Citation: Peipei Jiang, Tingting Zhao, Jian Rong, Bangshao Yin, Yutao Rao, Mingbo Zhou, Ling Xu, Jianxin Song. Multi-(phenylthio)porphyrinato Ni(Ⅱ) compounds: Synthesis, structures and properties[J]. Chinese Chemical Letters, ;2021, 32(8): 2562-2566. doi: 10.1016/j.cclet.2021.02.022 shu

Multi-(phenylthio)porphyrinato Ni(Ⅱ) compounds: Synthesis, structures and properties

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China

xulingchem@hunnu.edu.cn

jxsong@hunnu.edu.cn

Received Date: 24 December 2020
Revised Date: 2 February 2021
Accepted Date: 10 February 2021
Available Online: 15 February 2021

Figures(4)

A series of multi-(phenylthio)porphyrinato Ni(ò) compounds were synthesized without the participation of transition metal catalysts. All of these products were well characterized by ¹H NMR, ¹³C NMR and HRMS. Structures of three typical compounds were further confirmed by X-ray single crystal diffraction. Remarkable red shifts were observed in UVɃvis absorption spectra of multi-(phenylthio)porphyrinato Ni(ò) compounds which meet well with the electrochemical data. DFT calculation indicates that the phenylthio groups have strong effects on the frontier orbitals of these molecules. The order of a_1u-like and a_2u-like orbitals mainly distributed in porphyrin moiety is often inversed in energy when multi-phenylthio groups are attached.
- Phenylthio,
- Porphyrin,
- S_NAr reaction,
- a_1u/a_2u orbital
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