Citation: Chen Xijian, Dai Xing, Xie Rongzhen, Li Jie, Khayambashi Afshin, Xu Lei, Yang Chuang, Shen Nannan, Wang Yaxing, He Linwei, Zhang Yugang, Xiao Chengliang, Chai Zhifang, Wang Shuao. Chromate separation by selective crystallization[J]. Chinese Chemical Letters, ;2020, 31(7): 1974-1977. doi: 10.1016/j.cclet.2019.11.034 shu

Chromate separation by selective crystallization

a.
State Key Laboratory of Radiation Medicine and Protection, School of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China
b.
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

xiaoc@zju.edu.cn

Received Date: 25 October 2019
Revised Date: 8 November 2019
Accepted Date: 20 November 2019
Available Online: 21 November 2019

Figures(3)

A new paradigm to remove toxic chromate anions from aqueous solution by crystallization of chromatewater clusters with imine-linked guanidinium cationic ligands is introduced. The guanidium-based cationic ligand was easily prepared through the imine condensation of an aldehyde and aminoguanidine hydrochloride. The cationic imine-linked guanidinium ligand (BBIG-Cl) showed a high removal capacity (292.5 mg/g) in the solutions. Rapid decontamination of chromate anions from the wastewater by this cationic ligand was resulted from an instantaneous crystallization. The produced guanidium chromate salts have an extremely low solubility (K_{sp, BBIG} = 8.19×10^-9). Such superior removal performance of these materials was attributed to the charge-assisted hydrogen bonding between the cationic ligand and chromate-water hydrate anions, which was revealed by the single-crystal X-ray diffraction analysis and density functional theory (DFT) calculations. In addition, the successful recovery of the guanidium-based ligand makes it more attractive for real-world applications.
- Chromate,
- Crystallization,
- Hydrogen bonding,
- Chromate-water clusters,
- Guanidinium ligand
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1.
沈阳化工大学材料科学与工程学院沈阳 110142