Citation: Jingwen Jin, Jie Lin, Yipeng Huang, Linchun Zhang, Yaqi Jiang, Dongjie Tian, Fangyuan Lin, Yiru Wang, Xi Chen. High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor[J]. Chinese Chemical Letters, ;2022, 33(11): 4798-4802. doi: 10.1016/j.cclet.2022.01.017 shu

High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor

Jingwen Jin ^a ,
Jie Lin ^a ,
Yipeng Huang ^a ,
Linchun Zhang ^a ,
Yaqi Jiang ^a ,
Dongjie Tian ^a ,
Fangyuan Lin ^a ,
Yiru Wang ^a ,
Xi Chen ^{a, b, c, *,}

a.
Department of Chemistry and the MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
b.
State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China
c.
Shenzhen Research Institute of Xiamen University, Shenzhen 518000, China

xichen@xmu.edu.cn

Received Date: 28 October 2021
Revised Date: 1 December 2021
Accepted Date: 7 January 2022
Available Online: 14 January 2022

Figures(4)

A dual emission sensing film has been prepared for colorimetric temperature sensing using CsPbBr₃ perovskite nanocrystals (CsPbBr₃ NCs) and manganese doped potassium fluorosilicate (K₂SiF₆: Mn⁴⁺, KSF) encapsulated in polystyrene by a microencapsulation strategy. The CsPbBr₃-KSF-PS film shows good temperature sensing response from 30 ℃ to 70 ℃, with a relative temperature sensitivity (S_r) up to 10.31% ℃⁻¹ at 45 ℃. Meanwhile, the film maintains more than 95% intensity after 6 heating-cooling cycles and keeps its fluorescence characteristics after 3 months. The film can be used to monitor temperature change by naked eye under a UV lamp. In particular, the temperature discoloration point of the sensing film can be controlled by the ratio change of CsPbBr₃: KSF to expand its applications. The study of the CsPbBr₃-KSF-PS sensing mechanism in this work is helpful to provide effective strategies for the design of reliable, high sensitivity and stable temperature sensing system using CsPbBr₃ NCs.
- Ratiometric fluorescence sensing,
- High sensitivity,
- Perovskite nanocrystals,
- Temperature,
- Microencapsulation
1. [1]
  X. Zhu, J. Li, X. Qiu, et al., Nat. Commun. 9 (2018) 2176–2187. doi: 10.1038/s41467-018-04571-4
2. [2]
  T. Bai, N. Gu, Small 12 (2016) 4590–4610. doi: 10.1002/smll.201600665
3. [3]
  I.E. Kolesnikov, D.V. Mamonova, M.A. Kurochkin, E.Y. Kolesnikov, E. Lähderanta, J. Lumin. 231 (2021) 117828. doi: 10.1016/j.jlumin.2020.117828
4. [4]
  M.G. Nikolić, Ž. Antić, S. Ćulubrk, J.M. Nedeljković, M.D. Dramićanin, Sens. Actuators B: Chem. 201 (2014) 46–50. doi: 10.1016/j.snb.2014.04.108
5. [5]
  L. Tong, X. Li, J. Zhang, et al., Opt. Express 25 (2017) 16047–16058. doi: 10.1364/OE.25.016047
6. [6]
  H. Zheng, B. Chen, H. Yu, et al., J. Colloid Interface Sci. 420 (2014) 27–34. doi: 10.1016/j.jcis.2013.12.059
7. [7]
  H. Zheng, B. Chen, H. Yu, et al., Sens. Actuators B: Chem. 234 (2016) 286–293. doi: 10.1016/j.snb.2016.04.162
8. [8]
  S. Wang, J. Jiang, Y. Lu, et al., J. Lumin. 226 (2020) 117418. doi: 10.1016/j.jlumin.2020.117418
9. [9]
  Y. Park, C. Koo, H.Y. Chen, A. Han, D.H. Son, Nanoscale 5 (2013) 4944–4950. doi: 10.1039/c3nr00290j
10. [10]
  Y. Zhou, D. Zhang, J. Zeng, N. Gan, J. Cuan, Talanta 181 (2018) 410–415. doi: 10.1016/j.talanta.2018.01.024
11. [11]
  Q. Luo, H. Wang, X. Yin, L. Wang, Sci. China Mater. 62 (2019) 1065–1070. doi: 10.1007/s40843-018-9396-9
12. [12]
  P.C. Tsai, C.P. Epperla, J.S. Huang, et al., Angew. Chem. Int. Ed. 56 (2017) 3025–3030. doi: 10.1002/anie.201700357
13. [13]
  N. Rakov, S.A. Vieira, Q.P.S. Silva, G.S. Maciel, Sens. Actuators B: Chem. 209 (2015) 407–412. doi: 10.1016/j.snb.2014.11.119
14. [14]
  J. Liu, Y. Zhao, X. Li, et al., Cryst. Growth Des. 20 (2019) 454–459.
15. [15]
  X.D. Wang, X.H. Song, C.Y. He, et al., Anal. Chem. 83 (2011) 2434–2437. doi: 10.1021/ac200196y
16. [16]
  S. Xu, W. Ouyang, P. Xie, et al., Anal. Chem. 89 (2017) 1617–1623. doi: 10.1021/acs.analchem.6b03711
17. [17]
  C. Wang, T. Hu, T. Thomas, et al., Nanoscale 10 (2018) 21809–21817. doi: 10.1039/C8NR07445C
18. [18]
  J.S. Niezgoda, B.J. Foley, A.Z. Chen, J.J. Choi, ACS Energy Lett. 2 (2017) 1043–1049. doi: 10.1021/acsenergylett.7b00258
19. [19]
  Y. Wei, Z. Cheng, J. Lin, Chem. Soc. Rev. 48 (2019) 310–350. doi: 10.1039/C8CS00740C
20. [20]
  T.L. Doane, K.L. Ryan, L. Pathade, et al., ACS Nano 10 (2016) 5864–5872. doi: 10.1021/acsnano.6b00806
21. [21]
  X. Li, Y. Yu, J. Hong, et al., J. Lumin. 219 (2020) 116897. doi: 10.1016/j.jlumin.2019.116897
22. [22]
  L. Protesescu, S. Yakunin, M.I. Bodnarchuk, et al., Nano Lett. 15 (2015) 3692–3696. doi: 10.1021/nl5048779
23. [23]
  A. Swarnkar, R. Chulliyil, V.K. Ravi, et al., Angew. Chem. Int. Ed. 54 (2015) 15424–15428. doi: 10.1002/anie.201508276
24. [24]
  Q.A. Akkerman, V. D'Innocenzo, S. Accornero, et al., J. Am. Chem. Soc. 137 (2015) 10276–10281. doi: 10.1021/jacs.5b05602
25. [25]
  Y. Wang, J. He, H. Chen, et al., Adv. Mater. 28 (2016) 10710–10717. doi: 10.1002/adma.201603964
26. [26]
  B. Zhuang, Y. Liu, S. Yuan, et al., Nanoscale 11 (2019) 15010–15016. doi: 10.1039/C9NR05831A
27. [27]
  J. Guo, B. Zhou, C. Yang, Q. Dai, L. Kong, Adv. Funct. Mater. 29 (2019) 1902898. doi: 10.1002/adfm.201902898
28. [28]
  Y. Wang, J. He, H. Chen, et al., Adv. Mater. 28 (2016) 10710–10717. doi: 10.1002/adma.201603964
29. [29]
  B.T. Diroll, G. Nedelcu, M.V. Kovalenko, et al., Adv. Funct. Mater. 27 (2017) 1606750. doi: 10.1002/adfm.201606750
30. [30]
  X. Li, Y. Wu, S. Zhang, et al., Adv. Funct. Mater. 26 (2016) 2435–2445. doi: 10.1002/adfm.201600109
1. [1]
  Chenghe Yang , Yi Lü , Rui Liu . The Rise to Fame of Digital PCR. University Chemistry, 2025, 40(4): 340-345. doi: 10.12461/PKU.DXHX202406111
2. [2]
  Min Liu , Bin Feng , Feiyi Chu , Duoyang Fan , Fan Zheng , Fei Chen , Wenbin Zeng . An ESIPT-boosted NIR nanoprobe for ratiometric sensing of carbon monoxide via activatable aggregation-induced dual-color fluorescence. Chinese Chemical Letters, 2025, 36(5): 110043-. doi: 10.1016/j.cclet.2024.110043
3. [3]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
4. [4]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2023.100212
5. [5]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
6. [6]
  Shangda Qu , Yiming Yuan , Xu Ye , Wentao Xu . High sensitivity artificial synapses using printed high-transmittance ITO fibers for neuromorphic computing. Chinese Chemical Letters, 2024, 35(12): 110030-. doi: 10.1016/j.cclet.2024.110030
7. [7]
  Jiaqi Lin , Pupu Yang , Yimin Jiang , Shiqian Du , Dongcai Zhang , Gen Huang , Jinbo Wang , Jun Wang , Qie Liu , Miaoyu Li , Yujie Wu , Peng Long , Yangyang Zhou , Li Tao , Shuangyin Wang . Surface decoration prompting the decontamination of active sites in high-temperature proton exchange membrane fuel cells. Chinese Chemical Letters, 2024, 35(11): 109435-. doi: 10.1016/j.cclet.2023.109435
8. [8]
  Zhiqing Ge , Zuxiong Pan , Shuo Yan , Baoying Zhang , Xiangyu Shen , Mozhen Wang , Xuewu Ge . Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator. Chinese Chemical Letters, 2024, 35(11): 109850-. doi: 10.1016/j.cclet.2024.109850
9. [9]
  Meng Wang , Yan Zhang , Yunbo Yu , Wenpo Shan , Hong He . High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation. Chinese Chemical Letters, 2025, 36(1): 109928-. doi: 10.1016/j.cclet.2024.109928
10. [10]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
11. [11]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
12. [12]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
13. [13]
  Yunfa Dong , Shijie Zhong , Yuhui He , Zhezhi Liu , Shengyu Zhou , Qun Li , Yashuai Pang , Haodong Xie , Yuanpeng Ji , Yuanpeng Liu , Jiecai Han , Weidong He . Modification strategies for non-aqueous, highly proton-conductive benzimidazole-based high-temperature proton exchange membranes. Chinese Chemical Letters, 2024, 35(4): 109261-. doi: 10.1016/j.cclet.2023.109261
14. [14]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
15. [15]
  Tsegaye Tadesse Tsega , Jiantao Zai , Chin Wei Lai , Xin-Hao Li , Xuefeng Qian . Earth-abundant CuFeS2 nanocrystals@graphite felt electrode for high performance aqueous polysulfide/iodide redox flow batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100192-100192. doi: 10.1016/j.cjsc.2023.100192
16. [16]
  Weihong Ding , Kaiyue Song , Xianglong Li , Xiaoxia Sun . High-temperature-stable RRAMs with well-defined thermal effect mechanisms enable by engineering of robust 2D <100>-oriented organic-inorganic hybrid perovskites. Chinese Chemical Letters, 2025, 36(4): 110495-. doi: 10.1016/j.cclet.2024.110495
17. [17]
  Meiling Xu , Xinyang Li , Pengyuan Liu , Junjun Liu , Xiao Han , Guodong Chai , Shuangling Zhong , Bai Yang , Liying Cui . A novel and visible ratiometric fluorescence determination of carbaryl based on red emissive carbon dots by a solvent-free method. Chinese Chemical Letters, 2025, 36(2): 109860-. doi: 10.1016/j.cclet.2024.109860
18. [18]
  Ren Shen , Yanmei Fang , Chunxiao Yang , Quande Wei , Pui-In Mak , Rui P. Martins , Yanwei Jia . UV-assisted ratiometric fluorescence sensor for one-pot visual detection of Salmonella. Chinese Chemical Letters, 2025, 36(4): 110143-. doi: 10.1016/j.cclet.2024.110143
19. [19]
  Zhoupeng Zheng , Shengyi Gong , Qianhua Li , Shiya Zhang , Guoqiang Feng . Lipid droplets and gallbladder targeted fluorescence probe for ratiometric NO imaging in gallstones disease models. Chinese Chemical Letters, 2025, 36(5): 110191-. doi: 10.1016/j.cclet.2024.110191
20. [20]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(732)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr3 and K2SiF6: Mn4+ phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor