Citation: Du Zhonghui, Yu Xinhong, Han Yanchun. Inkjet printing of viscoelastic polymer inks[J]. Chinese Chemical Letters, ;2018, 29(3): 399-404. doi: 10.1016/j.cclet.2017.09.031 shu

Inkjet printing of viscoelastic polymer inks

Du Zhonghui ^a,b ,
Yu Xinhong ^a,, ,
Han Yanchun ^a,,

a.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of the Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yu Xinhong, xhyu@ciac.ac.cn Han Yanchun, ychan@ciac.ac.cn
Received Date: 26 July 2017
Revised Date: 1 September 2017
Accepted Date: 12 September 2017
Available Online: 14 March 2017

Figures(6)

Inkjet printing is a new fabricating method that can realize the precise film deposition. For polymer inks, the coil-stretch transition of polymer chains always impacts the ink droplet formation and a beads-on-a string structure filament is formed, thus generating unwanted satellite droplets. This review provides a short introduction of the dynamic process of the droplet formation. Then fluid rheological requirements for a printable polymer ink are summarized. Finally the strain hardening phenomenon of polymer chains in the filament formation and its impact on polymer ink-jetting are discussed. The research of viscoelastic polymer inks shows that rheological parameters and viscoelasticity are two key factors that determine the printability of polymer inks.
- Inkjet printing,
- Droplet formation,
- Rheological properties,
- Polymer inks,
- Coil-stretch transition
1. [1]
  T.R. Hebner, C.C. Wu, D. Marcy, M.H. Lu, J.C. Sturm, Appl. Phys. Lett. 72(1998) 519-521. doi: 10.1063/1.120807
2. [2]
  P. C. Duineveld, M. A. de Kok, M. Buechel, et al., Ink-jet printing of polymer lightemitting devices, in: Z. H. Kafafi (Ed. ), Organic Light-Emitting Materials and Devices V, Spie-Int Soc Optical Engineering, Bellingham, 2002, pp. 59-67.
3. [3]
  E. Tekin, E. Holder, V. Marin, B.J. de Gans, U.S. Schubert, Macromol. Rapid Commun. 26(2005) 293-297. doi: 10.1002/(ISSN)1521-3927
4. [4]
  Z. Du, R. Xing, X. Cao, X. Yu, Y. Han, Polymer 115(2017) 45-51. doi: 10.1016/j.polymer.2017.03.023
5. [5]
  R. Xing, S. Wang, B. Zhang, et al., RSC Adv. 7(2017) 7725-7733. doi: 10.1039/C6RA27475G
6. [6]
  Z. Ding, R. Xing, Q. Fu, D. Ma, Y. Han, Org. Electron. 12(2011) 703-709. doi: 10.1016/j.orgel.2011.01.027
7. [7]
  R. Xing, T. Ye, Y. Ding, D. Ma, Y. Han, Org. Electron. 10(2009) 313-319. doi: 10.1016/j.orgel.2008.12.006
8. [8]
  J.A. Lim, W.H. Lee, H.S. Lee, et al., Adv. Funct. Mater. 18(2008) 229-234. doi: 10.1002/(ISSN)1616-3028
9. [9]
  H. Sirringhaus, T. Kawase, R.H. Friend, et al., Science 290(2000) 2123-2126. doi: 10.1126/science.290.5499.2123
10. [10]
  C.N. Hoth, P. Schilinsky, S.A. Choulis, C.J. Brabec, Nano Lett. 8(2008) 2806-2813. doi: 10.1021/nl801365k
11. [11]
  T. Cuk, S.M. Troian, C.M. Hong, S. Wagner, Appl. Phys. Lett. 77(2000) 2063-2065. doi: 10.1063/1.1311954
12. [12]
  G. D. Martin, S. D. Hoath, I. M. Hutchings, Iop, Engineering and Physics-Synergy for Success, Iop Publishing Ltd, Bristol, 2008, pp. 14.
13. [13]
  O.A. Basaran, H.J. Gao, P.P. Bhat, Annu. Rev. Fluid Mech. 45(2013) 85-113. doi: 10.1146/annurev-fluid-120710-101148
14. [14]
  B.J. de Gans, L.J. Xue, U.S. Agarwal, U.S. Schubert, Macromol. Rapid Commun. 26(2005) 310-314. doi: 10.1002/(ISSN)1521-3927
15. [15]
  H. Yoo, C. Kim, Rheol. Acta 52(2013) 313-325. doi: 10.1007/s00397-013-0688-4
16. [16]
  D. Xu, V. Sanchez-Romaguera, S. Barbosa, et al., J. Mater. Chem. 17(2007) 4902-4907. doi: 10.1039/b710879f
17. [17]
  B.J. de Gans, P.C. Duineveld, U.S. Schubert, Adv. Mater. 16(2004) 203-213. doi: 10.1002/(ISSN)1521-4095
18. [18]
  S.D. Hoath, O.G. Harlen, I.M. Hutchings, J. Rheol. 56(2012) 1109-1127. doi: 10.1122/1.4724331
19. [19]
  H. Dong, W.W. Carr, J.F. Morris, Phys. Fluids 18(2006) 16.
20. [20]
  B. Derby, Inkjet Printing of Functional and Structural Materials: Fluid Property Requirements, Feature Stability, and Resolution, in: D. R. Clarke, M. Ruhle, F. Zok (Eds. ), Annual Review of Materials Research, Vol 40, Annual Reviews, Palo Alto, 2010, pp. 395-414.
21. [21]
  M.P. Brenner, J. Eggers, K. Joseph, S.R. Nagel, X.D. Shi, Phys. Fluids 9(1997) 1573-1590. doi: 10.1063/1.869279
22. [22]
  R. Suryo, P. Doshi, O.A. Basaran, Phys. Fluids 18(2006) 31.
23. [23]
  J. Eggers, T.F. Dupont, J. Fluid Mech. 262(1994) 205-221. doi: 10.1017/S0022112094000480
24. [24]
  B. Ambravaneswaran, E.D. Wilkes, O.A. Basaran, Phys. Fluids 14(2002) 2606-2621. doi: 10.1063/1.1485077
25. [25]
  O.E. Yildirim, O.A. Basaran, J. Non-newton Fluid 136(2006) 17-37. doi: 10.1016/j.jnnfm.2006.02.009
26. [26]
  Q. Xu, O.A. Basaran, Phys. Fluids 19(2007) 12.
27. [27]
  D. Jang, D. Kim, J. Moon, Langmuir 25(2009) 2629-2635. doi: 10.1021/la900059m
28. [28]
  K.S. Kwon, M.H. Jang, H.Y. Park, H.S. Ko, Rev. Sci. Instrum. 85(2014) 12.
29. [29]
  R.E. Saunders, B. Derby, Int. Mater. Rev. 59(2014) 430-448. doi: 10.1179/1743280414Y.0000000040
30. [30]
  D. Soltman, V. Subramanian, Langmuir 24(2008) 2224-2231. doi: 10.1021/la7026847
31. [31]
  Q.L. Niu, Y.X. Shao, W. Xu, et al., Org. Electron. 9(2008) 95-100. doi: 10.1016/j.orgel.2007.10.001
32. [32]
  H.C. Nallan, J.A. Sadie, R. Kitsomboonloha, S.K. Volkman, V. Subramanian, Langmuir 30(2014) 13470-13477. doi: 10.1021/la502903y
33. [33]
  B. Derby, N. Reis, Mrs. Bull. 28(2003) 815-818. doi: 10.1557/mrs2003.230
34. [34]
  B. Derby, J. Eur. Ceram. Soc. 31(2011) 2543-2550. doi: 10.1016/j.jeurceramsoc.2011.01.016
35. [35]
  J.E. Fromm, Ibm. J. Res. Dev. 28(1984) 322-333. doi: 10.1147/rd.283.0322
36. [36]
  N. Reis, B. Derby, Ink jet deposition of ceramic suspensions: Modelling and experiments of droplet formation, in: S. C. Danforth, D. Dimos, F. B. Prinz (Eds. ), Solid Freeform and Additive Fabrication-2000, San francisco, 2000, pp. 117-122.
37. [37]
  S.D. Hoath, D.C. Vadillo, O.G. Harlen, et al., J. Non-Newton Fluid 205(2014) 1-10. doi: 10.1016/j.jnnfm.2014.01.002
38. [38]
  T.Y. Hill, T.L. Reitz, M.A. Rottmayer, H. Huang, ECS J. Solid State Sci. Technol. 4(2015) 3015-3019. doi: 10.1149/2.0031504jss
39. [39]
  C.D. Stow, M.G. Hadfield, Proc. R. Soc. London Ser. A Math. Phys. Eng. Sci. 373(1981) 419-441. doi: 10.1098/rspa.1981.0002
40. [40]
  S.D. Hoath, I.M. Hutchings, G.D. Martin, et al., J. Imaging Sci. Technol. 53(2009) 8.
41. [41]
  X.J. Yan, W.W. Carr, H.M. Dong, Phys. Fluids 23(2011) 15.
42. [42]
  J.J. Cooper-White, J.E. Fagan, V. Tirtaatmadja, D.R. Lester, D.V. Boger, J. NonNewton Fluid 106(2002) 29-59. doi: 10.1016/S0377-0257(02)00084-8
43. [43]
  R.P. Mun, J.A. Byars, D.V. Boger, J. Non-Newton Fluid 74(1998) 285-297. doi: 10.1016/S0377-0257(97)00074-8
44. [44]
  Y. Christanti, L.M. Walker, J. Non-Newton Fluid 100(2001) 9-26. doi: 10.1016/S0377-0257(01)00135-5
45. [45]
  V. Tirtaatmadja, G.H. McKinley, J.J. Cooper-White, Phys. Fluids 18(2006) 18.
46. [46]
  K. A-Alamry, K. Nixon, R. Hindley, J.A. Odel, S.G. Yeates, Macromol. Rapid Commun. 32(2011) 316-320. doi: 10.1002/marc.201000521
47. [47]
  B.-J. de Gans, E. Kazancioglu, W. Meyer, U.S. Schubert, Macromol. Rapid Commun. 25(2004) 292-296. doi: 10.1002/(ISSN)1521-3927
48. [48]
  D.C. Vadillo, W. Mathues, C. Clasen, Rheol. Acta 51(2012) 755-769. doi: 10.1007/s00397-012-0640-z
49. [49]
  C. McLlroy, O.G. Harlen, N.F. Morrison, J. Non-Newton Fluid 201(2013) 17-28. doi: 10.1016/j.jnnfm.2013.05.007
50. [50]
  E. Tekin, E. Holder, D. Kozodaev, U.S. Schubert, Adv. Funct. Mater. 17(2007) 277-284. doi: 10.1002/(ISSN)1616-3028
51. [51]
  J. D. Meyer, A. V. Bazilevsky, A. N. Rozhkov, Soc Imaging Science & Technology, Springfield, 1997.
52. [52]
  H.J. Shore, G.M. Harrison, Phys. Fluids 17(2005) 7.
53. [53]
  P.G. Degennes, J. Chem. Phys. 60(1974) 5030-5042. doi: 10.1063/1.1681018
54. [54]
  S. Hoath, G. Martin, R. Castrejon-Pita, I. Hutchings, Sis Soc Imaging Science & Technology, Springfield, 2007.
55. [55]
  S.D. Hoath, I.M. Hutchings, O.G. Harlen, et al., Soc Imaging Science & Technology, Springfield, 2012.
56. [56]
  S.D. Hoath, J.R. Castrejon-Pita, W.K. Hsiao, et al., J. Imaging Sci. Technol. 57(2013) 10.
57. [57]
  S.D. Hoath, W.K. Hsiao, S.J. Jung, et al., J. Imaging Sci. Technol. 57(2013) 11.
58. [58]
  S.D. Hoath, S. Jung, I.M. Hutchings, Phys. Fluids 25(2013) 5.
59. [59]
  S.J. Jung, S.D. Hoath, I.M. Hutchings, Microfluid. Nanofluid. 14(2013) 163-169. doi: 10.1007/s10404-012-1034-3
60. [60]
  A.V. Bazilevskii, J.D. Meyer, A.N. Rozhkov, Fluid Dyn. 40(2005) 376-392. doi: 10.1007/s10697-005-0078-4
61. [61]
  T.R. Tuladhar, M.R. Mackley, J. Non-Newton Fluid 148(2008) 97-108. doi: 10.1016/j.jnnfm.2007.04.015
62. [62]
  C. McIlroy, O.G. Harlen, N.F. Morrison, J. Non-Newton Fluid 201(2013) 17-28. doi: 10.1016/j.jnnfm.2013.05.007
63. [63]
  B.J. de Gans, U.S. Schubert, Langmuir 20(2004) 7789-7793. doi: 10.1021/la049469o
1. [1]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
2. [2]
  Xiangjun Zhang , Xiaodi Yang , Yan Wang , Zhongping Xu , Sisi Yi , Tao Guo , Yue Liao , Xiyu Tang , Jianxiang Zhang , Ruibing Wang . A supramolecular nanoprodrug for prevention of gallstone formation. Chinese Chemical Letters, 2025, 36(2): 109854-. doi: 10.1016/j.cclet.2024.109854
3. [3]
  Guifeng Wen , Zheyuan Zhong , Yue Fan , Xuelin Tian , Shilin Huang . Multidimensional droplet manipulation on superhydrophobic surfaces using acoustic tweezers. Chinese Chemical Letters, 2025, 36(5): 110672-. doi: 10.1016/j.cclet.2024.110672
4. [4]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
5. [5]
  Fengkai Zou , Borui Su , Han Leng , Nini Xin , Shichao Jiang , Dan Wei , Mei Yang , Youhua Wang , Hongsong Fan . Red-emissive carbon quantum dots minimize phototoxicity for rapid and long-term lipid droplet monitoring. Chinese Chemical Letters, 2024, 35(10): 109523-. doi: 10.1016/j.cclet.2024.109523
6. [6]
  Huamei Zhang , Jingjing Liu , Mingyue Li , Shida Ma , Xucong Zhou , Aixia Meng , Weina Han , Jin Zhou . Imaging polarity changes in pneumonia and lung cancer using a lipid droplet-targeted near-infrared fluorescent probe. Chinese Chemical Letters, 2024, 35(12): 110020-. doi: 10.1016/j.cclet.2024.110020
7. [7]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
8. [8]
  Zili Ma , Zeyu Li , Jun Lv . Shortening the formation time of oxide thin film photoelectrodes from hours to seconds. Chinese Journal of Structural Chemistry, 2025, 44(4): 100450-100450. doi: 10.1016/j.cjsc.2024.100450
9. [9]
  Shujun Ning , Zhiyuan Wei , Zhening Chen , Tianmin Wu , Lu Zhang . Curvature and defect formation synergistically promote the photocatalysis of ZnO slabs. Chinese Chemical Letters, 2025, 36(7): 111057-. doi: 10.1016/j.cclet.2025.111057
10. [10]
  Yi Zhu , Jingyan Zhang , Yuchao Zhang , Ying Chen , Guanghui An , Ren Liu . Designing unimolecular photoinitiator by installing NHPI esters along the TX backbone for acrylate photopolymerization and their applications in coatings and 3D printing. Chinese Chemical Letters, 2024, 35(7): 109573-. doi: 10.1016/j.cclet.2024.109573
11. [11]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
12. [12]
  Yaohua Li , Qi Cao , Xuanhua Li . Tailoring the configuration of polymer passivators in perovskite solar cells. Chinese Journal of Structural Chemistry, 2025, 44(2): 100413-100413. doi: 10.1016/j.cjsc.2024.100413
13. [13]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
14. [14]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
15. [15]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
16. [16]
  Haoting Wang , Mengfan Luo , Yuzhong Wang , Jialong Yin , Heng Zhang , Jia Zhao , Bo Lai . Mn(Ⅱ) enhanced permanganate oxidation of trace organic pollutants in water: Critical role of in situ formation of colloidal MnO₂. Chinese Chemical Letters, 2025, 36(6): 110348-. doi: 10.1016/j.cclet.2024.110348
17. [17]
  Weibin Shen , Jie Liu , Gongyu Wen , Shuai Li , Binhui Yu , Shuangyu Song , Bojie Gong , Rongyang Zhang , Shibao Liu , Hongpeng Wang , Yao Wang , Yujing Liu , Huadong Yuan , Jianming Luo , Shihui Zou , Xinyong Tao , Jianwei Nai . Formation of FeNi-based nanowire-assembled superstructures with tunable anions for electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(7): 110184-. doi: 10.1016/j.cclet.2024.110184
18. [18]
  Xiaoyu Chen , Jiahao Hu , Jingyi Lin , Haiyang Huang , Changqing Ye , Hongli Bao . Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties. Chinese Chemical Letters, 2025, 36(2): 109923-. doi: 10.1016/j.cclet.2024.109923
19. [19]
  Bowen Song , Chenxu Shi , Yinghao Qu , Hongjun Liu , Hui Yang , Xiaoming Wu , Xijun Liu . The electrical properties and charge transport mechanism of MXenes. Chinese Chemical Letters, 2025, 36(6): 110823-. doi: 10.1016/j.cclet.2025.110823
20. [20]
  Guoju Guo , Xufeng Li , Jie Ma , Yongjia Shi , Jian Lv , Daoshan Yang . Photocatalyst/metal-free sequential C–N/C–S bond formation: Synthesis of S-arylisothioureas via photoinduced EDA complex activation. Chinese Chemical Letters, 2024, 35(11): 110024-. doi: 10.1016/j.cclet.2024.110024

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(926)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142