Citation: Yanzhen Huang, Chao Pi, Zhen Tang, Yangjie Wu, Xiuling Cui. Cp^*Co(Ⅲ)-catalyzed C-H amidation of azines with dioxazolones[J]. Chinese Chemical Letters, ;2020, 31(12): 3237-3240. doi: 10.1016/j.cclet.2020.08.046 shu

Cp^*Co(Ⅲ)-catalyzed C-H amidation of azines with dioxazolones

Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, College of Chemistry, Green Catalysis Center, Zhengzhou University, Zhengzhou 450052, China

pichao@zzu.edu.cn

cuixl@zzu.edu.cn

Received Date: 3 July 2020
Revised Date: 6 August 2020
Accepted Date: 26 August 2020
Available Online: 30 August 2020

Figures(5)

Cp^*Co(Ⅲ)-catalyzed direct C-H amidation of azines has been developed. This conversion could proceed smoothly in the absence of external oxidants, acids or bases, with excellent regioselectivity and broad functional group tolerance. CO₂ was released as the sole byproduct, thus providing an environmentally benign amidation process. The products obtained are important intermediates in organic synthesis.
- Cp^*Co(Ⅲ)-catalyzed,
- Azines,
- Amidation,
- Dioxazolone
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沈阳化工大学材料科学与工程学院沈阳 110142

Cp*Co(Ⅲ)-catalyzed C-H amidation of azines with dioxazolones

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通讯作者: 陈斌, bchen63@163.com

Cp^*Co(Ⅲ)-catalyzed C-H amidation of azines with dioxazolones