Citation: Huang Ci, Lu Feifei, Xu Ke, Ding Guanjun, You Lijun, Wang Jiabin, Zhang Qiqing. Synthesis of magnetic polyphosphazene-Ag composite particles as surface enhanced Raman spectroscopy substrates for the detection of melamine[J]. Chinese Chemical Letters, ;2019, 30(12): 2009-2012. doi: 10.1016/j.cclet.2019.02.006 shu

Synthesis of magnetic polyphosphazene-Ag composite particles as surface enhanced Raman spectroscopy substrates for the detection of melamine

Institute of Biomedical and Pharmaceutical Technology, College of Chemistry, Fuzhou University, Fuzhou 350002, China

ibptylj@fzu.edu.cn

Received Date: 19 January 2019
Accepted Date: 18 February 2019
Available Online: 19 December 2019

Figures(4)

Magnetic polyphosphazene (MPZS) particles coated by Ag nanoparticles (MPZS-Ag) have been developed as surface enhanced Raman spectroscopy (SERS) substrates for sensitive detection of melamine in aqueous solutions and milk samples. 5, 5'-Dithiobis-(2-nitrobenzoic acid) (DTNB) was used as model analyte to test the SERS activity of the MPZS-Ag particles. The prepared MPZS-Ag particles possess both magnetic responsiveness and excellent SERS properties. SERS detection of different concentrations of melamine aqueous solutions and spiked milk samples were performed by the MPZS-Ag particles. The limit of detection (LOD) of the melamine in aqueous solutions was 10^-7 mol/L (0.0126 mg/L) and 0.6 mg/L in real milk samples using the MPZS-Ag particles as SERS substrates. The LOD of the melamine are much lower than the safety values of Food and Drug Administration and Codex Alimentarius Commission. These results indicate that the MPZS-Ag particles have promising application prospect for SERS analysis in food safety fields.
- Polyphosphazene,
- Magnetic polymer particles,
- Surface enhanced Raman spectroscopy,
- Ag nanoparticles,
- Melamine detection
1. [1]
  A. Kim, S.J. Barcelo, R.S. Williams, Z.Y. Li, Anal. Chem. 84 (2012) 9303-9309. doi: 10.1021/ac302025q
2. [2]
  Z.Y. Xiong, X.W. Chen, P. Liou, M.S. Lin, Cellulose 24 (2017) 2801-2811. doi: 10.1007/s10570-017-1297-7
3. [3]
  H.J. Zhuang, W.F. Zhu, Z.Y. Yao, M. Li, Y.L. Zhao, Talanta 153 (2016) 186-190. doi: 10.1016/j.talanta.2016.03.011
4. [4]
  Y. Lu, Y.Q. Xia, G.Z. Liu, et al., Crit. Rev. Anal. Chem. 47 (2016) 51-66.
5. [5]
  A.K. Hau, T.H. Kwan, P.K. Li, J. Am. Soc. Nephrol. 20 (2009) 245-250. doi: 10.1681/ASN.2008101065
6. [6]
  World Health Organization (2010), https://www.who.int/mediacentre/news/releases/2010/melamine_food_20100706/en/.
7. [7]
  U.S. Food and Drug Administration (2008), http://wayback.archiveit.org/7993/20170404230622/https://www.fda.gov/Food/FoodborneIllnessContaminants/ChemicalContaminants/ucm164520.htm.
8. [8]
  H.T. Lei, R. Su, S.A. Haughey, et al., Molecules 16 (2011) 5591-5603. doi: 10.3390/molecules16075591
9. [9]
  Y. Zhou, C.Y. Li, Y.S. Li, et al., Food Chem. 135 (2012) 2681-2686. doi: 10.1016/j.foodchem.2012.07.053
10. [10]
  M. Faraji, M. Adeli, Food Chem. 221 (2017) 139-146. doi: 10.1016/j.foodchem.2016.10.002
11. [11]
  J. Li, H.Y. Qi, Y.P. Shi, J. Chromatogr. A 1216 (2009) 5467-5471. doi: 10.1016/j.chroma.2009.05.047
12. [12]
  K. Rovina, S. Siddiquee, Food Control 59 (2016) 801-808. doi: 10.1016/j.foodcont.2015.07.009
13. [13]
  G.X. Cao, X.M. Wu, Y.M. Dong, Z.J. Li, G.L. Wang, Microchim. Acta 183 (2016) 441-448. doi: 10.1007/s00604-015-1669-3
14. [14]
  H.N. Guan, J. Yu, D.F. Chi, Food Control 32 (2013) 35-41. doi: 10.1016/j.foodcont.2012.11.041
15. [15]
  L. You, A. Wang, L. Song, C. Huang, Q.Q. Zhang, Mater. Lett. 212 (2018) 65-68. doi: 10.1016/j.matlet.2017.10.069
16. [16]
  H. Zhang, L. Sun, Y. Zhang, et al., Chin. Chem. Lett. 29 (2018) 981-984. doi: 10.1016/j.cclet.2017.10.017
17. [17]
  S. Pang, T.X. Yang, L.L. He, Trac-Trend Anal. Chem. 85 (2016) 73-82. doi: 10.1016/j.trac.2016.06.017
18. [18]
  M.D. Porter, J.H. Granger, Faraday Discuss. 205 (2017) 601. doi: 10.1039/C7FD00206H
19. [19]
  S. Abalde-Cela, P. Aldeanueva-Potel, C. Mateo-Mateo, et al., J. R. Soc. Interface 7 (2010) 435-450.
20. [20]
  S.Y. Ding, E.Y. You, Z.Q. Tian, M. Moskovits, Chem. Soc. Rev. 46 (2017) 4042-4076. doi: 10.1039/C7CS00238F
21. [21]
  S. Schlücker, Angew. Chem. Int. Ed. 53 (2014) 4756-4795. doi: 10.1002/anie.201205748
22. [22]
  Z.Q. Duan, X.B. Gao, T.P. Li, K. Yao, X.M. Xie, Chin. Chem. Lett. 28 (2017) 521-524. doi: 10.1016/j.cclet.2016.11.031
23. [23]
  A.M. Giovannozzi, F. Rolle, M. Sega, et al., Food Chem. 159 (2014) 250-256. doi: 10.1016/j.foodchem.2014.03.013
24. [24]
  R.P. Li, G.H. Yang, J.L. Yang, et al., Food Control 68 (2016) 14-19. doi: 10.1016/j.foodcont.2016.03.009
25. [25]
  L. You, C. Huang, F. Lu, et al., Int. J. Biol. Macromol. 107 (2018) 1620-1628. doi: 10.1016/j.ijbiomac.2017.10.025
26. [26]
  B. Han, N. Choi, K.H. Kim, W.L. Dong, J. Choo, J. Phys. Chem. C 115 (2011) 6290-6296. doi: 10.1021/jp112265e
27. [27]
  C. Wang, R. Xiao, S. Wang, et al., J. Mater. Chem. C 3 (2015) 8684-8693. doi: 10.1039/C5TC01839K
28. [28]
  C.W. Wang, J.F. Wang, P. Li, et al., Nanoscale 8 (2016) 19816. doi: 10.1039/C6NR07295J
29. [29]
  Y. Hu, L.J. Meng, L.Y. Niu, Q.H. Lu, ACS Appl. Mater. Inter. 5 (2013) 4586-4591. doi: 10.1021/am400843d
30. [30]
  M.H. Wang, J.W. Fu, D.D. Huang, C. Zhang, Q. Xu, Nanoscale 5 (2013) 7913. doi: 10.1039/c3nr00010a
31. [31]
  J. Liu, Z.K. Sun, Y.H. Deng, et al., Angew. Chem. Int. Ed. 48 (2009) 5875-5879. doi: 10.1002/anie.200901566
32. [32]
  X.Z. Wang, M.H. Wang, J.W. Fu, C. Zhang, Q. Xu, J. Nanopart. Res.15 (2013) 1853. doi: 10.1007/s11051-013-1853-5
33. [33]
  P.Y. Ma, F.H. Liang, Y. Sun, et al., Microchim. Acta 180 (2013) 1173-1180. doi: 10.1007/s00604-013-1059-7
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