Citation: Li Chaojie, Wei Zhangwen, Pan Mei, Deng Haiying, Jiang Jijun, Su Chengyong. Structural tuning of coordination polymers by 4-connecting metal node and secondary building process[J]. Chinese Chemical Letters, ;2019, 30(6): 1297-1301. doi: 10.1016/j.cclet.2019.02.001 shu

Structural tuning of coordination polymers by 4-connecting metal node and secondary building process

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

panm@mail.sysu.edu.cn

Received Date: 15 January 2019
Revised Date: 28 January 2019
Accepted Date: 2 February 2019
Available Online: 4 June 2019

Figures(5)

Five transition metal coordination polymers, {[Cu(4-pmntd)₂(NO₃)₂]·2CHCl₃}_n(1), {[Cu(4-pmntd)₂(NO₃)₂]·3C₇H₈}_n (2), {[Cu(4-pmntd)₂(CF₃SO₃)(H₂O)]·CF₃SO₃·H₂O·CH₃OH}_n (3), [Cd(4-pmntd)₂]_n·nSiF₆·x(CH₃OH)·y(CHCl₃) (4)and[Zn(4-pmntd)₂(CF₃SO₃)₂]_n·χ(solvent) (5), have been obtained from a ditopic ligand, N, N'-bis(4-pyridylmethyl)naphthalene diimide (4-pmntd). Either sql-or dia-structures are generated from four connecting coordination nodes of the metal centers. While delicate interpenetration and structural tuning in these complexes is achieved by the different conformations and spatially extending geometries adopted by the ligand and "secondary building process" induced by pillar-like anions.
- Coordination polymer,
- Structural tuning,
- Interpenetration,
- Pillar anions,
- Secondary building process
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