Citation: Lin Chao, Pan Renming, Xing Ping, Jiang Biao. Synthesis and combined properties of novel fluorinated cationic surfactants derived from hexafluoropropylene dimer[J]. Chinese Chemical Letters, ;2018, 29(11): 1613-1616. doi: 10.1016/j.cclet.2018.04.017 shu

Synthesis and combined properties of novel fluorinated cationic surfactants derived from hexafluoropropylene dimer

Lin Chao ^a ,
Pan Renming ^a ,
Xing Ping ^b ,
Jiang Biao ^a,b,*,,

a.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
b.
CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Corresponding author: Jiang Biao, jiangb@mail.sioc.ac.cn

Received Date: 31 January 2018
Revised Date: 23 March 2018
Accepted Date: 13 April 2018
Available Online: 17 November 2018

Figures(3)

Three novel fluorinated cationic surfactants were prepared byadopting perfluoro-2-methyl-2-pentene as raw substrate. The as-obtained fluorinated cationic surfactants exhibited excellent surface properties, all of them can reduce the surface tension of water to below 20.00 mN/m at the critical micelle concentrations (CMC). The incorporation of SDS, AOS, APG or LAB into 2-(4-(3, 3, 4, 4, 5, 5, 5-heptafluoro-2, 2-bis(trifluoromethyl)pentyl)benzamido)-N, N-dimethylethana-mine oxide 4a could generate much lower CMC and surface tension value at the CMC than individual 4a. Especially, the surface tension values of that combined APG/4a can be reduced to 17.31 mN/m. The excellent surface activities and their remarkable compatibility to various types of hydrocarbon surfactants make them as sustainable alternatives to PFOA (perfluorooctanoic acid, C₇F₁₅CO₂H) and PFOS (perfluorooctane sulphonate, C₈F₁₇SO₃X, with X=K, Na, H).
- Fluorinated cationic surfactants,
- Surface tension,
- Combined properties,
- Fire fighting,
- Aqueous film forming foams
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