]
  M. Rahimi, Z. Schoener, X.P. Zhu, et al., J. Hazard. Mater. 322 (2017) 551–556. doi: 10.1016/j.jhazmat.2016.10.022
19. [19]
  W.G. Wang, G.Q. Shu, H. Tian, X.P. Zhu, Sep. Purif. Technol. 235 (2020) 116230. doi: 10.1016/j.seppur.2019.116230
20. [20]
  F. Vicari, A. D'angelo, Y. Kouko, et al., J. Appl. Electrochem. 48 (2018) 1381–1388. doi: 10.1007/s10800-018-1240-0
21. [21]
  F. Zhang, N. Labarge, W. Yang, J. Liu, B.E. Logan, ChemSusChem 8 (2015) 1043–1048. doi: 10.1002/cssc.201403290
22. [22]
  W.G. Wang, G.Q. Shu, X.P. Zhu, H. Tian, J. Mater. Chem. A 8 (2020) 12351–12360. doi: 10.1039/d0ta03236k
23. [23]
  Y.J. Li, S.Y. Shi, H.B. Cao, Z.J. Zhao, H. Wen, Appl. Surf. Sci. 442 (2018) 700–710. doi: 10.1016/j.apsusc.2018.02.166
24. [24]
  Y. Wang, S.S. Li, H.T. Yang, J. Luo, RSC Adv. 10 (2020) 15328–15345. doi: 10.18632/aging.103518
25. [25]
  Y. Peng, J.H. Li, Front. Environ. Sci. Eng. 7 (2013) 403–411. doi: 10.1007/s11783-013-0491-6
26. [26]
  Y.J. Li, S.Y. Shi, H.B. Cao, et al., ACS Appl. Nano Mater. 3 (2020) 588–596. doi: 10.1021/acsanm.9b02142
27. [27]
  M. Yang, C.W. Zhao, S.F. Zhang, P. Li, D.Y. Hou, Appl. Surf. Sci. 394 (2017) 149–159. doi: 10.1016/j.apsusc.2016.10.069
1. [1]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
2. [2]
  Rui Li , Ruijie Lu , Libin Yang , Jianwen Li , Zige Guo , Qiquan Yan , Mengjun Li , Yazhuo Ni , Keying Chen , Yaoyang Li , Bo Xu , Mengzhen Cui , Zhan Li , Zhiying Zhao . Immobilization of chitosan nano-hydroxyapatite alendronate composite microspheres on polyetheretherketone surface to enhance osseointegration by inhibiting osteoclastogenesis and promoting osteogenesis. Chinese Chemical Letters, 2025, 36(4): 110242-. doi: 10.1016/j.cclet.2024.110242
3. [3]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
4. [4]
  Jianwen Zhao , Shuai Wang , Shanshan Zhao , Liwei Chen , Fangang Meng , Xuelin Tian . A non-fluorinated liquid-like membrane with excellent anti-scaling performance for membrane distillation. Chinese Chemical Letters, 2025, 36(1): 109883-. doi: 10.1016/j.cclet.2024.109883
5. [5]
  Haobo Wang , Fei Wang , Yong Liu , Zhongxiu Liu , Yingjie Miao , Wanhong Zhang , Guangxin Wang , Jiangtao Ji , Qiaobao Zhang . Emerging natural clay-based materials for stable and dendrite-free lithium metal anodes: A review. Chinese Chemical Letters, 2025, 36(2): 109589-. doi: 10.1016/j.cclet.2024.109589
6. [6]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
7. [7]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
8. [8]
  Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
9. [9]
  Jiangping Chen , Hongju Ren , Kai Wu , Huihuang Fang , Chongqi Chen , Li Lin , Yu Luo , Lilong Jiang . Boosting hydrogen production of ammonia decomposition via the construction of metal-oxide interfaces. Chinese Journal of Structural Chemistry, 2024, 43(2): 100236-100236. doi: 10.1016/j.cjsc.2024.100236
10. [10]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
11. [11]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
12. [12]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
13. [13]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
14. [14]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
15. [15]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
16. [16]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
17. [17]
  Long Li , Kang Yang , Chenpeng Xi , Mengchao Li , Borong Li , Gui Xu , Yuanbin Xiao , Xiancai Cui , Zhiliang Liu , Lingyun Li , Yan Yu , Chengkai Yang . Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries. Chinese Chemical Letters, 2024, 35(6): 108814-. doi: 10.1016/j.cclet.2023.108814
18. [18]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
19. [19]
  Yang Li , Xiaoxu Liu , Tianyi Ji , Man Zhang , Xueru Yan , Mengjie Yao , Dawei Sheng , Shaodong Li , Peipei Ren , Zexiang Shen . Potassium ion doped manganese oxide nanoscrolls enhanced the performance of aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109551-. doi: 10.1016/j.cclet.2024.109551
20. [20]
  Hang Wang , Qi Wang , Chuan-De Wu . Continuous synthesis of ammonia. Chinese Journal of Structural Chemistry, 2025, 44(3): 100437-100437. doi: 10.1016/j.cjsc.2024.100437

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(715)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142