Citation: Feng Wang, Haoran Zhong, Zhenlu Chen, Ding Wang, Zhuangchai Lai, Yonghui Deng, Xianying Wang. Porous 2D CuO nanosheets for efficient triethylamine detection at low temperature[J]. Chinese Chemical Letters, ;2023, 34(2): 107392. doi: 10.1016/j.cclet.2022.03.115 shu

Porous 2D CuO nanosheets for efficient triethylamine detection at low temperature

Feng Wang ^{a, 1} ,
Haoran Zhong ^{a, 1} ,
Zhenlu Chen ^a ,
Ding Wang ^{a, *,} ,
Zhuangchai Lai ^b ,
Yonghui Deng ^c ,
Xianying Wang ^d

a.
School of Materials and Chemistry, University of Shanghai for Science & Technology, Shanghai 200093, China
b.
Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong, China
c.
Department of Chemistry, Fudan University, Shanghai 200433, China
d.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

wangding@usst.edu.cn

Received Date: 18 December 2021
Revised Date: 23 February 2022
Accepted Date: 30 March 2022
Available Online: 4 April 2022

Figures(4)

The freshness of seafood can be judged by detecting the concentration of triethylamine (TEA). In this work, 2D CuO porous nanosheets (CuO PNs) were prepared by a graphene oxide template method and their particle sizes were regulated by changing the calcination temperature. Their structure, morphology and gas sensing performances were investigated by various characterization methods. The response (R_g/R_a) of the gas sensor based on CuO PNs calcined at 700 ℃ was as high as 440-100 ppm TEA at the operating temperature of 40 ℃. The detection limit was as low as 0.25 ppm. In addition, the gas sensor has good selectivity and stability. The excellent TEA sensitivity is mainly resulted from the appropriate particle size and loose porous framework. This work not only paves the way to explore the novel low temperature TEA gas sensors, but also provides deep insight on improving the structure and properties of gas sensitive materials by controlling the calcination temperature.
- CuO nanosheets,
- Gas sensor,
- Porous materials,
- Triethylamine detection,
- Low operating temperature
1. [1]
  Y.Y. Shang, W.Q. Shi, R.H. Zhao, et al., Chin. Chem. Lett. 31 (2020) 2055-2058. doi: 10.1016/j.cclet.2020.01.009
2. [2]
  J.J. Liu, L.Y. Zhang, J.J. Fan, et al., Sens. Actuat. B 331 (2021) 129425. doi: 10.1016/j.snb.2020.129425
3. [3]
  Y. Sun, Z. Dong, D. Zhang, et al., Sens. Actuat. B 326 (2021) 128791. doi: 10.1016/j.snb.2020.128791
4. [4]
  W.J. Wei, J.X. Zhao, S.X. Shi, et al., J. Mater. Chem. C 8 (2020) 6734-6742. doi: 10.1039/d0tc01022g
5. [5]
  X.L. Xu, S.Y. Wang, W.W. Liu, et al., Sens. Actuator. B 333 (2021) 129616. doi: 10.1016/j.snb.2021.129616
6. [6]
  D.P. Xue, Y. Wang, J.L. Cao, et al., Nanomaterials-Basel. 8 (2018) 1025. doi: 10.3390/nano8121025
7. [7]
  Y.H. Zou, S. Chen, J. Sun, et al., ACS Sens. 2 (2017) 897-902. doi: 10.1021/acssensors.7b00276
8. [8]
  C.B. Zhai, M.M. Zhu, L. Jiang, et al., Appl. Surf. Sci. 463 (2019) 1078-1084. doi: 10.1016/j.apsusc.2018.09.049
9. [9]
  G. Li, Z. Ma, Q. Hu, et al., ACS Appl. Nano Mater. 4 (2021) 10921-10930. doi: 10.1021/acsanm.1c02377
10. [10]
  P.F. Cheng, F. Dang, Y.L. Wang, et al., Sens. Actuator. B 328 (2021) 129028. doi: 10.1016/j.snb.2020.129028
11. [11]
  S.X. Cai, X.Q. Song, Z.T. Chi, et al., Sens. Actuator. B 343 (2021) 130118. doi: 10.1016/j.snb.2021.130118
12. [12]
  M.T. Vijjapu, S.G. Surya, J.H. He, et al., ACS Appl. Mater. Interfaces 13 (2021) 40460-40470. doi: 10.1021/acsami.1c06546
13. [13]
  K. Rajendran, N. Pandurangan, C.P. Vinod, et al., Appl. Catal. B 297 (2021) 120417. doi: 10.1016/j.apcatb.2021.120417
14. [14]
  Y.Q. Guo, X.F. Hong, Y. Wang, et al., Adv. Funct. Mater. 29 (2019) 1809004. doi: 10.1002/adfm.201809004
15. [15]
  M.G. Zhao, J.T. Yu, X.M. Zhang, et al., Adv. Funct. Mater. 31 (2021) 2008604. doi: 10.1002/adfm.202008604
16. [16]
  Y. Yang, L.M. Sun, W.W. Zhan, et al., J. Mater. Chem. A 9 (2021) 4310-4316. doi: 10.1039/d0ta10831f
17. [17]
  H.S. Xie, X.F. Liu, R. Wu, et al., ACS Appl. Energy Mater. 3 (2020) 7325-7334. doi: 10.1021/acsaem.0c00590
18. [18]
  P.Y. Wang, L.L. Peng, J.Y. Lin, et al., Chem. Eng. J. 415 (2021) 128901. doi: 10.1016/j.cej.2021.128901
19. [19]
  H.N. Sun, J.P. Liu, G. Chen, et al., Small Methods (2021) 2101017.
20. [20]
  Y.L. Zhang, C.W. Jia, R.N. Tian, et al., Rare Metals 40 (2021) 1578-1587. doi: 10.1007/s12598-020-01547-6
21. [21]
  J. Hu, X. Chen, Y. Zhang, Sens. Actuator. B 349 (2021) 130738. doi: 10.1016/j.snb.2021.130738
22. [22]
  X. Chen, J. Hu, P. Chen, et al., Sens. Actuator. B 339 (2021) 129902. doi: 10.1016/j.snb.2021.129902
23. [23]
  C. Liu, J. Hu, G. Wu, et al., ACS Appl. Mater. Interfaces 13 (2021) 56309-56319. doi: 10.1021/acsami.1c17044
24. [24]
  K. Xu, C.Y. Zhan, W. Zhao, et al., J. Hazard. Mater. 416 (2021) 125906. doi: 10.1016/j.jhazmat.2021.125906
25. [25]
  N.D. Hoa, C.M. Hung, N.V. Duy, et al., Sens. Actuator. B 273 (2018) 784-793. doi: 10.1016/j.snb.2018.06.095
26. [26]
  Q. Rong, Y. Li, S. Hao, et al., J. Mater. Chem. A 9 (2021) 6529-6537. doi: 10.1039/d0ta11695e
27. [27]
  K. Zhang, S.W. Qin, P.G. Tang, et al., J. Hazard. Mater. 391 (2020) 122191. doi: 10.1016/j.jhazmat.2020.122191
28. [28]
  Y.P. Wu, W. Zhou, W.W. Dong, et al., Cryst. Growth Des. 17 (2017) 2158-2165. doi: 10.1021/acs.cgd.7b00102
29. [29]
  W.C. Geng, Z.Y. Ma, Y.J. Zhao, et al., Sens. Actuators, B. 325 (2020) 128775. doi: 10.1016/j.snb.2020.128775
30. [30]
  J.F. Xu, W. Ji, Z.X. Shen, et al., J. Raman Spectr. 30 (1999) 413-415. doi: 10.1002/(SICI)1097-4555(199905)30:5<413::AID-JRS387>3.0.CO;2-N
31. [31]
  X.B. Hu, Z.G. Zhu, Z.H. Li, et al., Sens. Actuat. B 264 (2018) 139-149. doi: 10.1016/j.snb.2018.02.110
32. [32]
  S. Liang, Y.M. Zhou, W.T. Wu, et al., J. Photochem. Photobiol. A 346 (2017) 168-176. doi: 10.1016/j.jphotochem.2017.06.005
33. [33]
  X.N. Meng, M.X. Yao, S.F. Mu, et al., ChemistrySelect 4 (2019) 11268-11274. doi: 10.1002/slct.201902174
34. [34]
  H.M. Sun, X.N. Tang, J.R. Zhang, et al., Sens. Actuator. B 346 (2021) 130546. doi: 10.1016/j.snb.2021.130546
35. [35]
  K. Xu, Q. Tang, W. Zhao, et al., Sens. Actuator. B 302 (2020) 127154. doi: 10.1016/j.snb.2019.127154
36. [36]
  Q. Wei, J. Sun, P. Song, et al., Sens. Actuator. B 317 (2020) 128205. doi: 10.1016/j.snb.2020.128205
37. [37]
  S.X. Cao, L.L. Peng, B.T. Liu, et al., J. Alloys Compd. 798 (2019) 478-483. doi: 10.1016/j.jallcom.2019.05.267
38. [38]
  K.C. Wan, D. Wang, F. Wang, et al., ACS Appl. Mater. Interfaces 11 (2019) 45214-45225. doi: 10.1021/acsami.9b16599
39. [39]
  Y.S. Xu, L.L. Zheng, C. Yang, et al., ACS Appl. Mater. Interfaces 12 (2020) 20704-20713. doi: 10.1021/acsami.0c04398
40. [40]
  X.J. Zhu, X.L. Zhang, X.T. Chang, et al., Sens. Actuator. B 347 (2021) 130599. doi: 10.1016/j.snb.2021.130599
41. [41]
  M.Z. Jiao, X.Y. Chen, K.X. Hu, et al., Rare Metals 40 (2021) 1515-1527. doi: 10.1007/s12598-020-01679-9
42. [42]
  Z.Z. Huang, X.M. Wang, F.Z. Sun, et al., Mater. Des. 201 (2021) 109507. doi: 10.1016/j.matdes.2021.109507
43. [43]
  X. An, C. Hu, H. Liu, et al., J. Mater. Chem. A 5 (2017) 24989-24994. doi: 10.1039/C7TA08809D
44. [44]
  L. Hou, Z. Guan, M. Zhang, et al., Catal. Sci. Technol. 8 (2018) 2809-2817. doi: 10.1039/C8CY00644J
1. [1]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
2. [2]
  Siqi Sun , Cheng Zhao , Zhaohuan Zhang , Ding Wang , Xinru Yin , Jingting Han , Jinlei Wei , Yong Zhao , Yongheng Zhu . Highly selective QCM sensor based on functionalized hierarchical hollow TiO₂ nanospheres for detecting ppb-level 3-hydroxy-2-butanone biomarker at room temperature. Chinese Chemical Letters, 2025, 36(5): 109939-. doi: 10.1016/j.cclet.2024.109939
3. [3]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
4. [4]
  Yuchen Zhang , Lifeng Ding , Zhenghe Xie , Xin Zhang , Xiaofeng Sui , Jian-Rong Li . Porous sorbents for direct capture of carbon dioxide from ambient air. Chinese Chemical Letters, 2025, 36(3): 109676-. doi: 10.1016/j.cclet.2024.109676
5. [5]
  Huakang Zong , Xinyue Li , Yanlin Zhang , Faxun Wang , Xingxing Yu , Guotao Duan , Yuanyuan Luo . Pt/Ti₃C₂ electrode material used for H₂S sensor with low detection limit and high stability. Chinese Chemical Letters, 2025, 36(5): 110195-. doi: 10.1016/j.cclet.2024.110195
6. [6]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
7. [7]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
8. [8]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
9. [9]
  Yijian Zhao , Jvzhe Li , Yunyi Shi , Jie Hu , Meiyi Liu , Yao Shen , Xinglin Hou , Qiuyue Wang , Qi Wang , Zhiyi Yao . A label-free and ratiometric fluorescent sensor based on porphyrin-metal-organic frameworks for sensitive detection of ochratoxin A in cereal. Chinese Chemical Letters, 2025, 36(4): 110132-. doi: 10.1016/j.cclet.2024.110132
10. [10]
  Ren Shen , Yanmei Fang , Chunxiao Yang , Quande Wei , Pui-In Mak , Rui P. Martins , Yanwei Jia . UV-assisted ratiometric fluorescence sensor for one-pot visual detection of Salmonella. Chinese Chemical Letters, 2025, 36(4): 110143-. doi: 10.1016/j.cclet.2024.110143
11. [11]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
12. [12]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699
13. [13]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
14. [14]
  Lu Dai , Yuxin Ren , Shuang Li , Meidi Wang , Chentao Hu , Ya-Pan Wu , Guangtong Hai , Dong-Sheng Li . Room-temperature synthesis of Co(OH)₂/Mo₂TiC₂T_x hetero-nanosheets with interfacial coupling for enhanced oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(4): 109774-. doi: 10.1016/j.cclet.2024.109774
15. [15]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243
16. [16]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
17. [17]
  Zeyin Chen , Jiaju Shi , Yusheng Zhou , Peng Zhang , Guodong Liang . Polymer microparticles with ultralong room-temperature phosphorescence for visual and quantitative detection of oxygen through phosphorescence image and lifetime analysis. Chinese Chemical Letters, 2025, 36(5): 110629-. doi: 10.1016/j.cclet.2024.110629
18. [18]
  Hualei Xu , Manman Han , Haiqiang Liu , Liang Qin , Lulu Chen , Hao Hu , Ran Wu , Chenyu Yang , Hua Guo , Jinrong Li , Jinxiang Fu , Qichen Hao , Yijun Zhou , Jinchao Feng , Xiaodong Wang . 4-Nitrocatechol as a novel matrix for low-molecular-weight compounds in situ detection and imaging in biological tissues by MALDI-MSI. Chinese Chemical Letters, 2024, 35(6): 109095-. doi: 10.1016/j.cclet.2023.109095
19. [19]
  Xinyu Yu , Fei Wu , Xianglang Sun , Linna Zhu , Baoyu Xia , Zhong'an Li . Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells. Chinese Chemical Letters, 2024, 35(10): 109821-. doi: 10.1016/j.cclet.2024.109821
20. [20]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(660)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142