Citation: Guang-Hui Li, Qing-Qing Han, Yuan-Yuan Sun, De-Mao Chen, Zu-Li Wang, Xin-Ming Xu, Xian-Yong Yu. Visible-light induced cascade radical cyclization of sulfinic acids and o-(allyloxy)arylaldehydes towards functionalized chroman-4-ones[J]. Chinese Chemical Letters, ;2020, 31(12): 3255-3258. doi: 10.1016/j.cclet.2020.03.007 shu

Visible-light induced cascade radical cyclization of sulfinic acids and o-(allyloxy)arylaldehydes towards functionalized chroman-4-ones

Guang-Hui Li ^{a, 1} ,
Qing-Qing Han ^{a, 1} ,
Yuan-Yuan Sun ^a ,
De-Mao Chen ^a ,
Zu-Li Wang ^{a, *,} ,
Xin-Ming Xu ^b ,
Xian-Yong Yu ^c

a.
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China
b.
College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

wangzulichem@163.com

wangzuli09@tsinghua.org.cn

Received Date: 18 January 2020
Revised Date: 27 February 2020
Accepted Date: 3 March 2020
Available Online: 3 March 2020

Figures(6)

An efficient method for the synthesis of functionalized chroman-4-ones induced by visible light via the radical cyclization reaction of sulfinic acids and o-(allyloxy)arylaldehydes at room temperature was described. The corresponding products were isolated with moderate to good yields. Radical mechanism was proposed for this transformation. Anti-microbial activity of some desired compounds were screened.
- Visible light,
- Sulfinic acids,
- Radical cyclization,
- Chroman-4-one,
- o-(Allyloxy)arylaldehydes
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