Citation: Zele Chen, Jiarong Chen, Jun Xuan. Photochemical defluorinative functionalization of α‐polyfluorinated carbonyls via spin‐center shift[J]. Chinese Chemical Letters, ;2022, 33(6): 2763-2764. doi: 10.1016/j.cclet.2022.03.094 shu

Photochemical defluorinative functionalization of α‐polyfluorinated carbonyls via spin‐center shift

Zele Chen ^a ,
Jiarong Chen ^{b, *,} ,
Jun Xuan ^{a, *,}

a.
Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China
b.
CCNU-uOttawa Joint Research Centre, College of Chemistry, Central China Normal University, Wuhan 430079, China

chenjiarong@mail.ccnu.edu.cn

xuanjun@ahu.edu.cn

Figures(1)

1. [1]
  K. Muller, C. Faeh, F. Diederich, Science317 (2007) 1881–1886. doi: 10.1126/science.1131943
2. [2]
  X. Ma, Q.L. Song, Chem. Soc. Rev. 49 (2020) 9197–9219. doi: 10.1039/d0cs00604a
3. [3]
  K. Chen, N. Berg, R. Gschwind, B. König, J. Am. Chem. Soc. 139 (2017)18444–18447. doi: 10.1021/jacs.7b10755
4. [4]
  H. Wang, N.T. Jui, J. Am. Chem. Soc. 140 (2018)163–166. doi: 10.1021/jacs.7b12590
5. [5]
  D.B. Vogt, C.P. Seath, H. Wang, N.T. Jui, J. Am. Chem. Soc. 141 (2019) 13203–13211. doi: 10.1021/jacs.9b06004
6. [6]
  J.B.I. Sap, N.J.W. Straathof, T. Knauber, et al., J. Am. Chem. Soc. 142 (2020) 9181–9187. doi: 10.1021/jacs.0c03881
7. [7]
  N. Sugihara, K. Suzuki, Y. Nishimoto, M. Yasuda, J. Am. Chem. Soc. 143 (2021) 9308–9313. doi: 10.1021/jacs.1c03760
8. [8]
  S.S. Yan, S.H. Liu, L. Chen, Chem7 (2021) 3099–3113. doi: 10.1016/j.chempr.2021.08.004
9. [9]
  T. Ye, Y.J. Yu, F.L. Zhang, Y.F. Wang, Chin. Chem. Lett. (2021) 33 (2022) 1193-1198. doi: 10.1016/j.cclet.2021.08.043
10. [10]
  Y.J. Yu, F.L. Zhang, T.Y. Peng, et al., Science371 (2021) 1232–1240. doi: 10.1126/science.abg0781
11. [11]
  M.W. Campbell, V.C. Polites, S. Patel, et al., J. Am. Chem. Soc. 143 (2021) 19648–19654. doi: 10.1021/jacs.1c11059
12. [12]
  J.H. Ye, P. Bellotti, C. Heusel, F. Glorius, Angew. Chem. Int. Ed. 61 (2022) e2021154566.
13. [13]
  S. Ghosh, Z.W. Qu, S. Pradhan, et al., Angew. Chem. Int. Ed. 61 (2022) e202115272.
14. [14]
  C. Liu, N. Shen, R. Shang, Nat. Commun. 13 (2022) 354. doi: 10.1038/s41467-022-28007-2
1. [1]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
2. [2]
  Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430
3. [3]
  Wenping Dong , Mo Ma , Jingkang Li , Lanlan Xu , Dejiang Gao , Pinyi Ma , Daqian Song . Near-infrared fluorescent probe with large Stokes shift and long emission wavelength for rapid diagnosis of lung cancer via aerosol inhalation delivery. Chinese Chemical Letters, 2025, 36(5): 110147-. doi: 10.1016/j.cclet.2024.110147
4. [4]
  Ruotong Wei , Aokun Liu , Jian Kuang , Zhiwen Wang , Lu Yu , Changlin Tian . Probing the dynamic properties in the LLPS process via site-directed spin labeling-electron paramagnetic resonance (SDSL-EPR) spectroscopy. Chinese Chemical Letters, 2025, 36(4): 110029-. doi: 10.1016/j.cclet.2024.110029
5. [5]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
6. [6]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
7. [7]
  Jian Han , Li-Li Zeng , Qin-Yu Fei , Yan-Xiang Ge , Rong-Hui Huang , Fen-Er Chen . Recent advances in remote C(sp³)–H functionalization via chelating group-assisted metal-catalyzed chain-walking reaction. Chinese Chemical Letters, 2024, 35(11): 109647-. doi: 10.1016/j.cclet.2024.109647
8. [8]
  Tao Zhou , Jing Zhou , Yunyun Liu , Jie-Ping Wan , Fen-Er Chen . Transition metal-free tunable synthesis of 3-(trifluoromethylthio) and 3-trifluoromethylsulfinyl chromones via domino C–H functionalization and chromone annulation of enaminones. Chinese Chemical Letters, 2024, 35(11): 109683-. doi: 10.1016/j.cclet.2024.109683
9. [9]
  Peng Wang , Jianjun Wang , Ni Song , Xin Zhou , Ming Li . Radical dehydroxymethylative fluorination of aliphatic primary alcohols and diverse functionalization of α-fluoroimides via BF₃·OEt₂-catalyzed C‒F bond activation. Chinese Chemical Letters, 2025, 36(1): 109748-. doi: 10.1016/j.cclet.2024.109748
10. [10]
  You Zhou , Li-Sheng Wang , Shuang-Gui Lei , Bo-Cheng Tang , Zhi-Cheng Yu , Xing Li , Yan-Dong Wu , Kai-Lu Zheng , An-Xin Wu . I₂-DMSO mediated tetra-functionalization of enaminones for the construction of novel furo[2′,3′:4,5]pyrimido[1,2-b]indazole skeletons via in situ capture of ketenimine cations. Chinese Chemical Letters, 2025, 36(1): 109799-. doi: 10.1016/j.cclet.2024.109799
11. [11]
  Zhiwei Zhong , Yanbin Huang , Wantai Yang . A simple photochemical method for surface fluorination using perfluoroketones. Chinese Chemical Letters, 2024, 35(5): 109339-. doi: 10.1016/j.cclet.2023.109339
12. [12]
  Mei Peng , Wei-Min He . Photochemical synthesis and group transfer reactions of azoxy compounds. Chinese Chemical Letters, 2024, 35(8): 109899-. doi: 10.1016/j.cclet.2024.109899
13. [13]
  Shehla Khalid , Muhammad Bilal , Nasir Rasool , Muhammad Imran . Photochemical reactions as synthetic tool for pharmaceutical industries. Chinese Chemical Letters, 2024, 35(9): 109498-. doi: 10.1016/j.cclet.2024.109498
14. [14]
  Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
15. [15]
  Ji Chen , Yifan Zhao , Shuwen Zhao , Hua Zhang , Youyu Long , Lingfeng Yang , Min Xi , Zitao Ni , Yao Zhou , Anran Chen . Heterogeneous bimetallic oxides/phosphides nanorod with upshifted d band center for efficient overall water splitting. Chinese Chemical Letters, 2024, 35(9): 109268-. doi: 10.1016/j.cclet.2023.109268
16. [16]
  Lei Shen , Yang Zhang , Linlin Zhang , Chuanwang Liu , Zhixian Ma , Kangjiang Liang , Chengfeng Xia . Phenylhydrazone anions excitation for the photochemical carbonylation of aryl iodides with aldehydes. Chinese Chemical Letters, 2024, 35(4): 108742-. doi: 10.1016/j.cclet.2023.108742
17. [17]
  Yan Guo , Hongtao Bian , Le Yu , Jiani Ma , Yu Fang . Photochemical reaction mechanism of benzophenone protected guanosine at N7 position. Chinese Chemical Letters, 2025, 36(3): 109971-. doi: 10.1016/j.cclet.2024.109971
18. [18]
  Chuanfeng Fan , Jian Gao , Yingkai Gao , Xintong Yang , Gaoning Li , Xiaochun Wang , Fei Li , Jin Zhou , Haifeng Yu , Yi Huang , Jin Chen , Yingying Shan , Li Chen . A non-peptide-based chymotrypsin-targeted long-wavelength emission fluorescent probe with large Stokes shift and its application in bioimaging. Chinese Chemical Letters, 2024, 35(10): 109838-. doi: 10.1016/j.cclet.2024.109838
19. [19]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
20. [20]
  Guanxiong Yu , Chengkai Xu , Huaqiang Ju , Jie Ren , Guangpeng Wu , Chengjian Zhang , Xinghong Zhang , Zhen Xu , Weipu Zhu , Hao-Cheng Yang , Haoke Zhang , Jianzhao Liu , Zhengwei Mao , Yang Zhu , Qiao Jin , Kefeng Ren , Ziliang Wu , Hanying Li . Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2023. Chinese Chemical Letters, 2024, 35(11): 109893-. doi: 10.1016/j.cclet.2024.109893

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(722)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142