Citation: Xingzi Zheng, Mengwei Yuan, Xianqiang Huang, Huifeng Li, Genban Sun. In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery[J]. Chinese Chemical Letters, ;2023, 34(1): 107152. doi: 10.1016/j.cclet.2022.01.045 shu

In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery

Xingzi Zheng ^a ,
Mengwei Yuan ^{a, c} ,
Xianqiang Huang ^b ,
Huifeng Li ^{a, *,} ,
Genban Sun ^a

a.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
b.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
c.
Department of Physics and Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China

lihuifeng@bnu.edu.cn

Received Date: 13 December 2021
Revised Date: 8 January 2022
Accepted Date: 16 January 2022
Available Online: 20 January 2022

Figures(4)

Application of Li-oxygen (Li-O₂) battery is in urgent need of bifunctional ORR/OER electrocatalyst. A surface-functionalization CoP/Ti₃C₂T_x composite was fabricated theoretically, with the optimized electronic structure and more active electron, which is beneficial to the electrochemical reaction. The accordion shaped Ti₃C₂T_x is featured with large specific surface area and outstanding electronic conductivity, which is beneficial for the adequate exposure of active sites and the deposition of Li₂O₂. Transition metal phosphides provide more electrocatalytic active sites and present good electrocatalytic effect. The CoP/Ti₃C₂T_x composite served as the electrocatalyst of Li-O₂ battery reaches a high specific discharge capacity of 17, 413 mAh/g at 100 mA/g and the lower overpotential of 1.25 V, superior to those of the CoP and Ti₃C₂T_x individually. The composite of transition metal phosphides and MXene are applied in Li-O₂ battery, not only demonstrating higher cycling stability of the prepared CoP/Ti₃C₂T_x composite, but pointing out the direction for their electrochemical performance improvement.
- MXene,
- Transition metal phosphide,
- Oxygen adsorption ability,
- Li-oxygen battery,
- Electrocatalyst
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In situ decoration of CoP/Ti3C2Tx composite as efficient electrocatalyst for Li-oxygen battery

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通讯作者: 陈斌, bchen63@163.com

In situ decoration of CoP/Ti₃C₂T_x composite as efficient electrocatalyst for Li-oxygen battery