Citation: Liyun Huang, Hao Zhang, Yujie Cheng, Qingdi Sun, Tao Gan, Qian He, Xiaohui He, Hongbing Ji. Quasi-continuous synthesis of cobalt single atom catalysts for transfer hydrogenation of quinoline[J]. Chinese Chemical Letters, ;2022, 33(5): 2569-2572. doi: 10.1016/j.cclet.2021.10.004 shu

Quasi-continuous synthesis of cobalt single atom catalysts for transfer hydrogenation of quinoline

Liyun Huang ^{a, d, 1} ,
Hao Zhang ^{a, 1} ,
Yujie Cheng ^a ,
Qingdi Sun ^a ,
Tao Gan ^a ,
Qian He ^{a, *} ,
Xiaohui He ^{a, b} ,
Hongbing Ji ^{a, b, c, *}

a.
Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
b.
Huizhou Research Institute of Sun Yat-sen University, Huizhou 516216, China
c.
School of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
d.
School of Environmental and Chemical Engineering, Foshan University, Foshan 528000, China

heqian27@mail.sysu.edu.cn

jihb@mail.sysu.edu.cn

Received Date: 31 July 2021
Revised Date: 19 September 2021
Accepted Date: 4 October 2021
Available Online: 8 October 2021

Figures(3)

Improving the transfer hydrogenation of N-heteroarenes is of key importance for various industrial processes and remains a challenge so far. We reported here a microcapsule-pyrolysis strategy to quasi-continuous synthesis S, N co-doped carbon supported Co single atom catalysts (Co/SNC), which was used for transfer hydrogenation of quinoline with formic acid as the hydrogen donor. Given the unique geometric and electronic properties of the Co single atoms, the excellent catalytic activity, selectivity and stability were observed. Benefiting from the quasi-continuous synthesis method, the as-obtained catalysts provide a reference for the large-scale preparation of single atom catalysts without amplification effect. Highly catalytic performances and quasi-continuous preparation process, demonstrating a new and promising approach to rational design of atomically dispersed catalysts with maximum atomic efficiency in industrial.
- Quasi-continuous synthesis,
- Single atom catalysts,
- Microcapsule,
- Transfer hydrogenation,
- Quinoline
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