Citation: Haonan Shi, Bangyuan Xiong, Ying Chen, Chaojun Lin, Jiajian Gu, Yanpeng Zhu, Jiaobing Wang. A fan-shaped synthetic chiral nanographene[J]. Chinese Chemical Letters, ;2023, 34(2): 107520. doi: 10.1016/j.cclet.2022.05.034 shu

A fan-shaped synthetic chiral nanographene

School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

wangjb5@mail.sysu.edu.cn

Received Date: 10 April 2022
Revised Date: 9 May 2022
Accepted Date: 11 May 2022
Available Online: 14 May 2022

Figures(3)

We report the synthesis and characterization of a fan-shaped chiral nanographene 1, which is composed of 6 hexabenzocoronene subunits with 216 conjugated carbon atoms. In the dehydrocyclization reaction, 38 CC bonds are formed simultaneously. 1 exhibits strong panchromatic absorption from the ultraviolet to the near-infrared, with an absorption coefficient of 209,000 L mol⁻¹ cm⁻¹ at 564 nm. Optically pure samples, obtained via chiral HPLC, show distinct ECD signals (|Δε| = 704 L mol⁻¹ cm⁻¹ at 405 nm). Upon excitation, 1 emits near-infrared fluorescence at 820 nm with a quantum yield of 5.5%. These photophysical properties of 1 were analyzed with the assistance of DFT calculations.
- Nanographene,
- Molecular nanocarbon,
- Chirality,
- Polycyclic aromatic hydrocarbon,
- Helicene
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