Citation: Jinkang Zhu, Chunhui Li, Xiuqin Li, Qiaochun Wang, Lei Zou. Different-shaped ligand mediating efficient structurally similar cage-to-cage transformation[J]. Chinese Chemical Letters, ;2023, 34(4): 107693. doi: 10.1016/j.cclet.2022.07.036 shu

Different-shaped ligand mediating efficient structurally similar cage-to-cage transformation

Key Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

qcwang@ecust.edu.cn

zoulei@ecust.edu.cn

Received Date: 14 March 2022
Revised Date: 12 July 2022
Accepted Date: 15 July 2022
Available Online: 19 July 2022

Figures(4)

The transformation of a Palladium-based metal-organic cage to a structurally similar one by direct ligand replacement usually leads to unwanted ligand scrambling. In this work, an intermediate ligand with different shape and basicity from the initial/final ones was introduced to avoid ligand scrambling to achieve the efficient indirect cage-to-similar-cage transformation. Compared with the direct transformation, the stepwise conversion has the advantages of high efficiency (93%) and simple workup.
- Cage to cage transformation,
- Ligand scrambling,
- Ligand exchange,
- Metal-organic cage,
- M₂L₄
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