Citation: Lin Xiaoyu, Wang Jing, Chu Zengyong, Liu Dongqing, Guo Taotao, Yang Lingni, Huang Zhenyu, Mu Sitong, Li Shun. The optimization of hydrothermal process of MoS₂ nanosheets and their good microwave absorption performances[J]. Chinese Chemical Letters, ;2020, 31(5): 1124-1128. doi: 10.1016/j.cclet.2019.07.003 shu

The optimization of hydrothermal process of MoS₂ nanosheets and their good microwave absorption performances

Lin Xiaoyu ^a ,
Wang Jing ^a,*, ,
Chu Zengyong ^a ,
Liu Dongqing ^b ,
Guo Taotao ^a ,
Yang Lingni ^a ,
Huang Zhenyu ^a ,
Mu Sitong ^a ,
Li Shun ^b,*,

a.
College of Liberal Arts and Sciences, National University of Defense Technology, Changsha 410073, China
b.
College of Aeronautics and Astronautics, National University of Defense Technology, Changsha 410073, China

jingwang@nudt.edu.cn

linudt@163.com

Received Date: 10 April 2019
Revised Date: 21 June 2019
Accepted Date: 24 June 2019
Available Online: 2 July 2019

Figures(4)

In this study, flower-like MoS₂ constructed by nanosheets was synthesized by a simple hydrothermal method. The hydrothermal process was optimized and the effects of hydrothermal condition, including reaction temperature, reaction time and the ratio of Mo source to S source (Mo:S) in precursor, on microwave absorption performances and dielectric properties were investigated. Our results showed that when the reaction temperature was 180℃, the reaction time was 18 h, and the Mo:S was 1:3.5, the synthesized MoS₂ had the best performance:Its minimum reflection loss could reach -55.78 dB, and the corresponding matching thickness was 2.30 mm with a wide effective bandwidth of 5.17 GHz. Further researches on the microwave absorption mechanism revealed that in addition to the destructive interference of electromagnetic waves, various polarization phenomena such as defect dipole polarization were the main reasons for microwave loss. We believe that MoS₂ is a candidate for a practical microwave absorbent.
- MoS₂,
- Hydrothermal preparation,
- Microwave absorption performance,
- Process optimization,
- Microwave absorption mechanism
1. [1]
  Z.G. Wang, Q.L. Su, G.Q. Yin, et al., Mater. Chem. Phys. 147(2014) 1068-1073. doi: 10.1016/j.matchemphys.2014.06.060
2. [2]
  B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Nat. Nanotechnol. 6(2011) 147-150. doi: 10.1038/nnano.2010.279
3. [3]
  Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Nat. Nanotechnol. 7(2012) 699-712. doi: 10.1038/nnano.2012.193
4. [4]
  K.S. Novoselov, D. Jiang, F. Schedin, et al., J. Am. Chem. Soc. 102(2005) 10451-10453.
5. [5]
  Z.Y. Zeng, Z.Y. Yin, X. Huang, et al., Angew. Chem. Int. Ed. 50(2011) 11093-11097. doi: 10.1002/anie.201106004
6. [6]
  H. Bian, X.J. Zhang, D.X. Huang, N. Zhang, Chin. Chem. Lett. 30(2019) 311-313. doi: 10.1016/j.cclet.2018.07.002
7. [7]
  Y.H. Lee, X.Q. Zhang, W.J. Zhang, et al., Adv. Mater. 24(2012) 2320-2325. doi: 10.1002/adma.201104798
8. [8]
  X.H. Liang, X.M. Zhang, W. Liu, et al., J. Mater. Chem. C 4(2016) 6816-6821. doi: 10.1039/C6TC02006B
9. [9]
  X.J. Zhang, S. Li, S.W. Wang, et al., J. Phys. Chem. C 120(2016) 22019-22027. doi: 10.1021/acs.jpcc.6b06661
10. [10]
  X. Ding, Y. Huang, S.P. Li, N. Zhang, J.G. Wang, Compos. Part A Appl. Sci. Manuf. 90(2016) 424-432. doi: 10.1016/j.compositesa.2016.08.006
11. [11]
  X.J. Zhang, S.W. Wang, G.S. Wang, et al., RSC Adv. 7(2017) 22454-22460. doi: 10.1039/C7RA03260A
12. [12]
  Z.Y. Guo, Y. Zhong, Y. Liu, C.M. Mao, G.C. Li, Chin. Chem. Lett. 28(2017) 743-747. doi: 10.1016/j.cclet.2016.10.007
13. [13]
  C.J. Han, Z. Tian, H.L. Dou, X.M. Wang, X.W. Yang, Chin. Chem. Lett. 29(2018) 606-611. doi: 10.1016/j.cclet.2018.01.017
14. [14]
  X.L. Su, D. Wang, Q. Yan, et al., J. Mater. Sci.-Mater. Electron. 29(2018) 4020-4029. doi: 10.1007/s10854-017-8344-x
15. [15]
  P. Joensen, R.F. Frindt, S.R. Morrison, Mater. Res. Bull. 21(1986) 457-461. doi: 10.1016/0025-5408(86)90011-5
16. [16]
  G. Eda, H. Yamaguchi, D. Voiry, et al., Nano Lett. 11(2011) 5111-5116. doi: 10.1021/nl201874w
17. [17]
  D. Wang, X. Zhang, S. Bao, et al., J. Mater. Chem. A 5(2017) 2681-2688. doi: 10.1039/C6TA09409K
18. [18]
  J.R. Liu, M. Itoh, K.I. Machida, Appl. Phys. Lett. 83(2003) 4017-4019. doi: 10.1063/1.1623934
19. [19]
  X. Tian, F.B. Meng, F.C. Meng, et al., ACS Appl. Mater. Interfaces 9(2017) 15711-15718. doi: 10.1021/acsami.7b02607
20. [20]
  T. Zhang, B. Xiao, P.Y. Zhou, et al., Nanotechnology 28(2017) 355708. doi: 10.1088/1361-6528/aa7ae9
21. [21]
  J.H. Luo, P. Shen, W. Yao, C.F. Jiang, J.G. Xu, Nanoscale Res. Lett.11(2016) 141-154. doi: 10.1186/s11671-016-1340-x
22. [22]
  J. Wang, X.Y. Lin, R.X. Zhang, R.X. Zhang, Z.Y. Chu, J. Alloys Compd. 743(2018) 26-35. doi: 10.1016/j.jallcom.2018.01.118
23. [23]
  Y. Zhang, Y. Huang, T. Zhang, et al., Adv. Mater. 27(2015) 2049-2053. doi: 10.1002/adma.201405788
24. [24]
  X.G. Huang, J. Zhang, M. Lai, T.Y. Sang, J. Alloys Compd. 627(2015) 367-373. doi: 10.1016/j.jallcom.2014.11.235
25. [25]
  P. Wang, L.F. Cheng, Y.N. Zhang, L.T. Zhang, J. Alloys Compd. 716(2017) 306-320. doi: 10.1016/j.jallcom.2017.05.059
26. [26]
  B. Zhao, G. Shao, B.B. Fan, et al., J. Mater. Chem. A 3(2015) 10345-10352. doi: 10.1039/C5TA00086F
27. [27]
  M.S. Cao, J. Yang, W.L. Song, et al., ACS Appl. Mater. Interfaces 4(2012) 6949-6956. doi: 10.1021/am3021069
28. [28]
  V. Panwar, R.M. Mehra, Polym. Eng. Sci. 48(2008) 2178-2187. doi: 10.1002/pen.21163
29. [29]
  N. Tang, W. Zhong, C. Au, et al., J. Phys. Chem. C 112(2008) 19316-19323. doi: 10.1021/jp808087n
30. [30]
  M.Q. Ning, M.M. Lu, J.B. Li, et al., Nanoscale 7(2015) 15734-15740. doi: 10.1039/C5NR04670J
31. [31]
  I. Kong, S.H. Ahmad, M.H. Abdullah, et al., J. Magn. Magn. Mater. 322(2010) 3401-3409. doi: 10.1016/j.jmmm.2010.06.036
32. [32]
  B. Wang, J. Wei, Y. Yang, T. Wang, F.S. Li, J. Magn. Magn. Mater. 323(2011) 1101-1103. doi: 10.1016/j.jmmm.2010.12.028
1. [1]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
2. [2]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
3. [3]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
4. [4]
  Xinyu Guo , Chang Li , Wenjun Deng , Yi Zhou , Yan Chen , Yushuang Xu , Rui Li . Phase engineering and heteroatom incorporation enable defect-rich MoS₂ for long life aqueous iron-ion batteries. Chinese Chemical Letters, 2025, 36(3): 109715-. doi: 10.1016/j.cclet.2024.109715
5. [5]
  Hui Jin , Qin Cai , Peiwen Liu , Yan Chen , Derong Wang , Weiping Zhu , Yufang Xu , Xuhong Qian . Multistep continuous flow synthesis of Erlotinib. Chinese Chemical Letters, 2024, 35(4): 108721-. doi: 10.1016/j.cclet.2023.108721
6. [6]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
7. [7]
  Chunwei Lei , Jian Li , Bo Xu , Yu Xie , Yun Ling , Juhua Luo , Wei Zhang . Synthesis of Ni/MnO/C nano-microspheres with synergistic effects of dielectric and magnetic loss for efficient microwave absorption. Chinese Chemical Letters, 2025, 36(7): 110419-. doi: 10.1016/j.cclet.2024.110419
8. [8]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
9. [9]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
10. [10]
  Wenkai Liu , Yanxian Hou , Weijian Liu , Ran Wang , Shan He , Xiang Xia , Chengyuan Lv , Hua Gu , Qichao Yao , Qingze Pan , Zehou Su , Danhong Zhou , Wen Sun , Jiangli Fan , Xiaojun Peng . Se-substituted pentamethine cyanine for anticancer photodynamic therapy mediated using the hot band absorption process. Chinese Chemical Letters, 2024, 35(12): 109631-. doi: 10.1016/j.cclet.2024.109631
11. [11]
  Haifeng Ma , Xiaocong Tian , Fengbin Wang , Zhonghua Xi , QingWang . Design of College Chemistry Experiment Based on Product Quality Control: Taking “Optimization of Ferrous Fumarate Synthesis Process” as an Example. University Chemistry, 2025, 40(7): 321-327. doi: 10.12461/PKU.DXHX202409056
12. [12]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
13. [13]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
14. [14]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
15. [15]
  Junan Pan , Xinyi Liu , Huachao Ji , Yanwei Zhu , Yanling Zhuang , Kang Chen , Ning Sun , Yongqi Liu , Yunchao Lei , Kun Wang , Bao Zang , Longlu Wang . The strategies to improve TMDs represented by MoS₂ electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(11): 109515-. doi: 10.1016/j.cclet.2024.109515
16. [16]
  Xian-Rui Meng , Qian Chen , Mei-Feng Wu , Qiang Wu , Su-Qin Wang , Li-Ping Jin , Fan Zhou , Ren-Li Ma , Jian-Ping Zou . Nano-flowers FeS/MoS2 composites as a peroxymonosulfate activator for efficient p-chlorophenol degradation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100543-100543. doi: 10.1016/j.cjsc.2025.100543
17. [17]
  Linghui Zou , Meng Cheng , Kaili Hu , Jianfang Feng , Liangxing Tu . Vesicular drug delivery systems for oral absorption enhancement. Chinese Chemical Letters, 2024, 35(7): 109129-. doi: 10.1016/j.cclet.2023.109129
18. [18]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
19. [19]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
20. [20]
  Yayun Shi , Congcong Liu , Zhijun Zuo , Xiaowei Yang . Self-assembled ultrathick MoS₂ conductive hydrogel membrane via ionic gelation for superior capacitive energy storage. Chinese Chemical Letters, 2025, 36(6): 109772-. doi: 10.1016/j.cclet.2024.109772

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1440)
HTML views(67)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

The optimization of hydrothermal process of MoS2 nanosheets and their good microwave absorption performances

Metrics

通讯作者: 陈斌, bchen63@163.com

The optimization of hydrothermal process of MoS₂ nanosheets and their good microwave absorption performances