Citation: Qin He, Zhang Hong, Zhou Xiaoteng, Gu Danfei, Li Lingxiao, Kan Chengyou. Preparation and reducing-responsive property of a novel functional polyurethane nanoemulsion[J]. Chinese Chemical Letters, ;2020, 31(1): 292-294. doi: 10.1016/j.cclet.2019.04.015 shu

Preparation and reducing-responsive property of a novel functional polyurethane nanoemulsion

Department of Chemical Engineering and Key Laboratory of Advanced Materials of Ministry of Education of China, Tsinghua University, Beijing 100084, China

kancy@mail.tsinghua.edu.cn

Received Date: 27 February 2019
Revised Date: 2 April 2019
Accepted Date: 8 April 2019
Available Online: 8 January 2019

Figures(3)

As a kind of stimuli-responsive materials, the disulfide-containing material has received a tremendous amount of interest. A novel functional disulfide-containing waterborne polyurethane (DS-WPU) nanoemulsion was prepared via a one-step in situ phase inverse emulsification technique and its reducing-responsive property was investigated using dithiothreitol as the reductant. Results showed that the DS-WPU nanoemulsion had a uniform particle size in nanoscale and a good film-forming characteristic, and the DS-WPU latex film exhibited great responsiveness along with a self-assembled behavior in the reducing environment to form WPU emulsion again, including a long-to-short process of the polymer chains.
- Polyurethane,
- Disulfide bond,
- Nanoemulsion,
- Reducing-responsiveness,
- Self-assembly
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