Citation: Xusheng Gao, Liduo Zhao, Meijuan Ding, Xiaozu Wang, Lu Zhai, Xiaoming Ren. Insight understanding into influence of binding mode of carboxylate with metal ion on ligand-centered luminescence properties in Pb-based coordination polymers[J]. Chinese Chemical Letters, ;2021, 32(8): 2423-2426. doi: 10.1016/j.cclet.2021.01.015 shu

Insight understanding into influence of binding mode of carboxylate with metal ion on ligand-centered luminescence properties in Pb-based coordination polymers

Xusheng Gao ^a ,
Liduo Zhao ^a ,
Meijuan Ding ^a ,
Xiaozu Wang ^{b, *,} ,
Lu Zhai ^a ,
Xiaoming Ren ^{a, c, d, **,}

a.
State Key Laboratory of Materials–Oriented Chemical Engineering and College of Chemistry & Molecular Engineering, Nanjing Tech University, Nanjing 211816, China
b.
College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
c.
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
d.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

wangxiaozu@njtech.edu.cn

xmren@njtech.edu.cn

Received Date: 14 December 2020
Revised Date: 3 January 2021
Accepted Date: 8 January 2021
Available Online: 13 January 2021

Figures(4)

In the crystal engineering area, it is important to clearly demonstrating the relationship of structure and certain functionality. Herein, we present the study of the relationship of structure with phosphorescent nature for two new room temperature phosphorescence (RTP) coordination polymers (CPs). [Pb(FDA)(H₂O)] (1) and [NH₃(CH₃)NH₂(CH₃)₂][Pb₄(FDA)₅] (2), where H₂FDA is 2, 5-furandicarboxylic acid, have been synthesized by solvothermal method using different solvents and Pb²⁺ sources and characterized by microanalysis, powder X-ray diffraction (PXRD), thermogravimetric (TG), IR and UV–vis spectra. The Pb²⁺ ions adopt bicapped triangle prism coordination sphere in 1 and 2, which are connected together via FDA²⁻ ligands into bilayer structure in 1 while pillared-layer framework in 2. The FDA²⁻ ligands show different bridging modes in 1 and 2, leading to distinct coordination interactions between Pb²⁺ ion and FDA²⁻ ligand in both CPs. Both 1 and 2 emit ligand-centered RTP due to the heavy atom of Pb²⁺ ion, with a lifetime and quantum yield of 0.62 ms and 14.9% in 1 versus 1.69 ms and 15.7% in 2. The emission peak shows significant redshift (79 nm) in 2 regarding 1, which arises from their distinction of coordination interactions between Pb²⁺ ion and FDA²⁻ ligand in both CPs.
- Pb-based coordination polymer,
- Carboxylate binding mode,
- Heavy atom effect,
- Room temperature phosphorescence,
- Frontier orbital analysis
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