Citation: Rong Rong, Liu Song. Reversible chemical switches of functionalized nitrogen-doped graphene field-effect transistors[J]. Chinese Chemical Letters, ;2020, 31(2): 565-569. doi: 10.1016/j.cclet.2019.05.014 shu

Reversible chemical switches of functionalized nitrogen-doped graphene field-effect transistors

Rong Rong ,
Liu Song ^*,

Institute of Chemical Biology and Nanomedicine (ICBN), State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

liusong@hnu.edu.cn

Received Date: 16 April 2019
Revised Date: 5 May 2019
Accepted Date: 7 May 2019
Available Online: 7 May 2019

Figures(5)

Nitrogen doping is a promising way to modulate the electrical properties of graphene to realize graphene-based electronics and promise fascinating properties and applications. Herein, we report a method to noncovalently assembly titanium(Ⅳ) bis(ammoniumlactato) dihydroxide (Ti complex) on nitrogen-doped graphene to create a reliable hybrids which can be used as a reversible chemical induced switching. As the adsorption and desorption of Ti complex in sequential treatments, the conductance of the nitrogen-doped graphene transistors was finely modulated. Control experiments with pristine graphene clearly demonstrated the important effort of the nitrogen in this chemical sensor. Under optimized conditions, nitrogen-doped graphene transistors open up new ways to develop multifunctional devices with high sensitivity.
- Field-effect transistors,
- Nitrogen-doped graphene,
- Doping effect,
- Ti complex,
- Reversible switch
1. [1]
  K.S. Novoselov, A.K. Geim, S.V. Morozov, et al., Science 306(2004) 666-669. doi: 10.1126/science.1102896
2. [2]
  R. Raccichini, A. Varzi, S. Passerini, B. Scrosati, Nat. Mater. 14(2014) 271-279.
3. [3]
  V. Georgakilas, J.N. Tiwari, K.C. Kemp, et al., Chem. Rev.116(2016) 5464-5519. doi: 10.1021/acs.chemrev.5b00620
4. [4]
  Y. Cao, V. Fatemi, S. Fang, et al., Nature 556(2018) 43-50. doi: 10.1038/nature26160
5. [5]
  S. Kawai, S. Saito, S. Osumi, et al., Nat. Commun. 6(2015) 8098. doi: 10.1038/ncomms9098
6. [6]
  T.H. Han, S.J. Kwon, N. Li, et al., Angew. Chem. Int. Ed. 55(2016) 6197-6201. doi: 10.1002/anie.201600414
7. [7]
  S.M. Shinde, E. Kano, G. Kalita, et al., Carbon 96(2016) 448-453. doi: 10.1016/j.carbon.2015.09.086
8. [8]
  L. Gan, D. Zhang, X. Guo, Small 8(2012) 1326-1330. doi: 10.1002/smll.201102302
9. [9]
  M. Rybin, A. Pereyaslavtsev, T. Vasilieva, et al., Carbon 96(2016) 196-202. doi: 10.1016/j.carbon.2015.09.056
10. [10]
  X. Wang, X. Li, L. Zhang, et al., Science 324(2009) 768-771. doi: 10.1126/science.1170335
11. [11]
  H. Kim, J. Byun, S.H. Bae, et al., Adv. Energy Mater. 6(2016) 1600172. doi: 10.1002/aenm.201600172
12. [12]
  L. Qu, Y. Liu, J.B. Baek, et al., ACS Nano 4(2010) 1321-1326. doi: 10.1021/nn901850u
13. [13]
  F. Schedin, A.K. Geim, S.V. Morozov, et al., Nat. Mater. 6(2007) 652-655. doi: 10.1038/nmat1967
14. [14]
  J. Kim, M.S. Lee, S. Jeon, et al., Adv. Mater. 27(2015) 3292-3297. doi: 10.1002/adma.201500710
15. [15]
  S. Liu, S. Jamali, Q. Liu, et al., Macromolecules 49(2016) 7434-7441. doi: 10.1021/acs.macromol.6b01011
16. [16]
  X. Wang, X. Liu, H. Yuan, et al., Mater. Design 139(2018) 372-379. doi: 10.1016/j.matdes.2017.11.023
17. [17]
  S. Kumar, W. Ahlawat, R. Kumar, et al., Biosens. Bioelectron.70(2015) 498-503. doi: 10.1016/j.bios.2015.03.062
18. [18]
  Z. Zhu, Nano-Micro Lett. 9(2017) 25. doi: 10.1007/s40820-017-0128-6
19. [19]
  K.S. Kim, Y. Zhao, H. Jang, et al., Nature 457(2009) 706-710. doi: 10.1038/nature07719
20. [20]
  Y. Cao, S. Dong, S. Liu, et al., Angew. Chem. Int. Ed. 51(2012) 12228-12232. doi: 10.1002/anie.201205607
21. [21]
  W.J. Lee, J.M. Lee, S.T. Kochuveedu, et al., ACS Nano 6(2012) 935-943. doi: 10.1021/nn204504h
22. [22]
  Y.T. Lee, N.S. Kim, S.Y. Bae, et al., J. Phys. Chem. B 107(2003) 12958-12963. doi: 10.1021/jp0274536
23. [23]
  S.S. Nanda, M.J. Kim, K.S. Yeom, et al., Trac-Trend. Anal. Chem. 80(2016) 125-131. doi: 10.1016/j.trac.2016.02.024
24. [24]
  R. Beams, L. Gustavo Cançado, L. Novotny, J. Phys.-Condens. Mat. 27(2015) 083002. doi: 10.1088/0953-8984/27/8/083002
25. [25]
  X.L. Li, X.F. Qiao, W.P. Han, et al., Nanoscale 7(2015) 8135-8141. doi: 10.1039/C5NR01514F
26. [26]
  L. Gan, S. Liu, D.N. Li, et al., Acta Phys.-Chim. Sin. 26(2010) 1151-1156.
27. [27]
  T. Kato, R. Hatakeyama, ACS Nano 6(2012) 8508-8515. doi: 10.1021/nn302290z
28. [28]
  S. Myung, A. Solanki, C. Kim, et al., Adv. Mater. 23(2011) 2221-2225. doi: 10.1002/adma.201100014
29. [29]
  S. Mao, G. Lu, K. Yu, Z. Bo, J. Chen, Adv. Mater. 22(2010) 3521-3526. doi: 10.1002/adma.201000520
1. [1]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
2. [2]
  Lingdan Kong , Pingping Huang , Feng Yuan , Yue Zhang , Xiaoqian Shi , Kang Han , Keke Liu , Qing Xu , Wenjing Zhang , Tom Lawson , Xiaoru Xia , Yong Liu , Yuepeng Jin . A metal-free bionic nanozyme for efficient inhibition of cancer recurrence and metastasis following photothermal therapy. Chinese Chemical Letters, 2025, 36(9): 111030-. doi: 10.1016/j.cclet.2025.111030
3. [3]
  Zhilei Zhang , Yanan Sun , Xiaosong Shi , Xiaozhe Yin , Dawei Liu , Erjing Wang , Jie Liu , Yuanyuan Hu , Lang Jiang . Molecular tailoring towards two-dimensional organic crystals at the thickness limit. Chinese Chemical Letters, 2025, 36(9): 110786-. doi: 10.1016/j.cclet.2024.110786
4. [4]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
5. [5]
  Le Li , Shaofeng Jia , Shi Yue , Yuanyuan Yang , Chao Tan , Conghui Wang , Hengwei Qiu , Yongqiang Ji , Minghui Cao , Zige Tai , Dan Zhang . Vanadium doping inhibit the Jahn−Teller effect of Mn³⁺ for high-performance aqueous zinc ion battery. Chinese Chemical Letters, 2025, 36(10): 111009-. doi: 10.1016/j.cclet.2025.111009
6. [6]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
7. [7]
  Shaohua Zhang , Xiaojuan Dai , Wei Hao , Liyao Liu , Yingqiao Ma , Ye Zou , Jia Zhu , Chong-an Di . A first-principles study of the Nernst effect in doped polymer. Chinese Chemical Letters, 2024, 35(12): 109837-. doi: 10.1016/j.cclet.2024.109837
8. [8]
  Haiyan Wang , Hucheng Zhang , Lijing Wang , Yonghui Li , Tianhao Zhang , Zhansheng Lu , Hao Jiang , Chunzhong Li , Jianji Wang . Ti₃C₂T_x MXene-mediating near- and long-range electronic effect on atomically dispersed Co for efficient lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(10): 110373-. doi: 10.1016/j.cclet.2024.110373
9. [9]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
10. [10]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
11. [11]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
12. [12]
  Mingzhu Jiang , Panqing Wang , Qiheng Chen , Yue Zhang , Qi Wu , Lei Tan , Tianxiang Ning , Lingjun Li , Kangyu Zou . Enabling the Nb/Ti co-doping strategy for improving structure stability and rate capability of Ni-rich cathode. Chinese Chemical Letters, 2025, 36(6): 110040-. doi: 10.1016/j.cclet.2024.110040
13. [13]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
14. [14]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
15. [15]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
16. [16]
  Wenrui Jia , Chenghuan Qiao , Dongfang Zhao , Juanshan Du , Yaohua Wu , Yongqi Liang , Qinglian Wu , Xiaochi Feng , Huazhe Wang , Wanqian Guo . Insight into nitrogen-doped biochar prepared from Chinese medicine compound residue for peracetic acid activation in sulfamethoxazole degradation: Electron transfer mechanism. Chinese Chemical Letters, 2025, 36(11): 110886-. doi: 10.1016/j.cclet.2025.110886
17. [17]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
18. [18]
  Yiwen Xu , Chaozheng He , Chenxu Zhao , Ling Fu . Single-atom Ti doping on S-vacancy two-dimensional CrS₂ as a catalyst for ammonia synthesis: A DFT study. Chinese Chemical Letters, 2025, 36(4): 109797-. doi: 10.1016/j.cclet.2024.109797
19. [19]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
20. [20]
  Xiaoqin Li , Xiaohan Chen , Yongqiang Guo , Jian Xiang , Yinkun Zhao , Taotao Gao , Qu Yue , Wenlong Liu , Lu Qiu , Dan Xiao , Panpan Li . Regulating zincophilic sites and electric field distribution to achieve reversible zinc plating/stripping for high-performance flexible Zn-ion batteries. Chinese Chemical Letters, 2025, 36(9): 110327-. doi: 10.1016/j.cclet.2024.110327

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1833)
HTML views(146)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142