Citation: Ying Zou, Qiang Gao, Na Sun, Songde Han, Xiaoyu Li, Guoming Wang. Ligand-regulated unusual nickel clusters: A centrosymmetric dicubane Ni₈ and a tetrahedral Ni₁₀ cluster[J]. Chinese Chemical Letters, ;2023, 34(3): 107390. doi: 10.1016/j.cclet.2022.03.113 shu

Ligand-regulated unusual nickel clusters: A centrosymmetric dicubane Ni₈ and a tetrahedral Ni₁₀ cluster

Ying Zou ^a ,
Qiang Gao ^b ,
Na Sun ^c ,
Songde Han ^a ,
Xiaoyu Li ^{a, *,} ,
Guoming Wang ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China
b.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
c.
The Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China

xylichem@126.com

gmwang_pub@163.com

Received Date: 3 March 2022
Revised Date: 27 March 2022
Accepted Date: 30 March 2022
Available Online: 3 April 2022

Figures(3)

Based on the reported Fe clusters constructed by using N-tris(hydroxymethyl)methylglycine (H₅thmmg), herein, we explored the use of H₅thmmg for Ni chemistry. Successfully, an octanuclear Ni cluster, Ni₈O(H₃thmmg)₆·2NO₃ (Ni₈) was acquired under solvothermal condition. Its metallic core is comprised of two centrosymmetric cubanes Ni₄(µ₃-O)₃(µ₆-O) linked by sharing an O²⁻ ion and six H₃thmmg²⁻ ligands are attached to the periphery. Interestingly, the 2-mercapto-5-amino-1,3,4-thiadiazole (Hmat) ligand with both N and S donor atoms was introduced into the synthesis of Ni₈ cluster, a disparate decanuclear nickel cluster, Ni₁₀O(OH)₂(H₃thmmg)₄(mat)₈ (Ni₁₀) is assembled by H₃thmmg²⁻ and mat⁻ mixed ligands. The metal core of Ni₁₀ cluster is a pudgy tetrahedron, whose four vertexes are four Ni²⁺ ions and the remanent six Ni²⁺ ions are located in the tetrahedral cavity. Four H₃thmmg²⁻ ligands are located at the four vertices of the tetrahedron and 8 mat⁻ ligands are all on the six sides of the tetrahedron. The different synthetic conditions contribute to the different configurations. Magnetic studies indicate that both complexes Ni₈ and Ni₁₀ display antiferromagnetic interactions.
- Polymetallic,
- Nickel clusters,
- Ligand-regulated,
- Synthesis,
- Magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142

Ligand-regulated unusual nickel clusters: A centrosymmetric dicubane Ni8 and a tetrahedral Ni10 cluster

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通讯作者: 陈斌, bchen63@163.com

Ligand-regulated unusual nickel clusters: A centrosymmetric dicubane Ni₈ and a tetrahedral Ni₁₀ cluster