Citation: Xiao Tangxin, Zhou Ling, Sun Xiao-Qiang, Huang Feihe, Lin Chen, Wang Leyong. Supramolecular polymers fabricated by orthogonal self-assembly based on multiple hydrogen bonding and macrocyclic host-guest interactions[J]. Chinese Chemical Letters, ;2020, 31(1): 1-9. doi: 10.1016/j.cclet.2019.05.011 shu

Supramolecular polymers fabricated by orthogonal self-assembly based on multiple hydrogen bonding and macrocyclic host-guest interactions

Xiao Tangxin ^a,*, ,
Zhou Ling ^a ,
Sun Xiao-Qiang ^a ,
Huang Feihe ^b,**, ,
Lin Chen ^c ,
Wang Leyong ^a,c,*,

a.
School of Petrochemical Engineering, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, China
b.
State Key Laboratory of Chemical Engineering, Center for Chemistry of High Performance & Novel Materials, Department of Chemistry, Zhejiang University, Hangzhou 310027, China
c.
Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Author Bio: Tangxin Xiao is a lecturer at the School of Petrochemical Engineering, Changzhou University. He studied chemistry at Nanjing University where he received his PhD degree under the supervision of Prof. Leyong Wang in 2014. He has been to University of Cambridge as a visiting PhD student supervised by Prof. Oren Scherman in 2013. After postdoctoral research on fine chemicals at Zhejiang University-NHU Company United R&D Center, he joined Changzhou University in 2017. His current research interests concern the supramolecular self-assembly and smart materials.

^☆

^**

xiaotangxin@cczu.edu.cn

lywang@nju.edu.cn

Received Date: 1 April 2019
Revised Date: 23 April 2019
Accepted Date: 6 May 2019
Available Online: 7 January 2019

Figures(12)

Supramolecular polymers constructed by orthogonal self-assembly based on multiple hydrogen bonding and macrocyclic host-guest interactions have received increasing attention due to their elegant structures, outstanding properties, and potential applications. Hydrogen bonding endows these supramolecular polymers with good adaptability and reversibility, while macrocyclic host-guest interactions give them good selectivity and versatile stimuli-responsiveness. Therefore, functional supramolecular polymers fabricated by these two highly specific, noninterfering interactions in an orthogonal way have shown wide applications in the fields of molecular machines, electronics, soft materials, etc. In this review, we discuss the recent advances of functional supramolecular polymers fabricated by orthogonal self-assembly based on multiple hydrogen bonding and host-guest interactions. In particular, we focus on crown ether- and pillar[n]arene-based supramolecular polymers due to their compatibility with multiple hydrogen bonds in organic solution. The fabrication strategies, interesting properties, and potential applications of these advanced supramolecular materials are mainly concerned.
- Supramolecular polymer,
- Orthogonal self-assembly,
- Hydrogen bonding,
- Host-guest interactions,
- Stimuli-responsiveness
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