Citation: Lingxia Liu, Jinping Chen, Tianjun Yu, Rui Hu, Guoqiang Yang, Yi Zeng, Yi Li. Amplified circularly polarized luminescence enabled by photon upconversion in spin-coating cellulose matrix[J]. Chinese Chemical Letters, ;2023, 34(3): 107649. doi: 10.1016/j.cclet.2022.06.072 shu

Amplified circularly polarized luminescence enabled by photon upconversion in spin-coating cellulose matrix

Lingxia Liu ^{a, c} ,
Jinping Chen ^a ,
Tianjun Yu ^a ,
Rui Hu ^b ,
Guoqiang Yang ^{b, c} ,
Yi Zeng ^{a, c, *,} ,
Yi Li ^{a, c, *,}

a.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

zengyi@mail.ipc.ac.cn

yili@mail.ipc.ac.cn

Received Date: 20 April 2022
Revised Date: 16 June 2022
Accepted Date: 26 June 2022
Available Online: 30 June 2022

Figures(4)

It is of great significance to construct organic circularly polarized luminescence systems (CPL) with large luminescence dissymmetry factors (g_lum) for practical applications. Here we report organic CPL systems constructed by merging triplet-triplet annihilation upconversion chromophores in cellulose matrices. The chirality of the matrix is transferred to the achiral chromophores of photon upconversion and then the multistep energy transfer processes of upconversion amplify g_lum. The g_lum value of upconversion CPL in the left-handed ethyl cellulose and the right-handed (acetyl) ethyl cellulose are up to +0.1 and −0.15, respectively. The study provides a straightforward approach for constructing solid organic upconversion CPL materials with large g_lum, which may expand the application potentials of organic chiroptical materials.
- Circularly polarized luminescence,
- Photon upconversion,
- Cellulose,
- Chirality,
- Triplet-triplet annihilation
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