Citation: Di Huang, Daxiong Wu, Jixing Zhu, Jinyu Xie, Jipeng Wu, Jiaojiao Liang. One-dimensional ZnSe@N-doped carbon nanofibers with simple electrospinning route for superior Na/K-ion storage[J]. Chinese Chemical Letters, ;2023, 34(2): 107416. doi: 10.1016/j.cclet.2022.04.014 shu

One-dimensional ZnSe@N-doped carbon nanofibers with simple electrospinning route for superior Na/K-ion storage

Di Huang ^a ,
Daxiong Wu ^b ,
Jixing Zhu ^a ,
Jinyu Xie ^a ,
Jipeng Wu ^{a, b} ,
Jiaojiao Liang ^{a, *,}

a.
Hunan University of Technology, Zhuzhou 412008, China
b.
School of Physics and Electronics, Hunan University, Changsha 410082, China

liangjiaojiao@hut.edu.cn

Received Date: 4 January 2022
Revised Date: 6 February 2022
Accepted Date: 7 April 2022
Available Online: 11 April 2022

Figures(4)

One-dimensional carbon nanofibers are widely applied as anode material in the energy storage field due to its unique structure and high conductivity. In this work, one-dimensional ZnSe@N-doped carbon nanofibers (ZnSe@NC NFs) are successfully synthesized by electrospinning and annealed without extra troublesome conditions. ZnSe nanocrystals are enfolded in the N-doped carbon nanofibers, which can act as a protective layer to avoid the volume expansion of active material and promote ion transport during the cycling process. More importantly, the as-synthesized ZnSe@NC NFs are served as the anode material and display the admirable storage properties for Na/K-ion batteries. The one-dimensional ZnSe@NC NFs material shows the high capacity of 237 mAh/g for Na-ion batteries at a current density of 1 A/g for 2000 cycles. Meanwhile, it also delivers a high discharge capacity of 337 mAh/g for K-ion batteries at 0.2 A/g for 300 cycles. Additionally, it is confirmed that the pseudocapacitive contribution of the nano-structure material is up to 54.5% at a scan rate of 0.6 mV/s through the cyclic voltammetry (CV) measurement in K-ion batteries.
- ZnSe,
- Nanofibers,
- Electrospinning,
- Na-ion batteries,
- K-ion batteries,
- Pseudocapacitive
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