Citation: Guanyu Tao, Feichao Yang, Lujun Zhang, Yang Li, Zheng Duan, François Mathey. Synthesis of phosphanaphthalenes and nido-carborane fused six-membered phosphacycles[J]. Chinese Chemical Letters, ;2021, 32(1): 194-197. doi: 10.1016/j.cclet.2020.11.018 shu

Synthesis of phosphanaphthalenes and nido-carborane fused six-membered phosphacycles

College of Chemistry, Green Catalysis Center, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China

duanzheng@zzu.edu.cn

Received Date: 21 September 2020
Revised Date: 4 November 2020
Accepted Date: 9 November 2020
Available Online: 11 November 2020

Figures(10)

A simple method to synthesize luminescent λ⁵-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoalde-hydes or ortho-phosphinocarboranylaldehydes with an electron-deficient alkyne, respectively. Similar results were obtained with the imino analogues.
- Phosphorus,
- λ⁵-Phosphanaphthalenes,
- Zwitterionic,
- nido-Carborane,
- Electron-deficient alkyne
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