Citation: Qianqian Yang, Zhiyuan Feng, Mingyue Liu, Jinxing Zhang, Hongying Zhao, Guohua Zhao. A general strategy via photoelectrocatalytic oxygen reduction for generating singlet oxygen with carbon bridged carbon-nitride electrode[J]. Chinese Chemical Letters, ;2021, 32(11): 3393-3397. doi: 10.1016/j.cclet.2021.05.066 shu

A general strategy via photoelectrocatalytic oxygen reduction for generating singlet oxygen with carbon bridged carbon-nitride electrode

School of Chemical Science and Engineering, and Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, Shanghai 200092, China

hyzhao@tongji.edu.cn

Received Date: 8 February 2021
Revised Date: 20 April 2021
Accepted Date: 27 May 2021
Available Online: 1 June 2021

Figures(4)

With the ever-growing demand of clean water for the healthy world, water purification has become an urgent global issue. Singlet oxygen (¹O₂) as unique non-radical derivative of oxygen, possessing unoccupied π^* orbital and exhibiting high selectivity towards electron-rich organic pollutants. Nevertheless, most of the approaches suffer from low-efficiency or biotoxicity, which severely restrict their potential applications. Therefore, in this work, we propose a general strategy via photoelectrocatalytic for selectively reducing oxygen to ¹O₂ with designed carbon bridged carbon nitride (CBCN). This work highlights the important role of synergistic photo-electro-catalytic effect for selectively generating the ¹O₂ via oxygen reduction pathway, which can be a promising way especially for degrading electron-rich pollutants.
- Oxygen reduction reaction,
- Singlet oxygen,
- Photoelectrocatalytic process,
- Carbon-nitride,
- Wastewater treatment
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