Citation: Hailiang Hu, Huan Yang, Xiuyan Yang, Ran Wang, Lan Zhou, Yi Dai, Ningning Ji, Huanjiang Wang, Zhiqiang Shi, Guoyong Zhou, Baokuan Chen, Yingchun Luo, Chaozheng He. Copper-sulfide cluster assembled architecture via in situ reaction[J]. Chinese Chemical Letters, ;2020, 31(12): 3213-3215. doi: 10.1016/j.cclet.2020.08.025 shu

Copper-sulfide cluster assembled architecture via in situ reaction

Hailiang Hu ^{a, *,} ,
Huan Yang ^a ,
Xiuyan Yang ^a ,
Ran Wang ^d ,
Lan Zhou ^a ,
Yi Dai ^a ,
Ningning Ji ^b ,
Huanjiang Wang ^a ,
Zhiqiang Shi ^{b, *,} ,
Guoyong Zhou ^a ,
Baokuan Chen ^{c, *,} ,
Yingchun Luo ^a ,
Chaozheng He ^{d, *,}

a.
Cllege of Chemical Engineering, Guizhou Minzu University, Guiyang 550025, China
b.
College of Chemistry and Chemical Engineering, Taishan University, Tai'an 271021, China
c.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
d.
Shaanxi KeyLaboratory of Optoelectronic Functional Materials and Devices, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China

hlhu@gzmu.edu.cn

kobeecho@163.com

chenbaokuan@lnpu.edu.cn

hecz2019@xatu.edu.cn

Received Date: 15 June 2020
Revised Date: 21 July 2020
Accepted Date: 17 August 2020
Available Online: 19 August 2020

Figures(3)

A new copper-thiolate cluster assembled framework [Cu₂(μ₄-SCH₃)Cl]_n (1), has been solvothermally synthesized through in situ reaction viz., in situ ligand generation and metal reduction. Compound 1 represents the first 3D framework based on Atlas-sphere functionalized by single μ₂-Cl^- groups. DOS calculation reveals the interaction of electronic structures. It is found that the HOMO is mainly distributed on Cl, Cu and S bonding orbitals, while the LUMO is dominated by Cu-Cl antibonding orbitals.
- Chalcogenide,
- Cluster,
- In situ,
- Assemble,
- Architecture
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