Citation: Junjie Yang, Junxian Qin, Ziyang Guo, Yun Hu, Xia Zhang. Zn-based metal organic framework derivative with uniform metal sites and hierarchical pores for efficient adsorption of formaldehyde[J]. Chinese Chemical Letters, ;2021, 32(5): 1819-1822. doi: 10.1016/j.cclet.2020.11.023 shu

Zn-based metal organic framework derivative with uniform metal sites and hierarchical pores for efficient adsorption of formaldehyde

Junjie Yang ^a ,
Junxian Qin ^a ,
Ziyang Guo ^a ,
Yun Hu ^{a, b, c, *,} ,
Xia Zhang ^d

a.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
b.
Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, China
c.
The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, China
d.
Zhejiang Tianchuan Environmental Science & Technology Co., Ltd., Hangzhou 310015, China

huyun@scut.edu.cn

Received Date: 15 August 2020
Revised Date: 10 October 2020
Accepted Date: 17 November 2020
Available Online: 20 November 2020

Figures(3)

A Zn-containing graphite carbon (Zn-GC) with uniform Zn metal sites and hierarchical pore structure was obtained by pyrolysis of Zn-based metal organic framework (MOF). Zn-GC exhibited excellent adsorption capacity and reproducibility for formaldehyde. The adsorption capacity of Zn-GC was 736 times that of commercial activated carbon and 5.6 times that of ZSM-5 adsorbents. The characterization and experimental results showed that the surface chemical characteristics of the adsorption material play an important role in the adsorption performance. The superior performance was attributed to Zn metal sites and oxygen-containing functional groups on the MOF derivative as well as hierarchical pore structure. The material showed a great potential in the field of organic pollutant removal.
- Formaldehyde,
- Adsorption,
- Hierarchical Pore,
- MOF-derivative,
- Carbon
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