Citation: Minzan Zuo, Weirui Qian, Min Hao, Kaiya Wang, Xiao-Yu Hu, Leyong Wang. An AIE singlet oxygen generation system based on supramolecular strategy[J]. Chinese Chemical Letters, ;2021, 32(4): 1381-1384. doi: 10.1016/j.cclet.2020.09.033 shu

An AIE singlet oxygen generation system based on supramolecular strategy

Minzan Zuo ^a ,
Weirui Qian ^b ,
Min Hao ^b ,
Kaiya Wang ^a ,
Xiao-Yu Hu ^{a, *,} ,
Leyong Wang ^b

a.
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China
b.
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

huxy@nuaa.edu.cn

Received Date: 3 August 2020
Revised Date: 7 September 2020
Accepted Date: 21 September 2020
Available Online: 22 September 2020

Figures(5)

The design of supramolecular systems with efficient singlet oxygen generation has attracted considerable interests. Herein, an AIE-based singlet oxygen generation system with chemiluminescence properties is reported in aqueous media based on supramolecular host-guest assembly between a water-soluble pillar[5]arene (WP5) and an AIE photosensitizer (TPEDM). The formed supramolecular nanoparticles exhibit significant singlet oxygen generation ability as well as enhanced fluorescence. In addition, by introducing catalase, this H₂O₂-responsive supramolecular system shows increased ¹O₂ generation efficiency compared with the blank nanoparticles. An efficient chemiluminescence system can also be achieved by entrapping an energy donor adamantane derivative (AMPPD). Moreover, the present system can function as nanoreactors to perform the photooxidation of dopamine to form polydopamine with visible light irradiation. This work provides a new strategy for the construction of ¹O₂ generation system based on supramolecular nanomaterials, which has potential applications in the fields such as chemiluminescence imaging and controlled photocatalysis.
- Aggregation-induced emission,
- Singlet oxygen,
- Self-assembly,
- Chemiluminescence,
- Photocatalysis
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