Citation: Xiaoyan Wang, Zhao Chen, Jun Yin, Sheng Hua Liu. Mononuclear aggregation-induced emission (AIE)-active gold(I)-isocyanide phosphors: Contrasting phosphorescent mechanochromisms and effect of halogen substitutions on room-temperature phosphorescence nature[J]. Chinese Chemical Letters, ;2022, 33(5): 2522-2526. doi: 10.1016/j.cclet.2021.12.030 shu

Mononuclear aggregation-induced emission (AIE)-active gold(I)-isocyanide phosphors: Contrasting phosphorescent mechanochromisms and effect of halogen substitutions on room-temperature phosphorescence nature

Xiaoyan Wang ^a ,
Zhao Chen ^{a, b, *,} ,
Jun Yin ^a ,
Sheng Hua Liu ^{a, c, *,}

a.
Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
b.
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
c.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

chenzhao666@126.com

chshliu@mail.ccnu.edu.cn

Received Date: 8 August 2021
Revised Date: 11 December 2021
Accepted Date: 13 December 2021
Available Online: 17 December 2021
Fund Project: the financial support from the National Natural Science Foundation of China 22175069the financial support from the National Natural Science Foundation of China 22061018the financial support from the National Natural Science Foundation of China 21702079the financial support from the National Natural Science Foundation of China 21772054the 111 Project B17019the Natural Science Foundation for Distinguished Young Scholars of Jiangxi Province 20212ACB213003the Academic and Technical Leader Plan of Jiangxi Provincial Main Disciplines 20212BCJ23004

Figures(5)

Developing phosphors with long-lifetime (millisecond scale or even longer) solid state room temperature phosphorescence (RTP) feature has attracted considerable attention. However, to date, stimuli-responsive phosphors with RTP nature are still rare due to the absence of effective guidelines for the exploitation of luminophors synchronously possessing stimuli-responsive and RTP characteristics. In this work, a series of mononuclear gold(I) complexes are reported. All these complexes exhibit various solid-state RTP properties, and phosphor 1-Cl exhibits long-lived RTP behavior. The effect of halogen atoms on the RTP nature of these complexes is investigated in detail. Furthermore, the introduction of different types of halogen atoms can effectively regulate the phosphorescent mechanochromism phenomena of these gold(I)-containing complexes. In addition, these phosphors display typical aggregation-induced emission (AIE) effect except for phosphor 5-CCl, which lacks hydrogen-bonding interactions compared with the other four phosphors. This work will be very helpful to the development of mechanical-force-responsive AIE phosphors with lasting RTP.
- Gold(I) complexes,
- Halogen atoms,
- Room temperature phosphorescence,
- Aggregation-induced emission,
- Phosphorescent mechanochromism
1. [1]
  D. Li, W. Chen, S.H. Liu, X. Chen, J. Yin, Chin. Chem. Lett. 31(2020) 2891-2896. doi: 10.1016/j.cclet.2020.02.047
2. [2]
  W.K. Kwok, M.C. Tang, S.L. Lai, et al., Angew. Chem. Int. Ed. 59(2020) 9684-9692. doi: 10.1002/anie.202001972
3. [3]
  X. Liang, Z.P. Yan, H.B. Han, et al., Angew. Chem. Int. Ed. 57(2018) 11316-11320. doi: 10.1002/anie.201806323
4. [4]
  Y. Sun, F. Ding, Z. Chen, et al., Proc. Natl. Acad. Sci. U. S. A. 116(2019) 16729-16735. doi: 10.1073/pnas.1908761116
5. [5]
  F. Ding, Z. Chen, W.Y. Kim, et al., Chem. Sci. 10(2019) 7023-7028. doi: 10.1039/C9SC02466B
6. [6]
  Z. Huang, Z. Bin, R. Su, et al., Angew. Chem. Int. Ed. 59(2020) 9992-9996. doi: 10.1002/anie.201915397
7. [7]
  L. Xu, J. Wang, Q. Luo, et al., Mater. Chem. Front. 4(2020) 2389-2397. doi: 10.1039/D0QM00215A
8. [8]
  Y. Yin, Z. Chen, C. Fan, G. Liu, S. Pu, ACS Omega 4(2019) 14324-14332. doi: 10.1021/acsomega.9b02110
9. [9]
  J. Luo, Z. Xie, J.W.Y. Lam, et al., Chem. Commun. (2001) 1740-1741.
10. [10]
  H. Lu, K. Wang, B. Liu, et al., Mater. Chem. Front. 3(2019) 331-338. doi: 10.1039/C8QM00543E
11. [11]
  F. Ren, J. Shi, B. Tong, Z. Cai, Y. Dong, Mater. Chem. Front. 3(2019) 2072-2076. doi: 10.1039/C9QM00372J
12. [12]
  H. Nie, K. Hu, Y. Cai, et al., Mater. Chem. Front. 1(2017) 1125-1129. doi: 10.1039/C6QM00343E
13. [13]
  M. Yamaguchi, S. Ito, A. Hirose, K. Tanaka, Y. Chujo, Mater. Chem. Front. 1(2017) 1573-1579. doi: 10.1039/C7QM00076F
14. [14]
  R. Zhang, Y. Duan, B. Liu, Nanoscale 11(2019) 19241-19250. doi: 10.1039/C9NR06012J
15. [15]
  S. Jiang, L. Meng, W. Ma, et al., Chin. Chem. Lett. 32(2021) 1037-1040. doi: 10.1016/j.cclet.2020.09.019
16. [16]
  W. Qiao, P. Yao, Y. Chen, et al., Mater. Chem. Front. 4(2020) 2688-2696. doi: 10.1039/D0QM00357C
17. [17]
  Y. Takeda, P. Data, S. Minakata, Chem. Commun. 56(2020) 8884-8894. doi: 10.1039/D0CC03322G
18. [18]
  W. Yang, Y. Yang, Y. Qiu, et al., Mater. Chem. Front. 4(2020) 2047-2053. doi: 10.1039/D0QM00247J
19. [19]
  Z. Chen, J. Zhang, M. Song, et al., Chem. Commun. 51(2015) 326-329. doi: 10.1039/C4CC08087D
20. [20]
  Z. Chen, Y. Yin, S. Pu, S.H. Liu, Dye. Pigment. 184(2021) 108814. doi: 10.1016/j.dyepig.2020.108814
21. [21]
  Y. Yin, Z. Chen, R.H. Li, et al., Inorg. Chem. 60(2021) 9387-9393. doi: 10.1021/acs.inorgchem.1c00233
22. [22]
  M. Yang, I.S. Park, Y. Miyashita, K. Tanaka, T. Yasuda, Angew. Chem. Int. Ed. 59(2020) 13955-13961. doi: 10.1002/anie.202005584
23. [23]
  Z. Chen, Y. Nie, S.H. Liu, RSC Adv. 6(2016) 73933-73938. doi: 10.1039/C6RA17806E
24. [24]
  F. Lin, Y. Feng, X. Liu, et al., Mater. Chem. Front. 4(2020) 1492-1499. doi: 10.1039/C9QM00783K
25. [25]
  S. Saotome, K. Suenaga, K. Tanaka, Y. Chujo, Mater. Chem. Front. 4(2020) 1781-1788. doi: 10.1039/C9QM00719A
26. [26]
  Z. Chen, J.H. Tang, W. Chen, et al., Organometallics 38(2019) 4244-4249. doi: 10.1021/acs.organomet.9b00544
27. [27]
  Q. Liao, Q. Gao, J. Wang, et al., Angew. Chem. Int. Ed. 59(2020) 9946-9951. doi: 10.1002/anie.201916057
28. [28]
  J. Wang, Z. Chai, J. Wang, et al., Angew. Chem. Int. Ed. 58(2019) 17297-17302. doi: 10.1002/anie.201911648
29. [29]
  Y. Xie, Y. Ge, Q. Peng, et al., Adv. Mater. 29(2017) 1606829. doi: 10.1002/adma.201606829
30. [30]
  T. Jadhav, B. Dhokale, S.M. Mobin, R. Misra, J. Mater. Chem. C 3(2015) 9981-9988. doi: 10.1039/C5TC02181B
31. [31]
  Y. Tani, M. Terasaki, M. Komura, T. Ogawa, J. Mater. Chem. C 7(2019) 11926-11931. doi: 10.1039/C9TC04176A
32. [32]
  Y. Dong, J. Zhang, A. Li, et al., J. Mater. Chem. C 8(2020) 894-899. doi: 10.1039/C9TC06297A
33. [33]
  X.Y. Wang, J. Zhang, Y.B. Dong, et al., Dye. Pigment. 156(2018) 74-81. doi: 10.1016/j.dyepig.2018.03.062
34. [34]
  Z. Chen, G. Liu, S. Pu, S.H. Liu, Dye. Pigment. 152(2018) 54-59. doi: 10.1016/j.dyepig.2018.01.036
35. [35]
  W. Qiu, P.A. Gurr, G. d. Silva, G.G. Qiao, Polym. Chem. 10(2019) 1650-1659. doi: 10.1039/C9PY00017H
36. [36]
  C.L. Anderson, N. Dai, S.J. Teat, et al., Angew. Chem. Int. Ed. 58(2019) 17978-17985. doi: 10.1002/anie.201908609
37. [37]
  J.X. Chen, J.Y. Wang, Q.C. Zhang, Z.N. Chen, Inorg. Chem. 56(2017) 13257-13266. doi: 10.1021/acs.inorgchem.7b02023
38. [38]
  X. Zhang, L.Y. Zhang, J.Y. Wang, F.R. Dai, Z.N. Chen, J. Mater. Chem. C 8(2020) 715-720. doi: 10.1039/C9TC05879F
39. [39]
  T. Lu, J.Y. Wang, D. Tu, et al., Inorg. Chem. 57(2018) 13618-13630. doi: 10.1021/acs.inorgchem.8b02217
40. [40]
  X.Y. Wang, Y.X. Hu, X.F. Yang, et al., Org. Lett. 21(2019) 9945-9949. doi: 10.1021/acs.orglett.9b03875
41. [41]
  K.Y. Zhao, H.T. Mao, L.L. Wen, et al., J. Mater. Chem. C 6(2018) 11686-11693. doi: 10.1039/C8TC03696A
42. [42]
  J. Li, L. Wang, Z. Zhao, et al., Angew. Chem. Int. Ed. 59(2020) 8210-8217. doi: 10.1002/anie.201916379
43. [43]
  W. Zhu, L. Fan, Dye. Pigment. 76(2008) 663-668. doi: 10.1016/j.dyepig.2007.01.003
44. [44]
  Z. Chen, G. Liu, S. Pu, S.H. Liu, Dye. Pigment. 143(2017) 409-415. doi: 10.1016/j.dyepig.2017.05.003
45. [45]
  Y. Dong, F. Zhu, Z. Chen, J. Yin, S.H. Liu, Mater. Chem. Front. 3(2019) 1866-1871. doi: 10.1039/C9QM00274J
46. [46]
  S. Cheng, Z. Chen, Y. Yin, Y. Sun, S. Liu, Chin. Chem. Lett. 32(2021) 3718-3732. doi: 10.1016/j.cclet.2021.05.049
47. [47]
  T. Seki, S. Kurenuma, H. Ito, Chem. Eur. J. 19(2013) 16214-16220. doi: 10.1002/chem.201303394
48. [48]
  N. Mirzadeh, S.H. Privér, A.J. Blake, H. Schmidbaur, S.K. Bhargava, Chem. Rev. 120(2020) 7551-7591. doi: 10.1021/acs.chemrev.9b00816
49. [49]
  X.Y. Wang, Y. Yin, J. Yin, Z. Chen, S.H. Liu, Dalton Trans. 50(2021) 7744-7749. doi: 10.1039/D1DT00959A
50. [50]
  J. Mei, N.L.C. Leung, R.T.K. Kwok, J.W.Y. Lam, B.Z. Tang, Chem. Rev. 115(2015) 11718-11940. doi: 10.1021/acs.chemrev.5b00263
51. [51]
  F. Würthner, T.E. Kaiser, C.R. Saha-Möller, Angew. Chem. Int. Ed. 50(2011) 3376-3410. doi: 10.1002/anie.201002307
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