Citation: Ran Cen, Ming Liu, Jihong Lu, Weifang Zhang, Jingjing Dai, Xi Zeng, Zhu Tao, Xin Xiao. Synthesis and characterization of a sensitive and selective Fe³⁺ fluorescent sensor based on novel sulfonated calix[4]arene-based host-guest complex[J]. Chinese Chemical Letters, ;2022, 33(5): 2469-2472. doi: 10.1016/j.cclet.2021.12.005 shu

Synthesis and characterization of a sensitive and selective Fe³⁺ fluorescent sensor based on novel sulfonated calix[4]arene-based host-guest complex

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

gyhxxiaoxin@163.com

Received Date: 24 July 2021
Revised Date: 30 November 2021
Accepted Date: 1 December 2021
Available Online: 7 December 2021

Figures(8)

A novel fluorescent sensor was prepared from sulfonated calix[4]arene (SC4A) by the host-guest complexation method using the fluorescent dye rhodamine B (RB) as a structure-directing agent. The crystal structure of the host-guest complex (RB@(SC4A)₃) was confirmed by X-ray diffraction studies while its performance and sensing mechanism for metal ion pollutants were characterized using fluorescence and nuclear magnetic resonance spectroscopies. The results showed that RB@(SC4A)₃ had a triangular branch structure resulting from host-guest mediation of the interactions between the three SC4A host molecules and the three terminal groups of the guest molecule RB. The host-guest complex exhibited sensitive and selective sensing towards Fe³⁺ ions via a fluorescence quenching mechanism. The results indicated that RB@(SC4A)₃ could be a promising sensitive and selective fluorescent sensor for metal ion pollutants monitoring. It also provided new insights into the synthesis of calixarene-based host-guest complex.
- Calixarenes,
- Rhodamine B,
- Metal ions,
- Fluorescence probe,
- Host-guest chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and characterization of a sensitive and selective Fe3+ fluorescent sensor based on novel sulfonated calix[4]arene-based host-guest complex

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通讯作者: 陈斌, bchen63@163.com

Synthesis and characterization of a sensitive and selective Fe³⁺ fluorescent sensor based on novel sulfonated calix[4]arene-based host-guest complex