Citation: Pengfei Sun, Huijia Yu, Tingting Liu, Yingshuang Li, Zhongsen Wang, Yufei Xiao, Xiaoping Dong. Efficiently photothermal conversion in a MnO_x-based monolithic photothermocatalyst for gaseous formaldehyde elimination[J]. Chinese Chemical Letters, ;2022, 33(5): 2564-2568. doi: 10.1016/j.cclet.2021.09.050 shu

Efficiently photothermal conversion in a MnO_x-based monolithic photothermocatalyst for gaseous formaldehyde elimination

Department of Chemistry, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China

xpdong@zstu.edu.cn

Received Date: 9 August 2021
Revised Date: 8 September 2021
Accepted Date: 13 September 2021
Available Online: 20 September 2021

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Volatile organic compound (VOC) pollution has a serious impact on human and urgently needs to be controlled through the development of new methods and catalytic materials. Compared with traditional thermal catalytic oxidation, the synergistic photothermocatalysis is regarded as a green and environmentally friendly strategy for organic compound pollutant removal, which can promote spontaneous heating of the surface of catalysts to achieve thermal catalytic reaction conditions via harvesting light irradiation. In this paper, a monolithic photothermocatalyst was synthesized through coating graphene oxide (GO) and MnOx in turn on a commercially available melamine sponge, where the GO mainly acted as a photothermal conversion layer to heat the catalytically active MnO_x. This monolithic catalyst presented excellent photo-induced activity for formaldehyde elimination under ambient conditions (~90% degradation ratio in 20 min for ~160 ppm initial concentration formaldehyde), and meanwhile possessed a high catalytic durability for multiple cycles. The kinetic study demonstrated that this photothermocatalytic process followed a pseudo-second-order kinetics. Finally, we proposed a possible formaldehyde degradation pathway based on in situ DRIFTS examination.
- Photothermal catalytic,
- Melamine sponge,
- Graphene oxide,
- MnO_x,
- Formaldehyde
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沈阳化工大学材料科学与工程学院沈阳 110142

Efficiently photothermal conversion in a MnOx-based monolithic photothermocatalyst for gaseous formaldehyde elimination

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通讯作者: 陈斌, bchen63@163.com

Efficiently photothermal conversion in a MnO_x-based monolithic photothermocatalyst for gaseous formaldehyde elimination