Citation: Pingli Feng, Wenshuo Hou, Zhe Bai, Yu Bai, Kening Sun, Zhenhua Wang. Ultrathin two-dimensional bimetal NiCo-based MOF nanosheets as ultralight interlayer in lithium-sulfur batteries[J]. Chinese Chemical Letters, ;2023, 34(4): 107427. doi: 10.1016/j.cclet.2022.04.025 shu

Ultrathin two-dimensional bimetal NiCo-based MOF nanosheets as ultralight interlayer in lithium-sulfur batteries

Beijing Key Laboratory for Chemical Power Source and Green Catalysis, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

wangzh@bit.edu.cn

Received Date: 28 February 2022
Revised Date: 30 March 2022
Accepted Date: 11 April 2022
Available Online: 14 April 2022

Figures(6)

Lithium-sulfur batteries as one of the most promising next-generation high-energy storage system, the shuttle effect, the expansion of cathode and the slow electrode redox kinetics limit its further development. Herein, we report a two-dimensional, ultrathin and ultra-light bimetal-NiCo-organic framework as the interlayer for Li-S batteries. This kind of interlayer can effectively block polysulfides and accelerate the conversion with a thickness of only 1 µm and a load of 0.1 mg/cm². Because the MOF nanosheets with a thickness of a few nanometers have a large specific surface and a large number of exposed accessible active sites. At the same time, the intrinsic activity of each site is enhanced and the catalytic performance is improved due to the synergistic effect of mixed metals and the unique coordination environment around the active sites. So, 2D NiCo MOF/CNT totally meets the requirements for the lightweight and effective interlayer. The initial discharge capacity of cell with 2D NiCo MOF/CNT interlayer can reach 1132.7 mAh/g at 0.5 C. It remained 709.1 mAh/g after 300 cycles, showing good cycling stability and rate performance.
- Li-S battery,
- Ultrathin and ultralight interlayer,
- 2D materials,
- Bimetal MOF,
- Synergistic effect
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