Citation: Wenying Mi, Na Shao. Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials[J]. Chinese Chemical Letters, ;2022, 33(1): 298-303. doi: 10.1016/j.cclet.2021.06.039 shu

Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials

Wenying Mi ,
Na Shao ^*,

College of Chemistry, Beijing Normal University, Beijing 100875, China

shaona@bnu.edu.cn

Received Date: 6 March 2021
Revised Date: 6 April 2021
Accepted Date: 14 June 2021
Available Online: 25 June 2021

Figures(9)

White-light-emitting diodes (WLEDs) possess many merits, such as high efficiency and stability. Developing cost-effective, environmentally friendly, high-performance luminophores to achieve high-quality, full-spectrum, white lighting is of great importance to the construction and progress of WLEDs. In this work, solid-state, highly luminescent orange-emitting nanoclusters (MgCl₂-Lys-Ag/Au NCs) were prepared via the salt-induced precipitation of Lys-Ag/Au NCs from solution, which showed a high absolute quantum yield of 44.5%. A cyan-emitting metal-organic framework (MOF)-like nanomaterial (named Fe@TAOH) was also prepared by the self-assembly of the coordination compound of Fe³⁺ and TAOH acted upon by H₃PO₄ via H-bonding and π-π stacking interactions, which showed an emission peak at 485 nm and an absolute quantum yield of 21.7%. The potential application of the two facile-synthesis, low toxicity, and highly luminescent materials in WLEDs was investigated. The WLEDs was constructed by coating powdered Fe@TAOH and MgCl₂-Lys-Ag/Au NCs samples on commercial GaN LED chip with 365 nm emissions, and it exhibited acceptable white light characteristics with a CIE color coordinates and a color rendering index (CRI) of (0.28, 0.34) and 79.6, respectively, implying good prospects in the field of WLEDs.
- Metal nanoclusters,
- Salt-mediated precipitation,
- Fe@TAOH MOFs,
- Self-assembly,
- White light-emitting materials
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