Citation: Liu Jianguo, Zhang Ailing, Song Heng, Tong Qingxiao, Tung Chen-Ho, Wang Wenguang. Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand[J]. Chinese Chemical Letters, ;2018, 29(6): 949-953. doi: 10.1016/j.cclet.2017.09.059 shu

Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand

a.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
b.
Department of Chemistry, Shantou University, Shantou 515063, China

Corresponding author: Tong Qingxiao, qxtong@stu.edu.cn Wang Wenguang, wwg@sdu.edu.cn
Received Date: 6 August 2017
Revised Date: 28 September 2017
Accepted Date: 28 September 2017
Available Online: 4 June 2017

Figures(10)

A new class of iron(Ⅱ) hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron(Ⅱ) complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex[2H(NCMe)](BF₄) is capable of catalyzing aldehyde hydroboration by pinacolborane (HBpin) and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible.
- Iron(Ⅱ) hydride,
- Iron catalysis,
- Tetradentate ligand,
- Hydroboration,
- Aldehydes
1. [1]
  P.J. Chirik, Acc. Chem. Res. 48(2015) 1687-1695. doi: 10.1021/acs.accounts.5b00134
2. [2]
  T. Zell, D. Milstein, Acc. Chem. Res. 48(2015) 1979-1994. doi: 10.1021/acs.accounts.5b00027
3. [3]
  W.Y. Chu, X. Zhou, T.B. Rauchfuss, Organometallics 34(2015) 1619-1626. doi: 10.1021/om501152h
4. [4]
  D. Peng, Y. Zhang, X. Du, et al., J. Am. Chem. Soc. 135(2013) 19154-19166. doi: 10.1021/ja404963f
5. [5]
  P. Bhattacharya, J.A. Krause, H. Guan, Organometallics 30(2011) 4720-4729. doi: 10.1021/om2005589
6. [6]
  J. Chen, T. Xi, Z. Lu, Org. Lett. 16(2014) 6452-6455. doi: 10.1021/ol503282r
7. [7]
  L. Zhang, D. Peng, X. Leng, Z. Huang, Angew. Chem. Int. Ed. 52(2013) 3676-3680. doi: 10.1002/anie.201210347
8. [8]
  J.V. Obligacion, P.J. Chirik, Org. Lett. 15(2013) 2680-2683. doi: 10.1021/ol400990u
9. [9]
  S. Kaur-Ghumaan, L. Schwartz, R. Lomoth, et al., Angew. Chem. Int. Ed. 49(2010) 8033-8036. doi: 10.1002/anie.v49:43
10. [10]
  T. Liu, Q. Liao, M. O'Hagan, et al., Organometallics 34(2015) 2747-2764. doi: 10.1021/om501289f
11. [11]
  J.M. Darmon, S. Raugei, T. Liu, et al., ACS Catal. 4(2014) 1246-1260. doi: 10.1021/cs500290w
12. [12]
  T. Liu, D.L. Dubois, R.M. Bullock, Nat. Chem. 5(2013) 228-233. doi: 10.1038/nchem.1571
13. [13]
  C. Costentin, M. Robert, J.M. Saveant, Acc. Chem. Res. 48(2015) 2996-3006. doi: 10.1021/acs.accounts.5b00262
14. [14]
  H. Nakazawa, M. Itazaki, Top. Organomet. Chem. 33(2011) 27-81. doi: 10.1007/978-3-642-14670-1
15. [15]
  R.H. Morris, Acc. Chem. Res. 48(2015) 1494-1502. doi: 10.1021/acs.accounts.5b00045
16. [16]
  Y.Y. Li, S.L. Yu, W.Y. Shen, J.X. Gao, Acc. Chem. Res. 48(2015) 2587-2598. doi: 10.1021/acs.accounts.5b00043
17. [17]
  H. Fong, J.C. Peters, Inorg. Chem. 54(2015) 5124-5135.
18. [18]
  R. Bigler, A. Mezzetti, Org. Lett. 16(2014) 6460-6463. doi: 10.1021/ol503295c
19. [19]
  J.X. Gao, H.L. Wan, W.K. Wong, M.C. Tse, W.T. Wong, Polyhedron 15(1996) 1241-1251. doi: 10.1016/0277-5387(95)00385-1
20. [20]
  C. Bianchini, E. Farnetti, M. Graziani, M. Peruzzini, A. Polo, Organometallics 12(1993) 3753-3761. doi: 10.1021/om00033a054
21. [21]
  C. Zang, Y. Liu, Z.J. Xu, et al., Angew. Chem. Int. Ed. 55(2016) 10253-10257. doi: 10.1002/anie.201603410
22. [22]
  X. Gu, Y. Zhang, Z.J. Xu, C.M. Che, Chem. Commun. 50(2014) 7870-7873. doi: 10.1039/c4cc01631a
23. [23]
  J. Liu, F. Zhang, A. Zhang, et al., Chem. Asian J. 11(2016) 2271-2277. doi: 10.1002/asia.v11.16
24. [24]
  J. Herrmann, P.S. Pregosin, R. Salzmann, A. Albinati, Organometallics 14(1995) 3311-3318. doi: 10.1021/om00007a035
25. [25]
  T.B. Rauchfuss, F.T. Patino, D.M. Roundhill, Inorg. Chem. 14(1975) 652-656. doi: 10.1021/ic50145a043
26. [26]
  H. Lei, A.M. Royer, T.B. Rauchfuss, D. Gray, Organometallics 31(2012) 6408-6414. doi: 10.1021/om300631a
27. [27]
  A.A. Mikhailine, R.H. Morris, Inorg. Chem. 49(2010) 11039-11044. doi: 10.1021/ic101548j
28. [28]
  M. Aresta, P. Giannoccaro, M. Rossi, A. Sacco, Inorg. Chim. Acta 5(1971) 115-118. doi: 10.1016/S0020-1693(00)95893-6
29. [29]
  A. Suzuki, Angew. Chem. Int. Ed. 50(2011) 6722-6737. doi: 10.1002/anie.201101379
30. [30]
  S. Chakraborty, H. Guan, Dalton Trans. 39(2010) 7427-7436. doi: 10.1039/c002942d
31. [31]
  C. Wang, C. Wu, S. Ge, ACS Catal. 6(2016) 7585-7589. doi: 10.1021/acscatal.6b02654
32. [32]
  W. Yao, H. Fang, S. Peng, et al., Organometallics 35(2016) 1559-1564. doi: 10.1021/acs.organomet.6b00161
33. [33]
  X. Chen, Z. Lu, Org. Biomol. Chem. 15(2017) 2280-2306. doi: 10.1039/C6OB02817A
34. [34]
  S. Chakraborty, J.A. Krause, H. Guan, Organometallics 28(2009) 582-586. doi: 10.1021/om800948f
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1.
沈阳化工大学材料科学与工程学院沈阳 110142