Citation: Zhang Lu, Zhang Ying-Ming, Liu Guoxing, Liu Yu. Redox-responsive diphenylalanine aggregate mediated by cyclodextrin[J]. Chinese Chemical Letters, ;2019, 30(1): 120-122. doi: 10.1016/j.cclet.2018.04.028 shu

Redox-responsive diphenylalanine aggregate mediated by cyclodextrin

Zhang Lu ^a ,
Zhang Ying-Ming ^a ,
Liu Guoxing ^a ,
Liu Yu ^a,b,*,,

a.
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
b.
Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300072, China

Corresponding author: Liu Yu, yuliu@nankai.edu.cn

Received Date: 24 February 2018
Revised Date: 15 April 2018
Accepted Date: 24 April 2018
Available Online: 27 January 2018

Figures(4)

The molecular assembling properties can be dramatically improved using redox-responsive nanoplatforms, which can bring quite different aggregation modes and binding behaviors in the redox states. In this work, we fabricated a redox-responsive system based on the host-guest complexation of β-cyclodextrin (β-CD) with ferrocene-modified diphenylalanine (Fc-FF). The morphological conversion of Fc-FF can be easily achieved from nanofibers to nanospheres in the presence of β-CD, and the supramolecular nanospheres can be reversibly assembled and disassembled by the chemical redox of ferrocenyl groups in the Fc-FF⊂β-CD nanoassemblies. These results demonstrate that the incorporation of stimuli-switchable components with macrocyclic receptors may become a promising approach to the construction of smart peptide-involved supramolecular assemblies.
- Cyclodextrin,
- Diphenylalanine,
- Redox-responsiveness,
- Morphological conversion,
- Supramolecular assembly
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