Citation: Kaidi Xu, Zhi-Yuan Zhang, Zihao Zhou, Chunju Li. Prospering the biphen[n]arenes family by tailoring reaction modules[J]. Chinese Chemical Letters, ;2022, 33(5): 2451-2454. doi: 10.1016/j.cclet.2021.09.096 shu

Prospering the biphen[n]arenes family by tailoring reaction modules

Kaidi Xu ^{a, b} ,
Zhi-Yuan Zhang ^{b, *,} ,
Zihao Zhou ^a ,
Chunju Li ^{b, *,}

a.
College of Science, Center for Supramolecular Chemistry and Catalysis, Shanghai University, Shanghai 200444, China
b.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

zzy@tjnu.edu.cn

cjli@shu.edu.cn

Received Date: 7 August 2021
Revised Date: 27 September 2021
Accepted Date: 27 September 2021
Available Online: 2 October 2021

Figures(8)

Reported here is the comprehensive investigation on the formation of biphen[n]arenes by tailoring reaction modules. Five new macrocyclic arenes and four oligomers were synthesized by the condensation of monomers possessing different multimethoxyphenyl reaction modules and paraformaldehyde. We proved that the number and sites of methoxy on reaction modules greatly affected the reaction activity, shape, and connection mode of macrocycles. Moreover, the triangular and saddle-shaped configuration of macrocycles were revealed by single crystal structures. The results provided a typical and fundamental guidance in designing new macrocyclic arenes.
- Biphen[n]arenes,
- Macrocyclic arenes,
- Synthetic receptors,
- Supramolecular chemistry
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