Citation: Jinchuan Gu, Ping Yin, Yi Chen, Honglin Zhu, Rui Wang. A natural manganese ore as a heterogeneous catalyst to effectively activate peroxymonosulfate to oxidize organic pollutants[J]. Chinese Chemical Letters, ;2022, 33(11): 4792-4797. doi: 10.1016/j.cclet.2022.01.029 shu

A natural manganese ore as a heterogeneous catalyst to effectively activate peroxymonosulfate to oxidize organic pollutants

Jinchuan Gu ^a ,
Ping Yin ^b ,
Yi Chen ^{a, *,} ,
Honglin Zhu ^a ,
Rui Wang ^c

a.
School of Food and Bioengineering, Civil Engineering and Architecture and Environment, Emergency Science, Xihua University, Chengdu 610039, China
b.
Sichuan Rongxinkai Engineering Design Co., Ltd., Chengdu 610039, China
c.
Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu 611756, China

evechen1@163.com

Received Date: 14 October 2021
Revised Date: 4 December 2021
Accepted Date: 11 January 2022
Available Online: 16 January 2022

Figures(3)

Heterogeneous transition metal catalysts are indispensable in improving environmental pollution. However, their fabrication is often costly and cumbersome, and they can easily pollute the environment. This study proposed using a natural Gabonese ore (GBO) containing Mn_xO_y and Fe_xO_y as catalysts to degrade orange Ⅱ (OII) via peroxymonosulfate (PMS) activation. The GBO + PMS system exhibited extraordinarily high stability and catalytic activity towards OII elimination (92.2%, 0.0453 min⁻¹). The reactive oxygen species (ROS) generated in the system were identified using radical scavenging tests and electron spin-resonance (ESR) analysis. Singlet oxygen (¹O₂) represented the dominant reactive species for OII degradation, while the system presented a lower reaction energy barrier and was effective in a broad pH range (2–10). This work also proposed the activation mechanism for the GBO + PMS system and OII degradation pathways. This study revealed a new approach for exploring inexpensive, eco-friendly, efficient, and stable heterogeneous transition metal catalysts.
- Transition metal,
- Heterogeneous catalyst,
- Natural ore,
- Orange II,
- Peroxymonosulfate
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