Citation: Qian Wang, Hongrui Tian, Zhong Zhang, Tianyi Dang, Wanyu Zhang, Jie Wang, Ying Lu, Shuxia Liu. Keggin-type polycationic AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺ intercalated MoO₃ composites for methyl orange adsorption[J]. Chinese Chemical Letters, ;2022, 33(5): 2617-2620. doi: 10.1016/j.cclet.2021.09.079 shu

Keggin-type polycationic AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺ intercalated MoO₃ composites for methyl orange adsorption

Qian Wang ^{a, 1} ,
Hongrui Tian ^{b, 1} ,
Zhong Zhang ^a ,
Tianyi Dang ^a ,
Wanyu Zhang ^a ,
Jie Wang ^a ,
Ying Lu ^a ,
Shuxia Liu ^{a, *,}

a.
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, China
b.
Department of Chemistry and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, China

liusx@nenu.edu.cn

Received Date: 2 September 2021
Revised Date: 20 September 2021
Accepted Date: 23 September 2021
Available Online: 29 September 2021

Figures(3)

Molybdenum trioxide (MoO₃) can be employed as an excellent host for intercalation due to its 2D layered structure that connected by van der Waals interactions. Herein, a series of polyoxometalate-based MoO₃ composites (Al₁₃@MoO₃) were successfully prepared by interpolating the Keggin-type polycationic AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺ (Al₁₃) into MoO₃ gallery. These composites can be applied to rapidly adsorb the anionic dye methyl orange (MO) through strong electrostatic interactions lead to compact and stable gathering in the surrounding of the numerous charged Al₁₃. Adsorption behaviors of composites with the different amount of Al₁₃ were determined, these results revealed that Al₁₃-3.34%@MoO₃ exhibited the most remarkable adsorption capacity. More importantly, the composite maintains superior adsorption capacity for five consecutive adsorption/desorption cycles, suggesting that Al₁₃@MoO₃ can be an efficient and durable adsorbent.
- MoO₃,
- Keggin-type polycationic AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺,
- Intercalation,
- Adsorption,
- Methyl orange dye
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通讯作者: 陈斌, bchen63@163.com

Keggin-type polycationic AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺ intercalated MoO₃ composites for methyl orange adsorption