Citation: Wang Biwei, Liu Limin, Zhang Yi, Deng Yonghui, Dong Angang. A novel strategy for boosting the photoluminescence quantum efficiency of CdSe nanocrystals at room temperature[J]. Chinese Chemical Letters, ;2020, 31(1): 295-298. doi: 10.1016/j.cclet.2019.03.043 shu

A novel strategy for boosting the photoluminescence quantum efficiency of CdSe nanocrystals at room temperature

Wang Biwei ^a ,
Liu Limin ^a ,
Zhang Yi ^b ,
Deng Yonghui ^a ,
Dong Angang ^a,*,

a.
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, and Department of Chemistry, iChem, Fudan University, Shanghai 200433, China
b.
School of Materials Science and Energy Engineering, Foshan University, Foshan 528000, China

agdong@fudan.edu.cn

Received Date: 5 March 2019
Revised Date: 23 March 2019
Accepted Date: 26 March 2019
Available Online: 27 January 2019

Figures(4)

Highly luminescent colloidal nanocrystals have wide applications in bioimaging and various optoelectronic devices. Herein we report a facile and mild procedure by combining S^2- treatment and binary ligand passivation, which can efficiently enhance the luminescent property of CdSe nanocrystals at room temperature. The photoluminescence quantum yield of as-treated CdSe nanocrystals exhibits drastic enhancement (e.g., 188 times for CdSe nanorods) after this dual-passivation treatment. The methodology proposed here can be applied to various CdSe nanocrystals, regardless of their sizes, shapes, and crystal structures.
- Photoluminescence,
- CdSe nanocrystals,
- Sulfur ions,
- Surface passivation,
- Room temperature
1. [1]
  L. Wang, Y. Wang, T. Xu, et al., Nat. Commun. 5(2014) 5357. doi: 10.1038/ncomms6357
2. [2]
  S.M. Ng, M. Koneswaran, R. Narayanaswamy, RSC Adv. 6(2016) 21624-21661. doi: 10.1039/C5RA24987B
3. [3]
  H.R. Chandan, J.D. Schiffman, R.G. Balakrishna, Sens. Actuator. B-Chem. 258(2018) 1191-1214. doi: 10.1016/j.snb.2017.11.189
4. [4]
  L. Polavarapu, B. Nickel, J. Feldmann, A.S. Urban, Adv. Energy Mater. 7(2017) 1700267.
5. [5]
  Y.J. Bao, J.J. Li, Y.T. Wang, et al., Chin. Chem. Lett. 22(2011) 843-846. doi: 10.1016/j.cclet.2010.12.008
6. [6]
  L.L. Xi, H.B. Ma, G.H. Tao, Chin. Chem. Lett. 27(2016) 1531-1536. doi: 10.1016/j.cclet.2016.03.002
7. [7]
  Q. Zhang, Y. Yin, ACS Cent. Sci. 4(2018) 668-679. doi: 10.1021/acscentsci.8b00201
8. [8]
  D. Yang, M. Cao, Q. Zhong, et al., J. Mater. Chem. C 7(2019) 757-789. doi: 10.1039/C8TC04381G
9. [9]
  P. Fu, Q. Shan, Y. Shang, et al., Sci. Bull. 62(2017) 369-380. doi: 10.1016/j.scib.2017.01.006
10. [10]
  C. Pu, X. Peng, J. Am. Chem. Soc. 138(2016) 8134-8142. doi: 10.1021/jacs.6b02909
11. [11]
  A. Saha, K.V. Chellappan, K.S. Narayan, et al., J. Phys. Chem. Lett. 4(2013) 3544-3549. doi: 10.1021/jz401958u
12. [12]
  R. Wang, Y. Shang, P. Kanjanaboos, et al., Energy Environ. Sci. 9(2016) 1130-1143. doi: 10.1039/C5EE03887A
13. [13]
  Y. Shang, Z. Ning, Natl. Sci. Rev. 4(2017) 170-183. doi: 10.1093/nsr/nww097
14. [14]
  P. Reiss, M. Protière, L. Li, Small 5(2009) 154-168. doi: 10.1002/smll.200800841
15. [15]
  D. Vasudevan, R.R. Gaddam, A. Trinchi, I. Cole, J. Alloys Compd. 636(2015) 395-404. doi: 10.1016/j.jallcom.2015.02.102
16. [16]
  R. Ghosh Chaudhuri, S. Paria, Chem. Rev. 112(2012) 2373-2433. doi: 10.1021/cr100449n
17. [17]
  H. Zhu, N. Song, T. Lian, J. Am. Chem. Soc. 132(2010) 15038-15045. doi: 10.1021/ja106710m
18. [18]
  S. Kim, J. Park, T. Kim, et al., Small 7(2011) 70-73. doi: 10.1002/smll.201001096
19. [19]
  S. Kim, B. Fisher, H.J. Eisler, M. Bawendi, J. Am. Chem. Soc. 125(2003) 11466-11467. doi: 10.1021/ja0361749
20. [20]
  J. Zhou, M. Zhu, R. Meng, H. Qin, X. Peng, J. Am. Chem. Soc. 139(2017) 16556-16567. doi: 10.1021/jacs.7b07434
21. [21]
  D. Geißler, C. Würth, C. Wolter, H. Wellerb, U. Resch-Genger, Phys. Chem. Chem. Phys. 19(2017) 12509-12516. doi: 10.1039/C7CP02142A
22. [22]
  M. Cirillo, T. Aubert, R. Gomes, et al., Chem. Mater. 26(2014) 1154-1160. doi: 10.1021/cm403518a
23. [23]
  K.L. Sowers, Z. Hou, J.J. Peterson, et al., Chem. Phys. 471(2016) 24-31. doi: 10.1016/j.chemphys.2015.09.010
24. [24]
  I. Coropceanu, A. Rossinelli, J.R. Caram, F.S. Freyria, M.G. Bawendi, ACS Nano 10(2016) 3295-3301. doi: 10.1021/acsnano.5b06772
25. [25]
  J.J. Li, Y.A. Wang, W. Guo, et al., J. Am. Chem. Soc. 125(2003) 12567-12575. doi: 10.1021/ja0363563
26. [26]
  O. Chen, J. Zhao, V.P. Chauhan, et al., Nat. Mater. 12(2013) 445-451. doi: 10.1038/nmat3539
27. [27]
  A.C.A. Silva, S.W. da Silva, P.C. Morais, N.O. Dantas, ACS Nano 8(2014) 1913-1922. doi: 10.1021/nn406478f
28. [28]
  P. Jiang, C.N. Zhu, D.L. Zhu, et al., J. Mater. Chem. C. 3(2015) 964-967. doi: 10.1039/C4TC02437K
29. [29]
  M. Nasilowski, L. Nienhaus, S.N. Bertram, M.G. Bawendi, Chem. Commun. 53(2017) 869-872. doi: 10.1039/C6CC07403K
30. [30]
  S. Ithurria, D.V. Talapin, J. Am. Chem. Soc. 134(2012) 18585-18590. doi: 10.1021/ja308088d
31. [31]
  Z.A. Peng, X. Peng, J. Am. Chem. Soc. 124(2002) 3343-3353. doi: 10.1021/ja0173167
32. [32]
  J. Jasieniak, C. Bullen, J. van Embden, P. Mulvaney, J. Phys. Chem. B 109(2005) 20665-20668. doi: 10.1021/jp054289o
33. [33]
  H. Zhang, B. Hu, L. Sun, et al., Nano Lett. 11(2011) 5356-5361. doi: 10.1021/nl202892p
34. [34]
  L. Liu, X. Zhang, L. Ji, et al., RSC Adv. 5(2015) 90570-90577. doi: 10.1039/C5RA18192E
35. [35]
  W. Kim, S.J. Lim, S. Jung, S.K. Shin, J. Phys. Chem. C 114(2010) 1539-1546.
1. [1]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2023.100212
2. [2]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
3. [3]
  Tiantian Gong , Yanan Chen , Shuo Wang , Miao Wang , Junwei Zhao . Rigid-flexible-ligand-ornamented lanthanide-incorporated selenotungstates and photoluminescence properties. Chinese Journal of Structural Chemistry, 2024, 43(9): 100370-100370. doi: 10.1016/j.cjsc.2024.100370
4. [4]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
5. [5]
  Yan Wang , Si-Meng Zhai , Peng Luo , Xi-Yan Dong , Jia-Yin Wang , Zhen Han , Shuang-Quan Zang . Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals. Chinese Chemical Letters, 2024, 35(11): 109493-. doi: 10.1016/j.cclet.2024.109493
6. [6]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
7. [7]
  Bohan Zhang , Bingzhe Wang , Guichuan Xing , Zikang Tang , Songnan Qu . Regulation of the multi-emission centers in carbon dots via a bottom-up synthesis approach. Chinese Chemical Letters, 2024, 35(9): 109358-. doi: 10.1016/j.cclet.2023.109358
8. [8]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
9. [9]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
10. [10]
  Huanyu Liu , Gang Yu , Ruoyao Guo , Hao Qi , Jiayin Zheng , Tong Jin , Zifeng Zhao , Zuqiang Bian , Zhiwei Liu . Direct identification of energy transfer mechanism in Ce^Ⅲ-Mn^Ⅱ system by constructing molecular heteronuclear complexes. Chinese Chemical Letters, 2025, 36(2): 110296-. doi: 10.1016/j.cclet.2024.110296
11. [11]
  Huan Hu , Ying Zhang , Shi-Shuang Huang , Zhi-Gang Li , Yungui Liu , Rui Feng , Wei Li . Temperature- and pressure-responsive photoluminescence in a 1D hybrid lead halide. Chinese Journal of Structural Chemistry, 2024, 43(10): 100395-100395. doi: 10.1016/j.cjsc.2024.100395
12. [12]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
13. [13]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
14. [14]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
15. [15]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
16. [16]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
17. [17]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
18. [18]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
19. [19]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
20. [20]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1123)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142