Citation: Kangting Zheng, Bingxue Niu, Cunmeng Lin, Yizhen Song, Pengtao Ma, Jingping Wang, Jingyang Niu. DL-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism[J]. Chinese Chemical Letters, ;2023, 34(2): 107238. doi: 10.1016/j.cclet.2022.02.043 shu

DL-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism

Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

mpt@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 30 December 2021
Revised Date: 8 February 2022
Accepted Date: 17 February 2022
Available Online: 20 February 2022

Figures(4)

A series of DL-serine covalently modified multinuclear lanthanide implanted arsenotungstates K₂[{Ln(H₂O)₇}₂{As₄W₄₄O₁₃₇(OH)₁₈(H₂O)₂(DL-Ser)₂}{Ln₂(H₂O)₅(DL-Ser)}₂]·65H₂O (DL-Ser = DL-serine, Ln = La (1), Ce (2), Pr (3)) are obtained. Crystal structure analysis shows that these compounds are isomorphic and contain the basic [{As₄W₄₄O₁₃₇(OH)₁₈(H₂O)₂(DL-Ser)₂}{Ln₂(H₂O)₅(DL-Ser)}₂]^8– polyoxoanion constituted by two {As₂W₁₉O₅₉(OH)₈(H₂O)}^6‒ subunits, a [W₆O₂₃(OH)₂(DL-Ser)₂]^14‒ fragment, and two embedded [Ln₂(H₂O)₅(DL-Ser)]⁵⁺ groups, which further build into one dimensional linear chainlike structure via two peripheral Ln³⁺ ions. Most remarkably, these compounds exhibit rapid photochromic behaviors, which changed color quickly from white (1), yellow (2), green (3) to blue (1), brown (2) and glaucous (3) in ten minutes under UV irradiation, and that the colors gradually recovered in the dark for approximately 22 h.
- Polyoxometalate,
- Arsenotungstate,
- Carboxylate covalently modified,
- Lanthanide,
- Photochromism
1. [1]
  H.G. He, G.W. Wang, S.C. Chai, et al., Chin. Chem. Lett. 32 (2021) 2013–2016. doi: 10.1016/j.cclet.2021.01.051
2. [2]
  L. Cronin, A. Muller, Chem. Soc. Rev. 41 (2012) 7333–7334. doi: 10.1039/c2cs90087d
3. [3]
  T.P. Hu, Zhao Y. Q, Z. Jagličić, et al., Inorg. Chem. 54 (2015) 7415–7423. doi: 10.1021/acs.inorgchem.5b00962
4. [4]
  Y.Q. Zhao, K. Yu, L.W. Wang, et al., Inorg. Chem. 53 (2014) 11046–11050. doi: 10.1021/ic501567s
5. [5]
  J.J. Walsh, A.M. Bond, R.J. Forster, T.E. Keyes, Coord. Chem. Rev. 306 (2016) 217–234. doi: 10.1016/j.ccr.2015.06.016
6. [6]
  G.P. Yang, Y. Liu, K. Li, et al., Chin. Chem. Lett. 31 (2020) 3233–3236. doi: 10.1016/j.cclet.2020.07.018
7. [7]
  P.T. Ma, H Feng, J.P. Wang, J.Y. Niu, Coord. Chem. Rev. 378 (2019) 281–309. doi: 10.1016/j.ccr.2018.02.010
8. [8]
  P.T. Ma, H Feng, R. Wan, et al., J. Mater. Chem. C 4 (2016) 5424–5433. doi: 10.1039/C6TC00960C
9. [9]
  Y.T. Zhang, X.L. Wang, S.B. Li, et al., Inorg. Chem. 55 (2016) 8770–8775. doi: 10.1021/acs.inorgchem.6b01338
10. [10]
  Y.T. Zhang, X.L. Wang, S.B. Li, et al., Chem. Commun. 52 (2016) 9632–9635. doi: 10.1039/C6CC04583A
11. [11]
  Y.T. Zhang, S.B. Li, X.L. Wang, et al., Dalton Trans. 45 (2016) 14898–14901. doi: 10.1039/C6DT02764D
12. [12]
  K. Wang, N.J. Niu, D.Y. Zhao, et al., Inorg. Chem. 56 (2017) 14053–14059. doi: 10.1021/acs.inorgchem.7b02207
13. [13]
  A. Muller, V.P. Fedin, C. Kuhlmann, H. Bogge, M. Schmidtmann, Chem. Commun. (1999) 927–929.
14. [14]
  U. Kortz, M.G. Savelieff, F.Y.A. Ghali, et al., Angew. Chem. Int. Ed. 41 (2002) 4070–4073. doi: 10.1002/1521-3773(20021104)41:21<4070::AID-ANIE4070>3.0.CO;2-3
15. [15]
  D.H. Yang, Y.F. Liang, P.T. Ma, et al., CrystEngComm 16 (2014) 8041–8046. doi: 10.1039/C4CE00580E
16. [16]
  Y.F. Liang, S.Z. Li, D.H. Yang, et al., J. Mater. Chem. C 3 (2015) 4632–4639. doi: 10.1039/C5TC00297D
17. [17]
  D.H. Yang, S.Z. Li, P.T. Ma, J.P. Wang, J.Y. Niu, Inorg. Chem. 52 (2013) 14034–14039. doi: 10.1021/ic401804e
18. [18]
  D.H. Yang, Y.F. Liang, P.T. Ma, et al., Inorg. Chem. 53 (2014) 3048–3053. doi: 10.1021/ic402882a
19. [19]
  D.H. Yang, S.Z. Li, P.T. Ma, J.P. Wang, J.Y. Niu, Inorg. Chem. 52 (2013) 8987–8992. doi: 10.1021/ic401176j
20. [20]
  M.R. Healey, R.W. Gable, C. Ritchie, C. Boskovic, Polyhedron 64 (2013) 13–19. doi: 10.1016/j.poly.2013.01.058
21. [21]
  C. Ritchie, C.E. Miller, C. Boskovic, Dalton Trans. 40 (2011) 12037–12039. doi: 10.1039/c1dt10866b
22. [22]
  M. Vonci, F.A. Bagherjeri, P.D. Hall, et al., Chem. Eur. J. 20 (2014) 14102–14111. doi: 10.1002/chem.201403222
23. [23]
  F.A. Bagherjeri, M. Vonci, E.A. Nagul, et al., Inorg. Chem. 55 (2016) 12329–12347. doi: 10.1021/acs.inorgchem.6b02218
24. [24]
  X.J. Feng, H.Y. Han, Y.H. Wang, et al., CrystEngComm 15 (2013) 7267–7273. doi: 10.1039/c3ce40686e
25. [25]
  P.T. Ma, R. Wan, Y.N. Si, et al., Dalton Trans. 44 (2015) 11514–11523. doi: 10.1039/C5DT01323B
26. [26]
  Y. Wang, X.P. Sun, S.Z. Li, et al., Cryst. Growth Des. 15 (2015) 2057–2063. doi: 10.1021/cg5012499
27. [27]
  J. Wang, W.J. Shi, S.J. Li, et al., Dalton Trans. 47 (2018) 7949–7955.
28. [28]
  H.L. Li, Y.J. Liu, J.L. Liu, et al., Chem. Eur. J. 23 (2017) 2673–2689. doi: 10.1002/chem.201605070
29. [29]
  C. Ritchie, M. Speldrich, R.W. Gable, L. Sorace, C. Boskovic, Inorg. Chem. 50 (2011) 7004–7014. doi: 10.1021/ic200366a
30. [30]
  H.C. Wu, R. Wan, Y.N. Si, et al., Dalton Trans. 47 (2018) 1958–1965.
31. [31]
  B. Yan, H.C. Wu, P.T. Ma, J.P. Wang, J.Y. Niu, Inorg. Chem. Front. 8 (2021) 4158–4176. doi: 10.1039/d1qi00681a
32. [32]
  B. Yan, R.C. Liang, K.T. Zheng, et al., Inorg. Chem. 60 (2021) 8164–8172. doi: 10.1021/acs.inorgchem.1c00798
33. [33]
  T. Yamase, Chem. Rev. 98 (1998) 307–326. doi: 10.1021/cr9604043
34. [34]
  T. Yamase, M. Sugeta, J. Chem. Soc. Dalton Trans. (1993) 759–765.
35. [35]
  E. Papaconstantinou, Chem. Soc. Rev. 18 (1989) 1–31. doi: 10.1039/cs9891800001
36. [36]
  R. Dessapt, M. Collet, V. Coué, et al., Inorg. Chem. 48 (2009) 574–580. doi: 10.1021/ic8013865
37. [37]
  O. Oms, T. Benali, J. Marrot, et al., Inorganics 3 (2015) 279–294. doi: 10.3390/inorganics3020279
38. [38]
  R.C. Howell, F.G. Perez, S. Jain, et al., Angew. Chem. Int. Ed. 40 (2001) 4031–4034. doi: 10.1002/1521-3773(20011105)40:21<4031::AID-ANIE4031>3.0.CO;2-8
39. [39]
  J. Wang, P.T. Ma, Y.P. Wang, et al., J. Phys. Chem. Solids. 110 (2017) 161–166. doi: 10.1016/j.jpcs.2017.06.007
40. [40]
  V. Coué, R. Dessapt, M. Bujoli-Doeuff, M. Evain, S. Jobic, Inorg. Chem. 46 (2007) 2824–2835. doi: 10.1021/ic0621502
41. [41]
  Y.F. Liang, S.Z. Li, D.H. Yang, et al., J. Mater. Chem. C 3 (2015) 4632–4639. doi: 10.1039/C5TC00297D
1. [1]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
2. [2]
  Yarui Li , Huangjie Lu , Yingzhe Du , Jie Qiu , Peng Lin , Jian Lin . Highly efficient separation of high-valent actinide ions from lanthanides via fractional crystallization. Chinese Journal of Structural Chemistry, 2025, 44(4): 100562-100562. doi: 10.1016/j.cjsc.2025.100562
3. [3]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
4. [4]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
5. [5]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
6. [6]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
7. [7]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
8. [8]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
9. [9]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
10. [10]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
11. [11]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
12. [12]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
13. [13]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
14. [14]
  Hai-Ling Wang , Zhong-Hong Zhu , Hua-Hong Zou . Structure and assembly mechanism of high-nuclear lanthanide-oxo clusters. Chinese Journal of Structural Chemistry, 2024, 43(9): 100372-100372. doi: 10.1016/j.cjsc.2024.100372
15. [15]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
16. [16]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
17. [17]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
18. [18]
  Tiantian Gong , Yanan Chen , Shuo Wang , Miao Wang , Junwei Zhao . Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties. Chinese Journal of Structural Chemistry, 2024, 43(9): 100370-100370. doi: 10.1016/j.cjsc.2024.100370
19. [19]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
20. [20]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(957)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142