Citation: Wang Weikang, Wu Yihu, Jiang Zhiwen, Wang Mozhen, Wu Qichao, Zhou Xiao, Ge Xuewu. Self-assembly of graphene oxide nanosheets in t-butanol/water medium under gamma-ray radiation[J]. Chinese Chemical Letters, ;2018, 29(6): 931-934. doi: 10.1016/j.cclet.2017.11.003 shu

Self-assembly of graphene oxide nanosheets in t-butanol/water medium under gamma-ray radiation

Wang Weikang ^a ,
Wu Yihu ^a ,
Jiang Zhiwen ^a ,
Wang Mozhen ^a,, ,
Wu Qichao ^b ,
Zhou Xiao ^b ,
Ge Xuewu ^a

a.
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
b.
Guangdong Tianan New Material Co., Ltd., Foshan 528000, China

Corresponding author: Wang Mozhen, pstwmz@ustc.edu.cn
Received Date: 14 October 2017
Revised Date: 26 October 2017
Accepted Date: 6 November 2017
Available Online: 10 June 2017

Figures(4)

The research on the properties of graphene oxide (GO) in various media has become one of the hottest topics since GO is now the main raw material for graphene-based advanced materials. In this work, the γ-ray radiation chemistry effect of GO nanosheets and their self-aggregation behavior in t-butanol/water medium were investigated. The results show that GO nanosheets are reduced and hydroxyalkylated simultaneously by the alcohol free radicals produced by the radiolysis of t-butanol/water solution under γ-ray radiation. The radiation-modified GO nanosheets will self-assemble into a self-standing graphene hydrogel when the pH of the solution is lower than 2. A hydroxyl-functionalized free-standing graphene aerogel is further obtained simply by freeze-drying. This work provides not only a general self-assembly mechanism of GO nanosheets in strong acidic alcohol/water media under high energy radiation, but also a facile and economical preparation method for hydroxyalkylated graphene-based aerogel.
- Graphene oxide,
- Gamma-ray radiation,
- t-Butanol/water solution,
- Self-assembly,
- Hydroxyalkylation,
- Graphene hydrogel,
- Graphene aerogel
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