Citation: Liu Yang, Shaohua Luo, Yafeng Wang, Yang Zhan, Qing Wang, Yahui Zhang, Xin Liu, Wenning Mu, Fei Teng. Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance[J]. Chinese Chemical Letters, ;2020, 31(12): 3200-3204. doi: 10.1016/j.cclet.2020.05.036 shu

Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance

Liu Yang ^{a, b, c} ,
Shaohua Luo ^{b, c, d, *,} ,
Yafeng Wang ^{a, b, c} ,
Yang Zhan ^{a, b, c} ,
Qing Wang ^{b, c, d, *,} ,
Yahui Zhang ^{b, c, d} ,
Xin Liu ^{a, b, c, d} ,
Wenning Mu ^{b, d} ,
Fei Teng ^{b, d}

a.
School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
b.
School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, China
c.
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, Qinhuangdao 066004, China
d.
Qinhuangdao Laboratory of Resources Cleaner Conversion and Efficient Utilization, Qinhuangdao 066004, China

tianyanglsh@163.com

wangswork@126.com

Received Date: 12 March 2020
Revised Date: 16 May 2020
Accepted Date: 24 May 2020
Available Online: 26 May 2020

Figures(4)

Li₂FeTiO₄ composites have been produced using commercial LiAC, FeCl₂ and different titanium sources by hydrothermal synthesis (HS) at 175 ℃ and subsequent annealing at 700 ℃. Impure phase TiO₂, Fe₂O₃ and FeTiO₄ were detected out among the Li₂FeTiO₄ composites with different titanium sources. Micron and nano-sized particles of Li₂FeTiO₄ were prepared from various titanium raw materials, with nano-sized particles predominating when titanium raw materials were layered hydrogen titanate nanowire (H₂Ti₃O₇NW, HTO-NW) and titanium oxide nanotubes (TiO₂NB). The Li₂FeTiO₄ composites synthesized by HTO-NW shows a primary particle size of 50-200 nm of high crystallinity staggered with undissolved nanowire with a diameter size of about 100 nm. The samples using one-dimensional nanometer titanium oxide (TiO₂ NB) as the raw material can get a super high initial discharge capacity of 367.8 mAh/g at the rate of C/10 and excellent cycling stability. The selection of raw materials and adopting multi-phase modification can be considered as an effective strategy to improve the electro-chemical properties of Li₂FeTiO₄ composite cathode materials for the lithium secondary battery.
- Li₂FeTiO₄ nanocomposites,
- Cathode materials,
- Hydrothermal reaction,
- Lithium ion battery,
- Post-heat-treatment
1. [1]
  Y.S. Li, X. Cheng, Y. Zhang, J. Electrochem. Soc. 159 (2012) A69-A74. doi: 10.1149/2.022204jes
2. [2]
  A. Shintaro, T. Taisuke, U. Koki, M. Isamu, J. Chem. Commun. 49 (2013) 2939-2941. doi: 10.1039/c3cc40673c
3. [3]
  J.Z. Li, S.H. Luo, Q. Wang, et al., Electrochim. Acta 289 (2018) 415-421. doi: 10.1016/j.electacta.2018.09.095
4. [4]
  S. Litty, J. Gopalakrishnan, J. Solid State Chem. 172 (2003) 171-177. doi: 10.1016/S0022-4596(03)00010-0
5. [5]
  T.F. Yi, T.T. Wei, Y. Li, Y.B. He, Z.B. Wang, Energy Storage Mater. 26 (2020) 165-197. doi: 10.1016/j.ensm.2019.12.042
6. [6]
  D.C. An, L. Shen, D.N. Lei, et al., J. Energy Chem. 31 (2019) 19-26. doi: 10.1016/j.jechem.2018.05.002
7. [7]
  F.F. Huang, J.M. Ma, H.Y. Xia, et al., ACS Appl. Mater. Interfaces 11 (2019) 37357-37364. doi: 10.1021/acsami.9b14119
8. [8]
  S. Bao, S.H. Luo, Z.Y. Wang, et al., Ceram. Int. 44 (2018) 22512-22519. doi: 10.1016/j.ceramint.2018.09.022
9. [9]
  R. Dominko, M. Bele, M. Gaberscek, et al., Electrochem. Commun. 8 (2006) 217-222. doi: 10.1016/j.elecom.2005.11.010
10. [10]
  R. Dominko, C.V.A. Garrido, M. Bele, et al., J. Power Sources 196 (2011) 6856-6862. doi: 10.1016/j.jpowsour.2010.09.004
11. [11]
  M. Kuezma, R. Dominko, D. Hanzel, et al., J. Electrochem. Soc.156 (2009) A809-A816. doi: 10.1149/1.3205458
12. [12]
  H.B. Huang, S.H. Luo, C.L. Liu, et al., ACS Appl. Mater. Interfaces 10 (2018) 21281-21290. doi: 10.1021/acsami.8b03736
13. [13]
  J. Zhang, S.H. Luo, L.L. Sui, et al., J. Alloys Compd. 768 (2018) 991-994. doi: 10.1016/j.jallcom.2018.07.309
14. [14]
  W. Wei, F.F. Jia, K.F. Wang, et al., Chin. Chem. Lett. 28 (2017) 324-328. doi: 10.1016/j.cclet.2016.09.003
15. [15]
  L. Deng, W.H. Yang, S.X. Zhou, et al., Chin. Chem. Lett. 26 (2015) 1529-1534. doi: 10.1016/j.cclet.2015.06.009
16. [16]
  J. Li, Z. Tang, Z. Zhang, ChemInform 17 (2005) 5848-5855.
17. [17]
  J.Z. Li, S.H. Luo, Y. Sun, et al., Ceram. Int. 45 (2018) 4849-4856.
18. [18]
  S.C. Zhang, Y.L. Xing, T. Jiang, et al., J. Power Sources 196 (2011) 6915-6919. doi: 10.1016/j.jpowsour.2010.12.021
19. [19]
  R.X. Lin, S.C. Zhang, Z.J. Du, et al., RSC Adv. 5 (2015) 87090-87097. doi: 10.1039/C5RA13568K
20. [20]
  S.C. Zhang, Z.J. Du, R.X. Lin, et al., Adv. Mater. 22 (2010) 5378-5382. doi: 10.1002/adma.201003017
21. [21]
  X.M. Wu, S.C. Zhang, T. Qi, et al., J. Power Sources 307 (2016) 753-761. doi: 10.1016/j.jpowsour.2015.12.117
22. [22]
  M.M. Sun, S.C. Zhang, T. Jiang, et al., Electrochem. Commun. 10 (2008) 1819-1822. doi: 10.1016/j.elecom.2008.09.012
23. [23]
  H.B. Huang, S.H. Luo, C.L. Liu, et al., Electrochim. Acta 307 (2019) 232-240. doi: 10.1016/j.electacta.2019.03.188
24. [24]
  M. Yang, X.Y. Zhao, C. Yao, et al., Mater. Technol. 31 (2016) 537-543. doi: 10.1080/10667857.2016.1192372
25. [25]
  M. Kuezma, R. Dominko, A. Meden, et al., J. Power Sources 189 (2009) 81-88. doi: 10.1016/j.jpowsour.2008.11.015
26. [26]
  J.Q. Liao, R. Tan, Z.X. Kuang, et al., Chin. Chem. Lett. 29 (2018) 1785-1790. doi: 10.1016/j.cclet.2018.11.018
27. [27]
  H.Q. Dai, W.Q. Xu, K.H. Yu, W. Wei, Chin. Chem. Lett. 30 (2019) 517-520. doi: 10.1016/j.cclet.2018.06.020
28. [28]
  Y.Y. Chen, B.J. Wang, T.Y. Hou, et al., Chin. Chem. Lett. 29 (2018) 187-190. doi: 10.1016/j.cclet.2017.06.019
29. [29]
  K. Byrappa, T. Adschiri, Prog. Cryst. Growth Charact. Mater. 53 (2007) 117-166. doi: 10.1016/j.pcrysgrow.2007.04.001
30. [30]
  M. Yoshimura, K. Byrappa, J. Mater. Sci. 43 (2008) 2085-2103. doi: 10.1007/s10853-007-1853-x
31. [31]
  S.H. Luo, M. Wang, W.N. Sun, Ceram. Int. 38 (2012) 4325-4329. doi: 10.1016/j.ceramint.2012.02.014
32. [32]
  C.L. Liu, S.H. Luo, H.B. Wang, et al., J. Power Sources 389 (2018) 77-83. doi: 10.1016/j.jpowsour.2018.04.014
33. [33]
  C.L. Liu, S.H. Luo, H.B. Wang, et al., ChemSusChem 4 (2019) 873-880.
34. [34]
  S.H. Luo, D.B. Hu, H. Liu, et al., J. Hazard. Mater. 368 (2019) 714-721. doi: 10.1016/j.jhazmat.2019.01.106
35. [35]
  S.H. Luo, Y. Sun, S. Bao, et al., J. Electroanal. Chem. 832 (2019) 196-203. doi: 10.1016/j.jelechem.2018.10.062
36. [36]
  J.Z. Li, S.H. Luo, X. Ding, et al., Mater. Lett. 196 (2017) 183-186. doi: 10.1016/j.matlet.2017.03.051
37. [37]
  X.G. Kong, J.R. Zhang, J.F. Huang, et al., Chin. Chem. Lett. 30 (2019) 771-774. doi: 10.1016/j.cclet.2018.10.006
38. [38]
  R. Dang, X.L. Jia, P. Wang, et al., Chin. Chem. Lett. 28 (2017) 2263-2268. doi: 10.1016/j.cclet.2017.09.064
39. [39]
  J.K. Guo, J. Mater. Res. 2 (2000) 123-126.
40. [40]
  D.M. Bao, H. Xiao, G.L. Zhou, New Chem. Mater. 36 (2008) 55-57.
41. [41]
  R.B. Shaun, C.K. Blakely, J.B. Clapham, et al., J. Power Sources 273 (2015) 396-403. doi: 10.1016/j.jpowsour.2014.09.115
42. [42]
  M. Swietoslawski, M. Molenda, M. Grabowska, et al., Solid State Ionics 263 (2014) 99-102. doi: 10.1016/j.ssi.2014.05.005
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Excess capacity on compound phases of Li2FeTiO4 composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance

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通讯作者: 陈斌, bchen63@163.com

Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance