Citation: Yaolei Kong, Wenxiu Xu, Xinghai Liu, Jianquan Weng. Visible light-induced hydroxyalkylation of 2H-benzothiazoles with alcohols via selectfluor oxidation[J]. Chinese Chemical Letters, ;2020, 31(12): 3245-3249. doi: 10.1016/j.cclet.2020.05.022 shu

Visible light-induced hydroxyalkylation of 2H-benzothiazoles with alcohols via selectfluor oxidation

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

jqweng@zjut.edu.cn

Received Date: 12 February 2020
Revised Date: 11 May 2020
Accepted Date: 18 May 2020
Available Online: 22 May 2020

Figures(9)

A visible-light induced metal-free approach was described for the hydroxyalkylation of 2H-benzothiazoles with alcohols by using selectfluor as the oxidant. A variety of 2H-benzothiazoles and alcohols could be tolerated, providing a mild and simple method for the synthesis of C2-hydroxyalkylated 2H-benzothiazoles in moderate to good yields. Besides, ethers were also compatible in this reaction, leading to corresponding C2 ether-substituted 2H-benzothiazoles with high regioselectivity.
- Visible light-induced,
- Hydroxyalkylation,
- 2H-Benzothiazole,
- Alcohol,
- Selectfluor
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