Citation: Zhao Shiyong, Xu Bolian, Yu Lei, Fan Yining. Honeycomb-shaped PtSnNa/γ-Al₂O₃/cordierite monolithic catalyst with improved stability and selectivity for propane dehydrogenation[J]. Chinese Chemical Letters, ;2018, 29(6): 884-886. doi: 10.1016/j.cclet.2017.11.016 shu

Honeycomb-shaped PtSnNa/γ-Al₂O₃/cordierite monolithic catalyst with improved stability and selectivity for propane dehydrogenation

Zhao Shiyong ^a ,
Xu Bolian ^a,b ,
Yu Lei ^a,b,c,, ,
Fan Yining ^a,b,,

a.
Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
b.
Nanjing University-Yangzhou Chemistry and Chemical Engineering Institute, Yangzhou 211400, China
c.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: Yu Lei, yulei@yzu.edu.cn Fan Yining, yzuyulei@163.com
Received Date: 9 October 2017
Revised Date: 5 November 2017
Accepted Date: 14 November 2017
Available Online: 16 June 2017

Figures(4)

A novel honeycomb-shaped PtSnNa/γ-Al₂O₃/cordierite monolithic catalyst (Pt 0.5%, Sn 0.9%, Na 1.0%, relative to Al₂O₃ weight) was developed and its catalytic performances in propane dehydrogenation were tested and compared with the classical granule catalyst with same Pt, Sn and Na contents under the conditions of 0.1 MPa, 590℃, C₃H₈/H₂ at 3/1 (molar ratio) and gas hourly space velocity (GHSV) at 155 h^-1. Interestingly, despite the generated coke amount and exposed Pt fraction, the honey combshaped structure of monolithic catalyst exerted important influences on its catalytic activities and led to the advanced catalytic performances over the granule catalyst.
- Propane dehydrogenation,
- Propylene,
- Platinum,
- Cordierite,
- Monolithic catalyst
1. [1]
  W.W. Liu, Y.S. Feng, G.Y. Wang, et al., Chin. Chem. Lett. 27(2016) 905-909. doi: 10.1016/j.cclet.2016.02.026
2. [2]
  X.L. Ni, J. Liu, Y.Y. Liu, et al., Chin. Chem. Lett. 28(2017) 1057-1061. doi: 10.1016/j.cclet.2017.01.020
3. [3]
  F.T. Zangeneh, A. Taeb, K. Gholivand, S. Sahebdelfar, J. Energy Chem. 22(2013) 726-732. doi: 10.1016/S2095-4956(13)60096-0
4. [4]
  D.J. Childers, N.M. Schweitzer, S.M.K. Shahari, et al., J. Catal. 318(2014) 75-84. doi: 10.1016/j.jcat.2014.07.016
5. [5]
  U. Obenaus, F. Neher, M. Scheibe, et al., J. Phys. Chem. C 120(2016) 2284-2291. doi: 10.1021/acs.jpcc.5b11367
6. [6]
  S. Sokolov, M. Stoyanova, U. Rodemerck, D. Linke, E.V. Kondratenko, J. Catal. 293(2012) 67-75. doi: 10.1016/j.jcat.2012.06.005
7. [7]
  H.N. Pham, J.J.H.B. Sattler, B.M. Weckhuysen, A.K. Datye, ACS Catal. 6(2016) 2257-2264. doi: 10.1021/acscatal.5b02917
8. [8]
  H. Zhu, D.H. Anjum, Q. Wang, et al., J. Catal. 320(2014) 52-62. doi: 10.1016/j.jcat.2014.09.013
9. [9]
  Y. Zhang, Y. Zhou, L. Huang, et al., Chem. Eng. J. 270(2015) 352-361. doi: 10.1016/j.cej.2015.01.008
10. [10]
  M. Guisnet, N.S. Gnep, Catal. Today 31(1996) 275-292. doi: 10.1016/S0920-5861(96)00018-1
11. [11]
  S.R. De Miguel, S.A. Bocanegra, I.M.J. Vilella, A. Guerrero-Ruiz, O.A. Scelza, Catal. Lett. 119(2007) 5-15. doi: 10.1007/s10562-007-9215-5
12. [12]
  M.P. Lobera, C. Téuez, J. Herguido, M. Menéndez, Ind. Eng. Chem. Res. 47(2008) 9314-9320. doi: 10.1021/ie800848c
13. [13]
  S.J. Kim, Y. Liu, J.S. Moore, et al., Chem. Mater. 28(2016) 4397-4402. doi: 10.1021/acs.chemmater.6b01458
14. [14]
  Y. Wang, S. Wang, X. Guo, et al., Catal. Lett. 132(2009) 472-479. doi: 10.1007/s10562-009-0119-4
15. [15]
  P. Mériaudeau, A. Thangaraj, J.F. Dutel, C. Naccache, J. Catal. 167(1997) 180-186. doi: 10.1006/jcat.1997.1531
16. [16]
  P. Andy, M.E. Davis, Ind. Eng. Chem. Res. 43(2004) 2922-2928. doi: 10.1021/ie030357m
17. [17]
  J.J.H.B. Sattler, J. Ruiz-Martinez, E. Santillan-Jimenez, B.M. Weckhuysen, Chem. Rev. 114(2014) 10613-10653. doi: 10.1021/cr5002436
18. [18]
  S.F. Zhao, X.T. Yao, B.H. Yan, et al., Chin. Chem. Lett. 28(2017) 1318-1323. doi: 10.1016/j.cclet.2017.03.023
19. [19]
  F.T. Zangeneh, S. Sahebdelfar, M. Bahmani, Chin. J. Chem. Eng. 21(2013) 730-735. doi: 10.1016/S1004-9541(13)60537-6
20. [20]
  Z. Nawaz, X. Tang, Y. Chu, F. Wei, Chin. J. Catal. 31(2010) 552-556. doi: 10.1016/S1872-2067(09)60071-1
21. [21]
  R.E. Hayes, B. Liu, R. Moxom, M. Votsmeier, Chem. Eng. Sci. 59(2004) 3169-3181. doi: 10.1016/j.ces.2004.05.002
22. [22]
  L. Hu, K.A. Boateng, J.M. Hill, J. Mol. Catal. A:Chem. 259(2006) 51-60. doi: 10.1016/j.molcata.2006.06.018
23. [23]
  R. Guettel, J. Knochen, U. Kunz, M. Kassing, T. Turek, Ind. Eng. Chem. Res. 47(2008) 6589-6597. doi: 10.1021/ie800377n
24. [24]
  Z. Nawaz, X.P. Tang, Y. Wang, F. Wei, Ind. Eng. Chem. Res. 49(2010) 1274-1280. doi: 10.1021/ie901465s
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Honeycomb-shaped PtSnNa/γ-Al2O3/cordierite monolithic catalyst with improved stability and selectivity for propane dehydrogenation

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通讯作者: 陈斌, bchen63@163.com

Honeycomb-shaped PtSnNa/γ-Al₂O₃/cordierite monolithic catalyst with improved stability and selectivity for propane dehydrogenation