Citation: Xiaoyan Wang, Zhao Chen, Jun Yin, Sheng Hua Liu. Mononuclear aggregation-induced emission (AIE)-active gold(I)-isocyanide phosphors: Contrasting phosphorescent mechanochromisms and effect of halogen substitutions on room-temperature phosphorescence nature[J]. Chinese Chemical Letters, ;2022, 33(5): 2522-2526. doi: 10.1016/j.cclet.2021.12.030 shu

Mononuclear aggregation-induced emission (AIE)-active gold(I)-isocyanide phosphors: Contrasting phosphorescent mechanochromisms and effect of halogen substitutions on room-temperature phosphorescence nature

Xiaoyan Wang ^a ,
Zhao Chen ^{a, b, *,} ,
Jun Yin ^a ,
Sheng Hua Liu ^{a, c, *,}

a.
Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
b.
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

chenzhao666@126.com

chshliu@mail.ccnu.edu.cn

Received Date: 8 August 2021
Revised Date: 11 December 2021
Accepted Date: 13 December 2021
Available Online: 17 December 2021
Fund Project: the financial support from the National Natural Science Foundation of China 22175069the financial support from the National Natural Science Foundation of China 22061018the financial support from the National Natural Science Foundation of China 21702079the financial support from the National Natural Science Foundation of China 21772054the 111 Project B17019the Natural Science Foundation for Distinguished Young Scholars of Jiangxi Province 20212ACB213003the Academic and Technical Leader Plan of Jiangxi Provincial Main Disciplines 20212BCJ23004

Figures(5)

Developing phosphors with long-lifetime (millisecond scale or even longer) solid state room temperature phosphorescence (RTP) feature has attracted considerable attention. However, to date, stimuli-responsive phosphors with RTP nature are still rare due to the absence of effective guidelines for the exploitation of luminophors synchronously possessing stimuli-responsive and RTP characteristics. In this work, a series of mononuclear gold(I) complexes are reported. All these complexes exhibit various solid-state RTP properties, and phosphor 1-Cl exhibits long-lived RTP behavior. The effect of halogen atoms on the RTP nature of these complexes is investigated in detail. Furthermore, the introduction of different types of halogen atoms can effectively regulate the phosphorescent mechanochromism phenomena of these gold(I)-containing complexes. In addition, these phosphors display typical aggregation-induced emission (AIE) effect except for phosphor 5-CCl, which lacks hydrogen-bonding interactions compared with the other four phosphors. This work will be very helpful to the development of mechanical-force-responsive AIE phosphors with lasting RTP.
- Gold(I) complexes,
- Halogen atoms,
- Room temperature phosphorescence,
- Aggregation-induced emission,
- Phosphorescent mechanochromism
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