Citation: Ma Chuang, Tan Xianjun, Zhang Haijiao, Shen Qun, Sun Nannan, Wei Wei. Direct conversion of methane to methanol over Cu exchanged mordenite: Effect of counter ions[J]. Chinese Chemical Letters, ;2020, 31(1): 235-238. doi: 10.1016/j.cclet.2019.03.039 shu

Direct conversion of methane to methanol over Cu exchanged mordenite: Effect of counter ions

Ma Chuang ^a,b,1 ,
Tan Xianjun ^b,1 ,
Zhang Haijiao ^a ,
Shen Qun ^b ,
Sun Nannan ^b,*, ,
Wei Wei ^b,c,*,

a.
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
b.
CAS Key Lab of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
c.
School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

sunnn@sari.ac.cn

weiwei@sari.ac.cn

Received Date: 22 March 2019
Accepted Date: 23 March 2019
Available Online: 25 January 2019

Figures(5)

Direct conversion of methane (CH₄) to methanol (DMTM) is a promising, but very challenging process for the utilization of abundant CH₄ as a low carbon resource. In this context, Cu loaded zeolites, mordenite (MOR) in particular, were recognized as the most effective system to perform DMTM. In this work, different Cu salts were used to exchange with MOR, by which the effect of counter ions on the catalytic performance towards DMTM was investigated. The prepared catalysts were characterized and evaluated systematically. It was found that the counter ions affected the speciation of Cu sites, probably due to their capability in extraction of protons from MOR and the influence on the hydrolysis state of the Cu²⁺ in aqueous solution. These behaviors adjusted the association between Cu²⁺ and the exchangeable protons in MOR. As a result, varied DMTM performance was observed. Among the used Cu salts, Cu(CH₃COO)₂ exchanged MOR showed the highest performance, achieving stable CH₃OH yield of 117±28 μmol/g in 5 consecutive cycles, these values are among the highest for Cu loaded MOR zeolites in open publications.
- Methane,
- Methanol,
- Zeolite,
- Mordenite,
- MOR,
- Cu
1. [1]
  U.S. Energy Information Administration, International Energy Outlook, 2018.
2. [2]
  C.D. Elvidge, M. Zhizhin, K. Baugh, et al., Energies 9(2016) 14.
3. [3]
  J.R. Rostrup-Nielsen, J. Sehested, J.K. Nørskov, Adv. Catal. 47(2002) 65-139.
4. [4]
  M. Ravi, M. Ranocchiari, J.A. van Bokhoven, Angew. Chem. Int. Ed. 56(2017) 16464-16483. doi: 10.1002/anie.201702550
5. [5]
  P. Tomkins, M. Ranocchiari, J.A. Van Bokhoven, Acc. Chem. Res. 56(2017) 418-425. doi: 10.1021/acs.accounts.6b00534
6. [6]
  A.C. Rosenzweig, C.A. Frederick, S.J. Lippard, P. Nordlund, Nature 366(1993) 537-543. doi: 10.1038/366537a0
7. [7]
  S. Friedle, E. Reisner, S.J. Lippard, Chem. Soc. Rev. 39(2010) 2768-2779. doi: 10.1039/c003079c
8. [8]
  V.L. Sushkevich, D. Palagin, M. Ranocchiari, et al., Science 356(2017) 523-527. doi: 10.1126/science.aam9035
9. [9]
  P. Tomkins, A. Mansouri, S.E. Bozbag, et al., Angew. Chem. Int. Ed. 55(2016) 5467-5471. doi: 10.1002/anie.201511065
10. [10]
  E.M.C. Alayon, M. Nachtegaal, M. Ranocchiari, et al., Chem. Commun. 48(2012) 404-406. doi: 10.1039/C1CC15840F
11. [11]
  S.E. Bozbag, E.M.C. Alayon, J. Pechácek, et al., Catal. Sci. Technol. 6(2016) 50119-5022. doi: 10.1039/C6CY00041J
12. [12]
  M.B. Park, S.H. Ahn, A. Mansouri, et al., ChemCatChem 9(2017) 3705-3713. doi: 10.1002/cctc.201700768
13. [13]
  E.M.C. Alayon, M. Nachtegaal, A. Bodi, et al., Phys. Chem. Chem. Phys. 17(2015) 7681-7693. doi: 10.1039/C4CP03226H
14. [14]
  M.A.C. Markovits, A. Jentys, M. Tromp, et al., Top. Catal. 59(2016) 1554-1563. doi: 10.1007/s11244-016-0676-x
15. [15]
  T. Sheppard, C.D. Hamill, A. Goguet, et al., Chem. Commun. 50(2014) 11053-11055. doi: 10.1039/C4CC02832E
16. [16]
  M.J. Wulfers, S. Teketel, B. Ipek, et al., Chem. Commun. 51(2015) 4447-4450. doi: 10.1039/C4CC09645B
17. [17]
  B. Ipek, R.F. Lobo, Chem. Commun. 52(2016) 13401-13404. doi: 10.1039/C6CC07893A
18. [18]
  S. Grundner, M.A.C. Markovits, G. Li, et al., Nat. Commun. 6(2015) 7546. doi: 10.1038/ncomms8546
19. [19]
  K. Narsimhan, K. Iyoki, K. Dinh, et al., ACS Cent. Sci. 2(2016) 424-429. doi: 10.1021/acscentsci.6b00139
20. [20]
  S. Grundner, W. Luo, M. Sanchez-Sanchez, et al., Chem. Commun. 52(52) (2016) 2553-2556. doi: 10.1039/C5CC08371K
21. [21]
  D.K. Pappas, E. Borfecchia, M. Dyballa, et al., J. Am. Chem. Soc. 139(2017) 14961-14975. doi: 10.1021/jacs.7b06472
22. [22]
  T. Sheppard, H. Daly, A. Goguet, et al., ChemCatChem 8(2016) 562-570. doi: 10.1002/cctc.201500980
23. [23]
  Y. Kim, T.Y. Kim, H. Lee, et al., Chem. Commun. 53(2017) 4116-4119. doi: 10.1039/C7CC00467B
24. [24]
  H.V. Le, S. Parishan, A. Sagaltchik, et al., ACS Catal. 7(2017) 1403-1412. doi: 10.1021/acscatal.6b02372
25. [25]
  D.K. Pappas, A. Martini, M. Dyballa, et al., J. Am. Chem. Soc.140(2018) 15270-15278. doi: 10.1021/jacs.8b08071
26. [26]
  D. Palagin, A.J. Knorpp, A.B. Pinar, et al., Nanoscale 9(2017) 1144-1153. doi: 10.1039/C6NR07723D
27. [27]
  S.E. Bozbag, P. Šot, M. Nachtegaal, et al., ACS Catal. 8(2018) 5721-5731. doi: 10.1021/acscatal.8b01021
28. [28]
  E.M.C. Alayon, M. Nachtegaal, A. Bodi, et al., ACS Catal. 4(2013) 16-22. doi: 10.1021/cs400713c
29. [29]
  D. Palagin, A.J. Knorpp, A.B. Pinar, et al., Nanoscale 9(2017) 1144-1153. doi: 10.1039/C6NR07723D
30. [30]
  E.V. Starokon, M.V. Parfenov, L.V. Pirutko, et al., J. Phys. Chem. C 115(2011) 2155-2161. doi: 10.1021/jp109906j
31. [31]
  F.X. Llabrés i Xamena, P. Fisicaro, G. Berlier, et al., J. Phys. Chem. B 107(2003) 7036-7044. doi: 10.1021/jp0275847
32. [32]
  G.T. Palomino, P. Fisicaro, S. Bordiga, et al., J. Phys. Chem. B 104(2000) 4064-4073. doi: 10.1021/jp993893u
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