Citation: Fang Qing, Zhang Wei, Chen Xinghua, Zhang Yuanjian, Hu Ming. Hierarchically porous carbon cages synthesized through in situ migration of templates[J]. Chinese Chemical Letters, ;2020, 31(1): 303-306. doi: 10.1016/j.cclet.2019.04.006 shu

Hierarchically porous carbon cages synthesized through in situ migration of templates

Fang Qing ^a ,
Zhang Wei ^a ,
Chen Xinghua ^b ,
Zhang Yuanjian ^b,*, ,
Hu Ming ^a,*,

a.
State Key Laboratory of Precision Spectroscopy, School of Physics and Materials Science, East China Normal University, Shanghai 200241, China
b.
Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Device, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Yuanjian.Zhang@seu.edu.cn

mhu@phy.ecnu.edu.cn

Received Date: 29 January 2019
Revised Date: 28 March 2019
Accepted Date: 1 April 2019
Available Online: 3 January 2019

Figures(4)

In order to optimize mass transportation and exchange, nature creates hierarchically porous networks which are composed of multi-level branches. Although bottom-up templating methods have succeeded in fabrication of these kinds of hierarchically porous networks, the templates have to be assembled/ packed in advance, therefore, driving the fabrication process too complex. In this report, we presented that the hierarchically porous networks could be fabricated through migration of templates, which was similar to formation of rivers. During thermal pyrolysis of Prussian blue cages, the in situly generated iron oxides nanoparticles diffused and aggregated together to grow larger, and eventually moved outside from the porous carbons. The moving routes of the iron oxides became hierarchical channels in the obtained carbon cages. By using the porous carbon cages as electrode for Na-ion battery, a pseudocapacitor-type ion storage was investigated.
- Hierarchical structures,
- Hierarchically porous carbon,
- Mobile templates,
- Thermal pyrolysis,
- Na-ion battery
1. [1]
  J. Aizenberg, J.C. Weaver, M.S. Thanawala, et al., Science 309(2005) 275-278. doi: 10.1126/science.1112255
2. [2]
  X. Wang, Z. Huang, D. Miao, et al., ACS Nano 13(2019) 1060-1070.
3. [3]
  A. Bejan, J.P. Zane, Mech. Eng. 134(2012) 42-47.
4. [4]
  K.A. McCulloh, J.S. Sperry, F.R. Adler 421(2003) 939-942.
5. [5]
  G.B. West, J.H. Brown, B.J. Enquist, Science 276(1997) 122-126. doi: 10.1126/science.276.5309.122
6. [6]
  X. Zheng, G. Shen, C. Wang, et al., Nat. Commun. 8(2017) 14921. doi: 10.1038/ncomms14921
7. [7]
  M.R. Carvalho, J.M. Losada, K.J. Niklas, Curr. Opin. Plant Biol. 43(2018) 29-35. doi: 10.1016/j.pbi.2017.12.007
8. [8]
  S.K. Hetz, T.J. Bradley, Nature 433(2005) 516-519. doi: 10.1038/nature03106
9. [9]
  G.B. Pasternack, D. Baig, M.D. Weber, et al., Earth Surf. Process. Landforms 43(2018) 2510-2518. doi: 10.1002/esp.4411
10. [10]
  G.B. Pasternack, D. Baig, M.D. Weber, et al., Earth Surf. Process. Landforms 43(2018) 2519-2532. doi: 10.1002/esp.4410
11. [11]
  Y. Lv, L. Gan, M. Liu, et al., J. Power Sources 209(2012) 152-157. doi: 10.1016/j.jpowsour.2012.02.089
12. [12]
  J. Xu, W. Zhang, D. Hou, et al., Chin. Chem. Lett. 28(2017) 2295-2297. doi: 10.1016/j.cclet.2017.10.041
13. [13]
  L. Sun, Y. Zhou, L. Li, et al., Appl. Surf. Sci. 467-468(2019) 382-390.
14. [14]
  L. Shen, X. Zheng, G. Lei, et al., Chem. Eng. J. 346(2018) 238-248. doi: 10.1016/j.cej.2018.03.157
15. [15]
  P.K. Tripathi, M. Liu, Y. Zhao, et al., J. Mater. Chem. A 2(2014) 8534-8544. doi: 10.1039/c4ta00578c
16. [16]
  M. Liu, L. Gan, Y. Li, et al., Chin. Chem. Lett. 25(2014) 897-901. doi: 10.1016/j.cclet.2014.01.010
17. [17]
  D. Jing, S. Song, L. He, Int. J. Heat Mass Transfer 128(2019) 1344-1350. doi: 10.1016/j.ijheatmasstransfer.2018.08.006
18. [18]
  J. Kou, Y. Chen, X. Zhou, et al., Physica A 393(2014) 527-534. doi: 10.1016/j.physa.2013.08.029
19. [19]
  D.R. Emerson, K. Cieślicki, X. Gu, et al., Lab Chip 6(2006) 447-454. doi: 10.1039/b516975e
20. [20]
  C.D. Murray, Proc. Natl. Acad. Sci. USA 12(1926) 207-214. doi: 10.1073/pnas.12.3.207
21. [21]
  Z. Wang, T. Liu, Y. Yu, et al., Small 14(2018) 1802670. doi: 10.1002/smll.201802670
22. [22]
  G.S. Kassab, Am. J. Physiol. Heart Circ. Physiol. 290(2006) H894-H903. doi: 10.1152/ajpheart.00579.2005
23. [23]
  A. Kamiya, T. Takahashi, J. Appl. Physiol. 102(2007) 2315-2323. doi: 10.1152/japplphysiol.00856.2006
24. [24]
  M. Colombini, A. Stocchino, J. Fluid Mech. 695(2012) 63-80. doi: 10.1017/jfm.2011.556
25. [25]
  S.N. Wilkinson, R.J. Keller, I.D. Rutherfurd, Earth Surf. Process Landforms 29(2004) 737-753. doi: 10.1002/esp.1066
26. [26]
  Y. Deng, C. Liu, T. Yu, et al., Chem. Mater. 19(2007) 3271-3277. doi: 10.1021/cm070600y
27. [27]
  Z. Wu, K. Tian, T. Huang, et al., ACS Appl. Mater. Interfaces 10(2018) 11108-11115. doi: 10.1021/acsami.7b17264
28. [28]
  M. Hu, A.A. Belik, M. Imura, et al., J. Am. Chem. Soc. 135(2012) 384-391.
29. [29]
  R. Ojani, P. Hamidi, J. Raoof, Chin. Chem. Lett. 27(2016) 481-486. doi: 10.1016/j.cclet.2015.12.030
30. [30]
  Y. Liang, J. Wei, X. Zhang, et al., ChemCatChem 8(2016) 1901-1904. doi: 10.1002/cctc.201501402
31. [31]
  R. Qiang, Y. Du, H. Zhao, et al., J. Mater. Chem. A 3(2015) 13426-13434. doi: 10.1039/C5TA01457C
32. [32]
  C. Clauss, M. Schwarz, E. Kroke, Carbon 48(2010) 1137-1145. doi: 10.1016/j.carbon.2009.11.036
33. [33]
  M. Hu, S. Furukawa, R. Ohtani, et al., Angew. Chem. Int. Ed. 51(2012) 984-988. doi: 10.1002/anie.201105190
34. [34]
  B. Liu, H. Shioyama, T. Akita, et al., J. Am. Chem. Soc. 130(2008) 5390-5391. doi: 10.1021/ja7106146
35. [35]
  T. Kim, J. Jeong, M. Rahman, et al., Korean J. Chem. Eng. 31(2014) 2124-2129. doi: 10.1007/s11814-014-0322-x
36. [36]
  R. Rahmawati, M.G. Permanaa, B. Harisona, et al., Procedia Eng. 170(2017) 55-59. doi: 10.1016/j.proeng.2017.03.010
37. [37]
  D. Smilgies, J. Appl. Crystallogr. 42(2009) 1030-1034. doi: 10.1107/S0021889809040126
38. [38]
  L. Wang, Y. Yu, P.C. Chen, et al., J. Power Sources 183(2008) 717-723. doi: 10.1016/j.jpowsour.2008.05.079
39. [39]
  X. Chen, F. He, Y. Shen, et al., Chem.-Eur. J. 23(2017) 14597-14603. doi: 10.1002/chem.201703020
40. [40]
  L. Wang, Y. Wang, M. Wu, et al., Small 14(2018) 1800737. doi: 10.1002/smll.201800737
41. [41]
  Z. Zhou, F. He, Y. Shen, et al., Chem. Commun. 53(2017) 2044-2047. doi: 10.1039/C6CC09442B
42. [42]
  M. Wu, Y. Wang, Z. Wei, et al., J. Mater. Chem. A 6(2018) 10918-10925. doi: 10.1039/C8TA02416B
43. [43]
  J. Liang, Z. Wei, C. Wang, et al., Electrochim. Acta 285(2018) 301-308. doi: 10.1016/j.electacta.2018.07.230
44. [44]
  C. Zhu, X. Mu, P.A. van Aken, et al., Angew. Chem. Int. Ed. 53(2014) 2152-2156. doi: 10.1002/anie.201308354
45. [45]
  Y. Chen, B. Wang, T. Hou, et al., Chin. Chem. Lett. 29(2018) 187-190. doi: 10.1016/j.cclet.2017.06.019
46. [46]
  S. Liu, L. Shao, X. Zhang, et al., Acta Phys.-Chim. Sin. 34(2018) 581-597.
47. [47]
  X. Zhang, Y. Huang, S. Wu, et al., Acta Phys.-Chim. Sin. 34(2018) 219-226.
48. [48]
  Q. Ma, Y. Hu, H. Li, et al., Acta Phys.-Chim. Sin. 34(2018) 213-218.
49. [49]
  W. Song, H. Hou, X. Ji, Acta Phys.-Chim. Sin. 33(2017) 103-129.
50. [50]
  L. Fu, K. Tang, K. Song, et al., Nanoscale 6(2014) 1384-1389. doi: 10.1039/C3NR05374A
51. [51]
  X. Ma, L. Gan, M. Liu, et al., J. Mater. Chem. A 2(2014) 8407-8415. doi: 10.1039/C4TA00333K
52. [52]
  Y. Fang, Z. Chen, X. Ai, et al., Acta Phys.-Chim. Sin. 33(2017) 211-241.
53. [53]
  Y. Gogotsi, R.M. Penner, ACS Nano 12(2018) 2081-2083. doi: 10.1021/acsnano.8b01914
54. [54]
  W. Zhang, X. Jiang, Y. Zhao, et al., Chem. Sci. 8(2017) 3538-3546. doi: 10.1039/C6SC04903F
55. [55]
  T. Brousse, D. Bélanger, J.W. Long, J. Electrochem. Soc.162(2015) A5185-A5189. doi: 10.1149/2.0201505jes
56. [56]
  J. Liu, J. Liang, C. Wang, et al., J. Energy Chem. 33(2019) 160-166. doi: 10.1016/j.jechem.2018.09.006
57. [57]
  M. Zhao, L. Zhu, B. Fu, et al., Acta Phys.-Chim. Sin. 35(2019) 193-199.
58. [58]
  P. Simon, Y. Gogotsi, B. Dunn, Science 343(2014) 1210-1211. doi: 10.1126/science.1249625
59. [59]
  V. Augustyn, J. Come, M.A. Lowe, et al., Nat. Mater. 12(2013) 518-522. doi: 10.1038/nmat3601
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