Citation: Pusu Yang, Hui-Zhen Du, Xiang-Yu Zhang, Yong-Liang Xia, Jun-Tao Sun, Qian Peng, Bing-Tao Guan. Well-defined phosphate yttrium dialkyl complexes for catalytic stereo-controllable 1, 4-polymerization of isoprene[J]. Chinese Chemical Letters, ;2022, 33(5): 2402-2406. doi: 10.1016/j.cclet.2021.11.064 shu

Well-defined phosphate yttrium dialkyl complexes for catalytic stereo-controllable 1, 4-polymerization of isoprene

a.
College of Chemistry, Nankai University, Tianjin 300071, China
b.
Department of Chemistry, Fudan University, Shanghai 200438, China

bguan@fudan.edu.cn

Received Date: 23 July 2021
Revised Date: 15 November 2021
Accepted Date: 23 November 2021
Available Online: 27 November 2021

Figures(4)

Oxygen ligation is envisioned to provide a stable and distinctive coordination environment to the strongly oxophilic rare-earth metals. However, the well-defined dialkyl complexes bearing oxyanion ancillary ligand had been rarely addressed for the instability of the complexes and the shortage of easily available ligands. Herein, we report the synthesis of phosphate ligated dialkyl yttrium complexes (PYR₂) featuring a high stability and a tunable ligand. Treated with the borate reagent, the phosphate yttrium complex displays high activity and selectivity in the catalytic cis-1, 4-polymerization of isoprene (up to 96.5%). Furthermore, using AlMe₃ as an additive, the stereoselectivity switches to trans-1, 4-polymerization (up to 92.0%).
- Phosphate,
- Yttrium alkyls,
- Isoprene,
- Stereo-controllable,
- 1, 4-Polymerization
1. [1]
  E. Ceauşescu, Stereospecific Polymerization of Isoprene, 1st ed., Pergamon, Oxford, 1983.
2. [2]
  J. Song, B. Huang, D. Yu, J. Appl. Polym. Sci. 82 (2001) 81–89. doi: 10.1002/app.1826
3. [3]
  J.E. Puskas, E. Gautriaud, A. Deffieux, J.P. Kennedy, Prog. Polym. Sci. 31 (2006) 533–548. doi: 10.1016/j.progpolymsci.2006.05.002
4. [4]
  L. Porri, A. Giarrusso, 5-Conjugated diene polymerization, In: G. Allen, J.C. Bevington (Eds. ), Comprehensive Polymer Science and Supplements, Pergamon, Amsterdam, 1989, pp. 53–108.
5. [5]
  Z. Hou, Y. Wakatsuki, Coord. Chem. Rev. 231 (2002) 1–22. doi: 10.1016/S0010-8545(02)00111-X
6. [6]
  Z. Zhang, D. Cui, B. Wang, B. Liu, Y. Yang, Polymerization of 1, 3-conjugated dienes with rare-earth metal precursors. In: P.W. Roesky (Ed. ), Molecular Catalysis of Rare-Earth Elements, Springer Berlin Heidelberg, Berlin, Heidelberg, 2010, pp. 49–108.
7. [7]
  S. Arndt, K. Beckerle, P.M. Zeimentz, T.P. Spaniol, J. Okuda, Angew. Chem. Int. Ed. 44 (2005) 7473–7477. doi: 10.1002/anie.200502915
8. [8]
  L. Zhang, T. Suzuki, Y. Luo, M. Nishiura, Z. Hou, Angew. Chem. Int. Ed. 46 (2007) 1909–1913. doi: 10.1002/anie.200604348
9. [9]
  M. Zimmermann, N. Å. Frøystein, A. Fischbach, et al., Chem. Eur. J. 13 (2007) 8784–8800. doi: 10.1002/chem.200700534
10. [10]
  Y. Yang, B. Liu, K. Lv, et al., Organometallics 26 (2007) 4575–4584. doi: 10.1021/om7003095
11. [11]
  W. Gao, D. Cui, J. Am. Chem. Soc. 130 (2008) 4984–4991. doi: 10.1021/ja711146t
12. [12]
  K. Lv, D. Cui, Organometallics 29 (2010) 2987–2993. doi: 10.1021/om1002039
13. [13]
  D. Li, S. Li, D. Cui, X. Zhang, Organometallics 29 (2010) 2186–2193. doi: 10.1021/om100100r
14. [14]
  Y. Luo, S. Fan, J. Yang, J. Fang, P. Xu, Dalton Trans. 40 (2011) 3053–3059. doi: 10.1039/c0dt01241f
15. [15]
  Y. Pan, T. Xu, G. Yang, K. Jin, X. Lu, Inorg. Chem. 52 (2013) 2802–2808. doi: 10.1021/ic300976p
16. [16]
  J. Zhang, Z. Hao, W. Gao, et al., Chem. Asian J. 8 (2013) 2079–2087. doi: 10.1002/asia.201300581
17. [17]
  S. Sun, H. Ouyang, Y. Luo, et al., Dalton Trans. 42 (2013) 16355–16364. doi: 10.1039/c3dt52014e
18. [18]
  L. Li, C. Wu, D. Liu, S. Li, D. Cui, Organometallics 32 (2013) 3203–3209. doi: 10.1021/om400105t
19. [19]
  S. Liu, G. Du, J. He, et al., Macromolecules 47 (2014) 3567–3573. doi: 10.1021/ma500740m
20. [20]
  L. Guo, X. Zhu, S. Zhou, et al., Dalton Trans. 43 (2014) 6842–6847. doi: 10.1039/C4DT00242C
21. [21]
  L. Guo, X. Zhu, G. Zhang, et al., Inorg. Chem. 54 (2015) 5725–5731. doi: 10.1021/acs.inorgchem.5b00308
22. [22]
  M. Deng, S. Chi, Y. Luo, New J. Chem. 39 (2015) 7575–7581. doi: 10.1039/C5NJ00279F
23. [23]
  L. Shi, Q. Su, J. Chen, X. Li, Y. Luo, Dalton Trans. 45 (2016) 1391–1397. doi: 10.1039/C5DT03937A
24. [24]
  P. Zhang, H. Liao, H. Wang, et al., Organometallics 36 (2017) 2446–2451. doi: 10.1021/acs.organomet.7b00322
25. [25]
  M. Bonath, C.O. Hollfelder, D. Schädle, et al., Eur. J. Inorg. Chem. 2017 (2017) 4683–4692. doi: 10.1002/ejic.201700730
26. [26]
  C. Yu, P. Zhang, F. Gao, S. Zhang, X. Li, Polym. Chem. 9 (2018) 603–610. doi: 10.1039/C7PY01915G
27. [27]
  F. Bonnet, M. Visseaux, D. Barbier-Baudry, E. Vigier, M.M. Kubicki, Chem. Eur. J. 10 (2004) 2428–2434. doi: 10.1002/chem.200305595
28. [28]
  M. Zimmermann, K.W. Törnroos, R. Anwander, Angew. Chem. Int. Ed. 47 (2008) 775–778. doi: 10.1002/anie.200703514
29. [29]
  L. Annunziata, M. Duc, J. Carpentier, Macromolecules 44 (2011) 7158–7166. doi: 10.1021/ma2014595
30. [30]
  W. Rong, D. Liu, H. Zuo, et al., Organometallics 32 (2013) 1166–1175. doi: 10.1021/om300967h
31. [31]
  H. Liu, J. He, Z. Liu, et al., Macromolecules 46 (2013) 3257–3265. doi: 10.1021/ma4005549
32. [32]
  L.N. Jende, C. Maichle-Mössmer, R. Anwander, Chem. Eur. J. 19 (2013) 16321–16333. doi: 10.1002/chem.201302388
33. [33]
  S. Fadlallah, M. Terrier, C. Jones, et al., Organometallics 35 (2016) 456–461. doi: 10.1021/acs.organomet.5b00877
34. [34]
  L. Zhang, Y. Luo, Z. Hou, J. Am. Chem. Soc. 127 (2005) 14562–14563. doi: 10.1021/ja055397r
35. [35]
  G. Du, Y. Wei, L. Ai, et al., Organometallics 30 (2011) 160–170. doi: 10.1021/om100971d
36. [36]
  A.A. Kissel, D.M. Lyubov, T.V. Mahrova, et al., Dalton Trans. 42 (2013) 9211–9225. doi: 10.1039/c3dt33108c
37. [37]
  B. Liu, L. Li, G. Sun, et al., Macromolecules 47 (2014) 4971–4978. doi: 10.1021/ma501085c
38. [38]
  C. Yao, D. Liu, P. Li, et al., Organometallics 33 (2014) 684–691. doi: 10.1021/om400925a
39. [39]
  F. Kong, M. Li, X. Zhou, L. Zhang, RSC Adv. 7 (2017) 29752–29761. doi: 10.1039/C7RA04524G
40. [40]
  D. Diether, K. Tyulyunov, C. Maichle-Mössmer, R. Anwander, Organometallics 36 (2017) 4649–4659. doi: 10.1021/acs.organomet.7b00543
41. [41]
  F. Bonnet, C.E. Jones, S. Semlali, et al., Dalton Trans. 42 (2013) 790–801. doi: 10.1039/C2DT31624B
42. [42]
  Y. Yang, K. Lv, L. Wang, Y. Wang, D. Cui, Chem. Commun. 46 (2010) 6150–6152. doi: 10.1039/c0cc00297f
43. [43]
  R. Tanaka, K. Yuuya, H. Sato, et al., Polym. Chem. 7 (2016) 1239–1243. doi: 10.1039/C5PY01872B
44. [44]
  N.Y. Rad'Kova, A.O. Tolpygin, V.Y. Rad'Kov, et al., Dalton Trans. 45 (2016) 18572–18584. doi: 10.1039/C6DT03074B
45. [45]
  R. Tanaka, Y. Shinto, Y. Nakayama, T. Shiono, Catalysts7 (2017) 284. doi: 10.3390/catal7100284
46. [46]
  L. Zhang, M. Nishiura, M. Yuki, Y. Luo, Z. Hou, Angew. Chem., Int. Ed. 47 (2008) 2642–2645. doi: 10.1002/anie.200705120
47. [47]
  X. Yu, Q. You, X. Zhou, L. Zhang, ACS Catal. 8 (2018) 4465–4472. doi: 10.1021/acscatal.8b00600
48. [48]
  C. Döring, W.P. Kretschmer, R. Kempe, Eur. J. Inorg. Chem. 2010 (2010) 2853–2860. doi: 10.1002/ejic.201000097
49. [49]
  L. Wang, D. Liu, D. Cui, Organometallics 31 (2012) 6014–6021. doi: 10.1021/om300049h
50. [50]
  F. Chen, S. Fan, Y. Wang, J. Chen, Y. Luo, Organometallics 31 (2012) 3730–3735. doi: 10.1021/om3002119
51. [51]
  L. Luconi, D.M. Lyubov, A. Rossin, et al., Organometallics 33 (2014) 7125–7134. doi: 10.1021/om500918y
52. [52]
  B. Liu, G. Sun, S. Li, D. Liu, D. Cui, Organometallics 34 (2015) 4063–4068. doi: 10.1021/acs.organomet.5b00502
53. [53]
  J. Chen, Y. Gao, S. Xiong, et al., ACS Catal. 7 (2017) 5214–5219. doi: 10.1021/acscatal.7b01621
54. [54]
  G. Zhang, S. Wang, X. Zhu, et al., Organometallics 36 (2017) 3812–3822. doi: 10.1021/acs.organomet.7b00575
55. [55]
  A.A. Trifonov, D.M. Lyubov, Coord. Chem. Rev. 340 (2017) 10–61. doi: 10.1016/j.ccr.2016.09.013
56. [56]
  M. Nishiura, F. Guo, Z. Hou, Acc. Chem. Res. 48 (2015) 2209–2220. doi: 10.1021/acs.accounts.5b00219
57. [57]
  S. Arndt, J. Okuda, Adv. Synth. Catal. 347 (2005) 339–354. doi: 10.1002/adsc.200404269
58. [58]
  P.M. Zeimentz, S. Arndt, B.R. Elvidge, J. Okuda, Chem. Rev. 106 (2006) 2404–2433. doi: 10.1021/cr050574s
59. [59]
  F.T. Edelmann, Chem. Soc. Rev. 41 (2012) 7657–7672. doi: 10.1039/c2cs35180c
60. [60]
  M. Nishiura, Z. Hou, Nat. Chem. 2 (2010) 257–268. doi: 10.1038/nchem.595
61. [61]
  W.J. Evans, R.N.R. Broomhall-Dillard, J.W. Ziller, Organometallics 15 (1996) 1351–1355. doi: 10.1021/om9508400
62. [62]
  M.V. Butovskii, O.L. Tok, V. Bezugly, F.R. Wagner, R. Kempe, Angew. Chem. Int. Ed. 50 (2011) 7695–7698. doi: 10.1002/anie.201102363
63. [63]
  A. Lara-Sanchez, A. Rodriguez, D.L. Hughes, M. Schormann, M. Bochmann, J. Organomet. Chem. 663 (2002) 63–69. doi: 10.1016/S0022-328X(02)01657-1
64. [64]
  D.J.H. Emslie, W.E. Piers, M. Parvez, R. McDonald, Organometallics 21 (2002) 4226–4240. doi: 10.1021/om020382c
65. [65]
  S.C. Marinescu, T. Agapie, M.W. Day, J.E. Bercaw, Organometallics 26 (2007) 1178–1190. doi: 10.1021/om0608612
66. [66]
  G. Paolucci, M. Bortoluzzi, M. Napoli, P. Longo, J. Mol. Catal. A: Chem. 287 (2008) 121–127. doi: 10.1016/j.molcata.2008.03.009
67. [67]
  G. Paolucci, M. Bortoluzzi, S. Milione, A. Grassi, Inorg. Chim. Acta362 (2009) 4353–4357. doi: 10.1016/j.ica.2009.01.020
68. [68]
  N. Dettenrieder, H.M. Dietrich, C. Maichle-Mössmer, R. Anwander, Chem. Eur. J. 22 (2016) 13189–13200. doi: 10.1002/chem.201602424
69. [69]
  B.R. Elvidge, S. Arndt, T.P. Spaniol, J. Okuda, Dalton Trans. (2006) 890–901.
70. [70]
  S. Long, B. Wang, H. Xie, et al., New J. Chem. 39 (2015) 7682–7687. doi: 10.1039/C5NJ00737B
71. [71]
  P.L. Arnold, Z.R. Turner, R. Bellabarba, R.P. Tooze, J. Am. Chem. Soc. 133 (2011) 11744–11756. doi: 10.1021/ja204209t
72. [72]
  A. Fischbach, F. Perdih, E. Herdtweck, R. Anwander, Organometallics 25 (2006) 1626–1642. doi: 10.1021/om060052i
73. [73]
  C.S. Tredget, S.C. Lawrence, B.D. Ward, et al., Organometallics 24 (2005) 3136–3148. doi: 10.1021/om050209r
74. [74]
  W. Miao, S. Li, D. Cui, B. Huang, J. Organomet. Chem. 692 (2007) 3823–3834. doi: 10.1016/j.jorganchem.2007.05.032
75. [75]
  S. Ge, S. Bambirra, A. Meetsma, B. Hessen, Chem. Commun. (2006) 3320–3322. doi: 10.1039/b606384e
76. [76]
  W.J. Evans, D.G. Giarikos, J.W. Ziller, Organometallics 20 (2001) 5751–5758. doi: 10.1021/om010887n
77. [77]
  A. Fischbach, F. Perdih, P. Sirsch, W. Scherer, R. Anwander, Organometallics 21 (2002) 4569–4571. doi: 10.1021/om0205389
78. [78]
  W.J. Evans, D.G. Giarikos, Macromolecules 37 (2004) 5130–5132. doi: 10.1021/ma034925l
79. [79]
  D.M. Roitershtein, A.A. Vinogradov, A.A. Vinogradov, et al., Organometallics 32 (2013) 1272–1286. doi: 10.1021/om301020r
80. [80]
  P. Laubry, F. Barbotin, US20050130835 A1[P], 2006.
81. [81]
  R. Anwander, O. Nuyken, Neodymium Based Ziegler Catalysts: Fundamental Chemistry, Springer, Berlin, 2006.
82. [82]
  I.E. Nifant'Ev, A.N. Tavtorkin, A.V. Shlyahtin, et al., Dalton Trans. 42 (2013) 1223–1230. doi: 10.1039/C2DT31505J
83. [83]
  I.E. Nifant'ev, A.N. Tavtorkin, S.Y.A. Korchagina, et al., Appl. Catal. A478 (2014) 219–227. doi: 10.1016/j.apcata.2014.04.007
84. [84]
  S.K. Gupta, G.A. Bhat, R. Murugavel, Inorg. Chem. 56 (2017) 9071–9083. doi: 10.1021/acs.inorgchem.7b01100
85. [85]
  I. Carson, M.R. Healy, E.D. Doidge, et al., Coord. Chem. Rev. 335 (2017) 150–171. doi: 10.1016/j.ccr.2016.11.018
86. [86]
  H. Huang, J.Y. Kang, Org. Lett. 19 (2017) 5988–5991. doi: 10.1021/acs.orglett.7b03019
87. [87]
  C. Kutzbach, L. Jaenicke, J. LiebigsAnn. Chem. 692 (1966) 26–41. doi: 10.1002/jlac.19666920105
1. [1]
  Mengjia Luo , Yi Qiu , Zhengyang Zhou . Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446-100446. doi: 10.1016/j.cjsc.2024.100446
2. [2]
  Lingna Wang , Chenxin Tian , Ruobin Dai , Zhiwei Wang . Eco-friendly regeneration of end-of-life PVDF membrane with triethyl phosphate: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(9): 109356-. doi: 10.1016/j.cclet.2023.109356
3. [3]
  Xinxiu Yan , Xizhe Huang , Yangyang Liu , Weishang Jia , Hualin Chen , Qi Yao , Tao Chen . Hyperbranched polyamidoamine protective layer with phosphate and carboxyl groups for dendrite-free Zn metal anodes. Chinese Chemical Letters, 2024, 35(10): 109426-. doi: 10.1016/j.cclet.2023.109426
4. [4]
  Jumei Zhang , Ziheng Zhang , Gang Li , Hongjin Qiao , Hua Xie , Ling Jiang . Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes. Chinese Chemical Letters, 2025, 36(2): 110278-. doi: 10.1016/j.cclet.2024.110278
5. [5]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
6. [6]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
7. [7]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
8. [8]
  Guang Xu , Cuiju Zhu , Xiang Li , Kexin Zhu , Hao Xu . Copper-catalyzed asymmetric [4+1] annulation of yne–allylic esters with pyrazolones. Chinese Chemical Letters, 2025, 36(4): 110114-. doi: 10.1016/j.cclet.2024.110114
9. [9]
  Dongpu Wu , Zheng Yang , Yuchen Xia , Lulu Wu , Yingxia Zhou , Caoyuan Niu , Puhui Xie , Xin Zheng , Zhanqi Cao . Surface controllable wettability using amphiphilic rotaxane molecular shuttles. Chinese Chemical Letters, 2025, 36(2): 110353-. doi: 10.1016/j.cclet.2024.110353
10. [10]
  Yan Chen , Xinnan Wang , Yifan Lin , Chun Liu . Shape/dimension-controllable organic heterostructures from one monomer pair. Chinese Chemical Letters, 2025, 36(3): 109903-. doi: 10.1016/j.cclet.2024.109903
11. [11]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
12. [12]
  Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
13. [13]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
14. [14]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
15. [15]
  Jiao Chen , Zihan Zhang , Guojin Sun , Yudi Cheng , Aihua Wu , Zefan Wang , Wenwen Jiang , Fulin Chen , Xiuying Xie , Jianli Li . Benzo[4,5]imidazo[1,2-a]pyrimidine-based structure-inherent targeting fluorescent sensor for imaging lysosomal viscosity and diagnosis of lysosomal storage disorders. Chinese Chemical Letters, 2024, 35(11): 110050-. doi: 10.1016/j.cclet.2024.110050
16. [16]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
17. [17]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
18. [18]
  Yuqing Liu , Yu Yang , Yuhan E , Changlong Pang , Di Cui , Ang Li . Insight into microbial synthesis of metal nanomaterials and their environmental applications: Exploration for enhanced controllable synthesis. Chinese Chemical Letters, 2024, 35(11): 109651-. doi: 10.1016/j.cclet.2024.109651
19. [19]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
20. [20]
  Hongbin Liu , Putao Zhang . Effective approach to stabilize silicon anode: Controllable molecular construction of artificial solid electrolyte interphase. Chinese Journal of Structural Chemistry, 2025, 44(3): 100444-100444. doi: 10.1016/j.cjsc.2024.100444

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(994)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142