Citation: Wei Zhenni, Li Huiqing, Wu Jing, Dong Yalei, Zhang Hongyi, Chen Hongli, Ren Cuiling. 3DRGO-NiFe₂O₄/NiO nanoparticles for fast and simple detection of organophosphorus pesticides[J]. Chinese Chemical Letters, ;2020, 31(1): 177-180. doi: 10.1016/j.cclet.2019.05.031 shu

3DRGO-NiFe₂O₄/NiO nanoparticles for fast and simple detection of organophosphorus pesticides

Wei Zhenni ^a ,
Li Huiqing ^a ,
Wu Jing ^a ,
Dong Yalei ^c ,
Zhang Hongyi ^b ,
Chen Hongli ^a ,
Ren Cuiling ^a,*,

a.
State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
b.
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
c.
National Institutes for Food and Drug Control, Beijing 100050, China

rencl@lzu.edu.cn

Received Date: 2 March 2019
Revised Date: 14 May 2019
Accepted Date: 16 May 2019
Available Online: 17 January 2019

Figures(5)

The residues of organophosphorus pesticide (OPs) on fruits and vegetables pose a threat to human health, so it is very meaningful to explore simple and fast detect methods for OPs residual. In this work, nickel ferrite/nickel oxide nanoparticles co-loaded three-dimensional reduced graphene oxide (3DRGO-NiFe₂O₄/NiO NPs), as a new low cost nanocomposite, was prepared. Based on its high performance mimetic peroxidase activity, a colorimetric method for the detection of OPs has been developed. Dichlorvos was chosen as model compounds to evaluate the detection performance. The detection linear range for dichlorvos is from 50 mg/mL to 2.5×10⁴ mg/mL with a detection limit of 10 mg/mL. Furthermore, a test paper can be developed based on the 3DRGO-NiFe₂O₄/NiO NPs for visual detection of dichlorvos, and the image information of the paper sensor can be converted into digital signal and quantitative detection by a smartphone. Notably, this method can also be used to detect dichlorvos in real samples, including vegetables and fruits. Thus, the developed naked assay holds great potential in simple, inexpensive and rapid detection of OPs in fruit and vegetable samples.
- 3DRGO-NiFe₂O₄/NiO nanoparticles,
- Peroxidase-like activity,
- Organophosphorus pesticides (OPs),
- Test paper,
- Smartphone
1. [1]
  M.M. Liang, K.L. Fan, Y. Pan, et al., Anal. Chem. 85(2013) 308-312. doi: 10.1021/ac302781r
2. [2]
  F. Nachon, X. Brazzolotto, M. Trovaslet, P. Masson, Chem. Biol. Interact. 206(2013) 536-544. doi: 10.1016/j.cbi.2013.06.012
3. [3]
  H.G.J. Mol, R.C.J. van Dam, O.M. Steijger, J. Chromatogr. A 1015(2003) 119-127. doi: 10.1016/S0021-9673(03)01209-3
4. [4]
  J. Blesa, J.M. Soriano, J.C. Moltó, R. Marı'n, J. Mañes, J. Chromatogr. A 1011(2003) 49-54. doi: 10.1016/S0021-9673(03)01102-6
5. [5]
  R. Xue, T.F. Kang, L.P. Lu, S.Y. Cheng, Anal. Lett. 46(2013) 131-141. doi: 10.1080/00032719.2012.706852
6. [6]
  J. Fu, X. An, Y. Yao, Y. Guo, X. Sun, Sens. Actuators B-Chem. 287(2019) 503-509. doi: 10.1016/j.snb.2019.02.057
7. [7]
  W. Fang, X.W. Zhang, Y. Chen, et al., Anal. Chem. 87(2015) 9217-9224. doi: 10.1021/acs.analchem.5b01635
8. [8]
  W. Song, H.J. Zhang, Y.H. Liu, C.L. Ren, H.L. Chen, Chin. Chem. Lett. 28(2017) 1675-1680. doi: 10.1016/j.cclet.2017.05.001
9. [9]
  X. Gao, G.C. Tang, X.G. Su, Biosens. Bioelectron. 36(2012) 75-80. doi: 10.1016/j.bios.2012.03.042
10. [10]
  X. Yan, H.X. Li, X.S. Han, X.G. Su, Biosens. Bioelectron. 74(2015) 277-283. doi: 10.1016/j.bios.2015.06.020
11. [11]
  G. Santoni, J. de Sousa, E. de la Mora, et al., J. Med. Chem. 61(2018) 7630-7639. doi: 10.1021/acs.jmedchem.8b00592
12. [12]
  T.L. Rosenberry, X. Brazzolotto, I.R. Macdonald, et al., Molecules 22(2017) 2098. doi: 10.3390/molecules22122098
13. [13]
  S.H. Qian, H. Lin, Anal. Chem. 87(2015) 5395-5400. doi: 10.1021/acs.analchem.5b00738
14. [14]
  X.X. Hu, Y.T. Su, Y.W. Ma, et al., Chem. Commun. 51(2015) 15118-15121. doi: 10.1039/C5CC04630K
15. [15]
  S. Palanisamy, S.M. Chen, R. Sarawathi, Sensor. Actuat. B-Chem. 166-167(2012) 372-377. doi: 10.1016/j.snb.2012.02.075
16. [16]
  G. Rebollar Pérez, F. Lima Zambrano, G. Bairán, et al., Environ. Eng. Sci. 33(2016) 951-961. doi: 10.1089/ees.2016.0018
17. [17]
  E. Climent, M. Biyikal, K. Gawlitza, et al., Sensor. Actuat. B-Chem. 246(2017) 1056-1065. doi: 10.1016/j.snb.2017.02.115
18. [18]
  Y. Li, Q.J. Luo, R. Hu, Z.B. Chen, P. Qiu, Chin. Chem. Lett. 29(2018) 1845-1848. doi: 10.1016/j.cclet.2018.11.016
19. [19]
  H.X. Zhang, R.B. Wei, C.Z. Chen, X.L. Tuo, X.G. Wang, Chin. Chem. Lett. 26(2015) 39-42. doi: 10.1016/j.cclet.2014.10.014
20. [20]
  L. Su, J. Feng, X. Zhou, et al., Anal. Chem. 84(2012) 5753-5758. doi: 10.1021/ac300939z
21. [21]
  Z.S. Wu, S.B. Yang, Y. Sun, et al., J. Am. Chem. Soc. 134(2012) 9082-9085. doi: 10.1021/ja3030565
22. [22]
  B.C. Qiu, Y.X. Deng, M.M. Du, M.Y. Xing, J.L. Zhang, Sci. Rep. 6(2016) 29099. doi: 10.1038/srep29099
23. [23]
  X.J. Zheng, Q. Zhu, H.Q. Song, et al., ACS Appl. Mater. Interfaces 7(2015) 3480-3491. doi: 10.1021/am508540x
24. [24]
  X.H. Zhao, X. Liu, RSC Adv. 5(2015) 79548-79555. doi: 10.1039/C5RA12720C
25. [25]
  C. Chang, L. Zhang, C. Hsu, X.F. Chuah, S. Lu, ACS Appl. Mater. Interfaces 10(2018) 417-426. doi: 10.1021/acsami.7b13127
26. [26]
  J.S. Mu, X. Zhao, J. Li, E.C. Yang, X.J. Zhao, J. Mater. Chem. B 4(2016) 5217-5221. doi: 10.1039/C6TB01390B
27. [27]
  M. Fu, Q.Z. Jiao, Y. Zhao, J. Mater. Chem. A 1(2013) 5577-5586. doi: 10.1039/c3ta10402h
28. [28]
  M. Mouallem-Bahout, S. Bertrand, O. Peña, J. Solid State Chem. 178(2005) 1080-1086. doi: 10.1016/j.jssc.2005.01.009
29. [29]
  K.C. Babu Naidu, W. Madhuri, Mater. Sci. 40(2017) 417-425. doi: 10.1007/s12034-017-1374-4
30. [30]
  S.Q. Liu, B. Xiao, L.R. Feng, et al., Carbon 64(2013) 197-206. doi: 10.1016/j.carbon.2013.07.052
31. [31]
  L. Su, W.J. Qin, H.G. Zhang, et al., Biosens. Bioelectron. 63(2015) 384-391. doi: 10.1016/j.bios.2014.07.048
32. [32]
  C. Ray, S. Dutta, S. Sarkar, et al., J. Mater. Chem. B 2(2014) 6097-6105. doi: 10.1039/C4TB00968A
33. [33]
  J.S. Mu, X. Zhao, J. Li, E.C. Yang, X.J. Zhao, Mater. Sci. Eng. C-Mater. 74(2017) 434-442. doi: 10.1016/j.msec.2016.12.037
34. [34]
  J.M. Lan, W.M. Xu, Q.P. Wan, et al., Anal. Chim. Acta 825(2014) 63-68. doi: 10.1016/j.aca.2014.03.040
35. [35]
  X.M. Lei, T.T. Li, Y.P. Zuo, et al., Electrochim. Acta 209(2016) 661-670. doi: 10.1016/j.electacta.2016.05.131
36. [36]
  Y.P. Liu, F.Q. Yu, Nanotechnology 22(2011) 145704. doi: 10.1088/0957-4484/22/14/145704
37. [37]
  F.F. Liu, J. He, M.L. Zeng, et al., J. Nanopart. Res. 18(2016) 106. doi: 10.1007/s11051-016-3416-z
38. [38]
  A. Fujishima, T.N. Rao, D.A. Tryk, J. Photochem. Photobiol. C 1(2000) 1-21. doi: 10.1016/S1389-5567(00)00002-2
39. [39]
  J.Y. Hou, Z.B.Tian, H.Z.Xie, Q.Y. Tian, S.Y.Ai, Sensor.Actuat.B-Chem. 232(2016) 477-483. doi: 10.1016/j.snb.2016.03.092
40. [40]
  R. Zhang, N. Li, J.Y. Sun, F. Gao, J. Agric. Food. Chem. 63(2015) 8947-8954. doi: 10.1021/acs.jafc.5b03096
1. [1]
  Shaobin He , Xiaoyun Guo , Qionghua Zheng , Huanran Shen , Yuan Xu , Fenglin Lin , Jincheng Chen , Haohua Deng , Yiming Zeng , Wei Chen . Engineering nickel-supported osmium bimetallic nanozymes with specifically improved peroxidase-like activity for immunoassay. Chinese Chemical Letters, 2025, 36(4): 110096-. doi: 10.1016/j.cclet.2024.110096
2. [2]
  Gaowa Xing , Yuting Shang , Xiaorui Wang , Zengnan Wu , Qiang Zhang , Jiebing Ai , Qiaosheng Pu , Ling Lin . A microfluidic biosensor for multiplex immunoassay of foodborne pathogens agitated by programmed audio signals. Chinese Chemical Letters, 2024, 35(10): 109491-. doi: 10.1016/j.cclet.2024.109491
3. [3]
  Miao-Miao Chen , Min-Ling Zhang , Xiao Song , Jun Jiang , Xiaoqian Tang , Qi Zhang , Xiuhua Zhang , Peiwu Li . Smartphone-assisted electrochemiluminescence imaging test strips towards dual-signal visualized and sensitive monitoring of aflatoxin B1 in corn samples. Chinese Chemical Letters, 2025, 36(1): 109785-. doi: 10.1016/j.cclet.2024.109785
4. [4]
  Zian Fang , Qianqian Wen , Yidi Wang , Hongxia Ouyang , Qi Wang , Qiuping Li . The Test Paper for Metal Ion: A Popular Science Experiment Based on Color Aesthetics. University Chemistry, 2024, 39(5): 108-115. doi: 10.3866/PKU.DXHX202310032
5. [5]
  Yuwan Lu , Xiaodan Zhang , Yuming Huang . Dual-site Se/NC specific peroxidase-like nanozyme for highly sensitive methimazole detection. Chinese Chemical Letters, 2025, 36(4): 110129-. doi: 10.1016/j.cclet.2024.110129
6. [6]
  Yunxin Li , Jinghui Zhang , Jisen Chen , Feng Zhu , Zhiqiang Liu , Peng Bao , Wei Shen , Sheng Tang . Detection of SARS-CoV-2 based on artificial intelligence-assisted smartphone: A review. Chinese Chemical Letters, 2024, 35(7): 109220-. doi: 10.1016/j.cclet.2023.109220
7. [7]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
8. [8]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
9. [9]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
10. [10]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
11. [11]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
12. [12]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
13. [13]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
14. [14]
  Anjing Liao , Wei Sun , Yaming Liu , Han Yan , Zhi Xia , Jian Wu . Pyrrole and pyrrolidine analogs: The promising scaffold in discovery of pesticides. Chinese Chemical Letters, 2025, 36(3): 110094-. doi: 10.1016/j.cclet.2024.110094
15. [15]
  Sinong Wang , Shanshan Jin , Xue Yang , Yanyan Huang , Peng Liu , Yi Tang , Yuliang Yang . Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics. Chinese Chemical Letters, 2024, 35(9): 109890-. doi: 10.1016/j.cclet.2024.109890
16. [16]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
19. [19]
  Juanjuan Wang , Fang Wang , Bin Qin , Yue Wu , Huan Yang , Xiaolong Li , Lanfang Wang , Xiufang Qin , Xiaohong Xu . Controlled synthesis and excellent magnetism of ferrimagnetic NiFe₂Se₄ nanostructures. Chinese Chemical Letters, 2024, 35(11): 109449-. doi: 10.1016/j.cclet.2023.109449
20. [20]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1053)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

3DRGO-NiFe2O4/NiO nanoparticles for fast and simple detection of organophosphorus pesticides

Metrics

通讯作者: 陈斌, bchen63@163.com

3DRGO-NiFe₂O₄/NiO nanoparticles for fast and simple detection of organophosphorus pesticides